Triazine ring-containing polymer and membrane-forming composition containing the same

Patent metadata

Field	Value
Publication number	US-9695281-B2
Application number	US-201113818577-A
Country	US
Kind code	B2
Filing date	Aug 23, 2011
Priority date	Aug 25, 2010
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

Disclosed is a triazine ring-containing hyperbranched polymer containing a repeating unit structure represented by the expression (1). By this means, it is possible to achieve a triazine ring-containing polymer which, alone, has high heat resistance, high transparency, high refractive index, high light resistance, high solubility, low volume shrinkage without adding metal oxides; and also a membrane-forming composition containing the same.

In the formula, R and R′ represent independently a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, or an aralkyl group, and A represents an alkylene group optionally having a branched or alicyclic structure of 1 to 20 carbon atoms.

First claim

The invention claimed is:

1. A film consisting essentially of a triazine ring-containing hyperbranched polymer characterized by comprising a recurring unit structure of formula (1) below

wherein R and R′ are each independently a hydrogen atom or an alkyl, alkoxy, aryl or aralkyl group; and A is an alkylene group which may have an alicyclic structure of 1 to 20 carbons and is at least one moiety selected from the group consisting of moieties of formulas (2) to (14) below

R 1 and R 2 being each independently an alkylene group which may have a branched structure of 1 to 5 carbons, and
wherein the polymer is capped on at least one end by an alkyl, aralkyl, aryl, alkylamino, alkoxysilyl-containing alkylamino, aralkylamino, arylamino, alkoxy, aralkyloxy, aryloxy or ester group,
wherein the hyperbranched polymer has a weight-average molecular weight of between 400 and 10,000.

2. The film according to claim 1 , wherein A has formula (2).

3. The film according to claim 1 , wherein the recurring unit structure of the polymer has formula (15) below

4. The film according to claim 1 , wherein the recurring unit structure of the polymer has formula (16) below

5. The film according to claim 1 , wherein the polymer has at least one terminal triazine ring which is capped by an alkyl, aralkyl, aryl, alkylamino, alkoxysilyl-containing alkylamino, aralkylamino, arylamino, alkoxy, aralkyloxy, aryloxy or ester group.

6. An electronic device comprising a base material and the film of claim 1 formed on the base material.

7. An optical member comprising a base material and the film of claim 1 formed on the base material.

8. A solid-state image sensor formed of a charge-coupled device or complementary metal oxide semiconductor, which sensor comprises at least one layer of the film of claim 1 .

9. A solid-state image sensor comprising the film of claim 1 as a planarization layer on a color filter.

Assignees

• Nishimura Naoya
• Ozawa Masaaki
• Koide Yasuyuki
• Nissan Chemical Ind Ltd

Inventors

• Nishimura Naoya
• Ozawa Masaaki
• Koide Yasuyuki

Classifications

• C08L2203/16

  used for films · CPC title

• H05B33/10

  Apparatus or processes specially adapted to the manufacture of electroluminescent light sources · CPC title

• C08G73/0273 Primary

  Polyamines containing heterocyclic moieties in the main chain · CPC title

• C08G73/0644 Primary

  Poly(1,3,5)triazines · CPC title

• G02B1/04

  made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title