Alkali metal cinnamate powder and method for preparation

Patent metadata

Field	Value
Publication number	US-9695102-B2
Application number	US-201013513083-A
Country	US
Kind code	B2
Filing date	Dec 2, 2010
Priority date	Dec 3, 2009
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

A method for the preparation of an alkali metal cinnamate powdery product, preferably potassium cinnamate or sodium cinnamate, is disclosed herein. The resulting product has novel structural properties. The powder of the present disclosure is made via spray-drying and/or spray agglomeration and has a higher flowability, is less cohesive and less dusty, has an improved dissolution rate and in particular has a very favorable organoleptic profile. The disclosure is also directed to product applications in which the novel cinnamate product of the present disclosure may be applied.

First claim

The invention claimed is:

1. A method for the preparation of an alkali metal cinnamate powdery product comprising atomizing a solution or slurry comprising alkali metal cinnamate to droplets and contacting the droplets with heated gas to form solid alkali metal cinnamate particles followed by separating the solid particles from the gas, where in the solution or slurry of alkali metal cinnamate is obtained by the reaction of unsubstituted cinnamic acid with alkali metal hydroxide.

2. The method according to claim 1 wherein the gas is air.

3. The method according to claim 1 wherein said cinnamic acid is reacted with alkali metal hydroxide in an aqueous environment to obtain a solution or slurry of alkali metal cinnamate having a pH of from 8 to 10.

4. The method according to claim 1 wherein said alkali metal cinnamate is potassium cinnamate or sodium cinnamate, and wherein said solution or slurry comprising potassium cinnamate or sodium cinnamate is obtained by the reaction of said cinnamic acid with potassium hydroxide or sodium hydroxide.

5. The method according to claim 4 wherein the potassium cinnamate solution or slurry comprises 10-50 wt % of potassium cinnamate.

6. The method according to claim 1 wherein the droplets are also contacted with solid particles of the same alkali metal cinnamate as the droplets to form agglomerates of solid alkali metal cinnamate particles followed by the separation of said agglomerates of solid particles from the gas.

7. An alkali metal cinnamate powder obtained by the method according to claim 6 , said powder comprising alkali metal cinnamate particles, the particles having a ratio of the largest diameter to the smallest diameter of at the most 1.3, the powder having a Hausner ratio of at the most 1.2.

8. The method according to claim 1 further comprising treating the solution or slurry with activated carbon prior to atomizing.

9. An alkali metal cinnamate powder obtained by the method according to claim 8 , said powder comprising alkali metal cinnamate particles, the particles having a ratio of the largest diameter to the smallest diameter of at the most 1.3, the powder having a Hausner ratio of at the most 1.2.

10. An alkali metal cinnamate powder obtained by the method according to claim 1 , said powder comprising alkali metal cinnamate particles, the particles having a ratio of the largest diameter to the smallest diameter of at the most 1.3, the powder having a Hausner ratio of at the most 1.2.

11. The alkali metal cinnamate powder of claim 10 , wherein the particle size of the alkali metal cinnamate particles is between 100 and 1000 micrometers.

12. The alkali metal cinnamate powder of claim 10 , wherein the d 50 of the alkali metal cinnamate particles is between 250 and 450 micrometers.

13. The alkali metal cinnamate powder of claim 10 , wherein the alkali metal is potassium.

14. The alkali metal cinnamate powder of claim 10 and wherein the powder is used in personal care, cosmetic or technical product applications and/or food and/or beverage applications.

15. An alkali metal cinnamate powder of claim 10 and wherein the particles having a ratio of the largest diameter to the smallest diameter of at the most 1.2.

16. An alkali metal cinnamate powder of claim 10 and wherein the particles having a ratio of the largest diameter to the smallest diameter of at the most 1.1.

17. A method for the preparation of an alkali metal cinnamate powdery product having an improved organoleptic profile with respect to taste and color, the method comprising atomizing a solution or slurry comprising alkali metal cinnamate to droplets and contacting the droplets with heated gas to form solid alkali metal cinnamate particles followed by separating the solid particles from the gas, where in the solution or slurry of alkali metal cinnamate is obtained by the reaction of unsubstituted cinnamic acid with alkali metal hydroxide.

18. The method according to claim 17 wherein said alkali metal cinnamate is potassium cinnamate or sodium cinnamate, and wherein said solution or slurry comprising potassium cinnamate or sodium cinnamate is obtained by the reaction of said cinnamic acid with potassium hydroxide or sodium hydroxide.

19. The method according to claim 18 wherein the potassium cinnamate solution or slurry comprises 10-50 wt % of potassium cinnamate.

20. The method according to claim 17 wherein the droplets are also contacted with solid particles of the same alkali metal cinnamate as the droplets to form agglomerates of solid alkali metal cinnamate particles followed by the separation of said agglomerates of solid particles from the gas.

21. The method according to claim 17 further comprising treating the solution or slurry with activated carbon prior to atomizing.

22. The method according to claim 17 wherein said cinnamic acid is reacted with alkali metal hydroxide in an aqueous environment to obtain a solution or slurry of alkali metal cinnamate having a pH of from 8 to 10.

Assignees

• Roozen Lambertus Hendricus Elisabeth
• Bontenbal Elize Willem
• Vogiatzis Nikolaos
• Dierdorp-Andreas Brenda Marja
• Purac Biochem Bv

Inventors

• Roozen Lambertus Hendricus Elisabeth
• Bontenbal Elize Willem
• Vogiatzis Nikolaos
• Dierdorp-Andreas Brenda Marja

Classifications

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title

• C07C51/47

  by solid-liquid treatment; by chemisorption · CPC title

• C07C69/618

  having unsaturation outside the six-membered aromatic ring · CPC title

• C07C69/612

  Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety · CPC title

• C07C57/44 Primary

  Cinnamic acid · CPC title