Process for preparing a catalyst based on a group VIII metal and containing silicon, and a process of selective hydrogenation implementing said catalyst

Patent metadata

Field	Value
Publication number	US-9695095-B2
Application number	US-201314402620-A
Country	US
Kind code	B2
Filing date	Apr 5, 2013
Priority date	May 24, 2012
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

A process for preparing a selective hydrogenation catalyst is described, wherein is provided a catalyst precursor, comprising at least one group VIII metal in the metallic form, and at least one support formed of at least one oxide, characterized in that a step is performed of contacting the said catalyst precursor in the metallic form, in the liquid phase and in the presence of a reducing and/or inert atmosphere, with a non-polar solvent containing a silicon compound, the said silicon compound is selected from the silanes containing at least one Si—H bond and at least one Si—C bond, the silanols and the cyclic siloxanes.
The selective hydrogenation process implementing the said catalyst is also described.

First claim

The invention claimed is:

1. A process for preparing a selective hydrogenation catalyst comprising, contacting a catalyst precursor in the metallic form, in the liquid phase and in the presence of a reducing and/or inert atmosphere, with a non-polar solvent containing a silicon compound, that is a silane containing at least one Si—H bond and at least one Si—C bond, of the formula Si x H y R z , wherein x is an integer of 1 to 6, y is an integer of 1 to 2x+1, and z is an integer of 1 to 2x+1, the sum of y+z being 2x+2, and R is a monovalent hydrocarbon radical, identical or different for each valence, that is a saturated aliphatic radical, an unsaturated aliphatic radical, a cycloalkyl radical, an aryl radical or an arylalkyl radical, a silanol of the formula Si x (OH)R 2x+1 , wherein x is an integer within the range 1 to 6 and R is a monovalent hydrocarbon radical, identical or different for each valence, that is a saturated aliphatic radical, an unsaturated aliphatic radical, a cycloalkyl radical, an aryl radical or an arylalkyl radical or a cyclic siloxane in which a principal —Si—O—Si—O— chain forms a ring and is composed of (R 2 SiO) n units, with n being an integer of 3 to 11, and R is a monovalent hydrocarbon radical, identical or different for each valence, that is a saturated aliphatic radical, an unsaturated aliphatic radical, a cycloalkyl radical, an aryl radical or an arylalkyl radical, wherein the catalyst precursor, comprises palladium in the metallic form and at least one support comprising at least one simple oxide that is alumina, silica, titanium oxide, cerium oxide or zirconium dioxide.

2. A process according to claim 1 , wherein the non-polar solvent is an aliphatic hydrocarbon solvent, a cyclic hydrocarbon solvent, an aromatic hydrocarbon solvent, a partially saturated gasoline, a partially hydrogenated effluent derived from a selective hydrogenation process, or a mixture of these solvents.

3. A process according to claim 1 , wherein the silicon compound is present in the non-polar solvent in a concentration between 0.01 and 10 wt. % of silicon.

4. A process according to claim 1 , wherein contacting is performed at a temperature within the range 20 to 200° C.

5. A process according to claim 1 , which further comprises, before contacting:
a) at least one impregnation of a solution containing at least one precursor of palladium is impregnated onto the support,
b) at least once drying the impregnated support resulting from a),
c) at least one calcining of dried support resulting from b), so as to obtain palladium in oxide form,
d) at least one reductive treatment of calcined support resulting from c) by contact with a reducing gas so as to obtain palladium in the metallic form.

6. A process according to claim 5 , wherein drying b) is performed at a temperature within the range 20 to 160° C., calcining c) is performed at a temperature within the range 150 to 800° C. and d) reductive treatment by contact with a reducing gas is performed at a temperature above or equal to 50° C.

7. A process according to claim 5 further comprising e), wherein a passivation of the catalyst precursor is performed by a sulphur compound, said passivation being performed either after calcination c) and before d) reductive treatment of the catalyst precursor, or after d) reductive treatment of the catalyst precursor, or after contact of precursor and solvent.

8. A catalyst obtained by the process according to claim 1 .

9. A process of selective hydrogenation, wherein the catalyst in the metallic form and prepared according to claim 1 is placed in contact with a feed of polyunsaturated hydrocarbons containing at least 3 carbon atoms per molecule and having a final boiling point below or equal to 250° C.

10. A process according to claim 9 , wherein the feed is a C3 steam-cracking cut, a C4 steam-cracking cut a C5 steam-cracking cut or a steam-cracking gasoline, in such a way as to obtain a partially hydrogenated effluent.

11. A process according to claim 10 , wherein at least a part of the partially hydrogenated effluent is used as a non-polar solvent in process of preparation of the selective hydrogenation catalyst.

Assignees

• Ifp Energies Now

Inventors

• Dubreuil Anne-Claire
• Marques Mota Filipe Manuel
• Janvier Josselin

Classifications

• B01J37/0201

  Impregnation · CPC title

• C07C5/05 Primary

  Partial hydrogenation · CPC title

• B01J2231/645

  of C=C or C-C triple bonds · CPC title

• C10G9/36

  with heated gases or vapours · CPC title

• B01J37/20

  Sulfiding · CPC title