Production of aromatics from di- and polyoxygenates

Patent metadata

Field	Value
Publication number	US-9695094-B2
Application number	US-201615217715-A
Country	US
Kind code	B2
Filing date	Jul 22, 2016
Priority date	Mar 14, 2013
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

Methods, catalysts, and reactor systems for producing in high yield aromatic chemicals and liquid fuels from a mixture of oxygenates comprising di- and polyoxygenates are disclosed. Also disclosed are methods, catalysts, and reactor systems for producing aromatic chemicals and liquid fuels from oxygenated hydrocarbons such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like; and methods, catalysts, and reactor systems for producing the mixture of oxygenates from oxygenated hydrocarbons such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like. The disclosed catalysts for preparing the mixture of oxygenates comprise a Ni n Sn m alloy and a crystalline alumina support.

First claim

The invention claimed is:

1. A method for producing oxygenated compounds from oxygenated hydrocarbons, the method comprising:
reacting an aqueous feedstock, the aqueous feedstock comprising water and one or more oxygenated hydrocarbons selected from the group consisting of, monosaccharides, disaccharides, oligosaccharides, polysaccharides, sugar alcohols, sugar degradation products, alditols, starches, organic acids, polyols, and mixtures thereof, with hydrogen in the presence of a catalyst comprising a metal selected from the group consisting of Ni and Pd, at least one metal selected from the group consisting of Mo and Sn, and a support, to produce a mixture of oxygenates,
wherein the H:Ceff ratio of the mixture of oxygenates is greater than or equal to 0.5 and less than or equal to 1.7.

2. The method of claim 1 , wherein the mixture of oxygenates has one or more attributes selected from the group consisting of (i) a % CF ratio greater than or equal to 0.5 of dioxygenates and polyoxygenates to monooxygenates, (ii) a % CF ratio greater than or equal to 0.5 of dioxygenates to monooxygenates, (iii) a % CF ratio greater than or equal to 1.0 of C2-4 oxygenates to C5-6 oxygenates, and (iv) the mixture of oxygenates further comprising alkanes and less than or equal to 10% CF alkanes.

3. A method for producing hydrocarbons, the method comprising:
(a) reacting an aqueous feedstock, the aqueous feedstock comprising water and one or more oxygenated hydrocarbons selected from the group consisting of monosaccharides, disaccharides, oligosaccharides, polysaccharides, sugar alcohols, sugar degradation products, alditols, starches, organic acids, polyols, and mixtures thereof, with hydrogen in the presence of a catalyst comprising a metal selected from the group consisting of Ni and Pd, at least one metal selected from the group consisting of Mo and Sn, and a support, to produce a mixture of oxygenates and
(b) reacting the mixture of oxygenates with a condensation catalyst to produce a mixture of hydrocarbons comprising C4+ alkanes and aryls,
wherein the mixture of hydrocarbons comprises greater than or equal to 50% CF aryls and less than or equal to 20% CF C4+ alkanes.

4. The method of claim 3 , wherein the H:Ceff ratio of the mixture of oxygenates is greater than or equal to 0.5 and less than or equal to 1.7.

5. The method of claim 3 , wherein the mixture of oxygenates has one or more attributes selected from the group consisting of (i) a % CF ratio greater than or equal to 0.5 of dioxygenates and polyoxygenates to monooxygenates, (ii) a % CF ratio greater than or equal to 0.5 of dioxygenates to monooxygenates, (iii) a % CF ratio greater than or equal to 1.0 of C2-4 oxygenates to C5-6 oxygenates, and (iv) the mixture of oxygenates further comprising alkanes and less than or equal to 10% CF alkanes.

6. The method of claim 1 , wherein the catalyst comprises Pd, Mo, and Sn on a crystalline alumina support.

7. The method of claim 1 , wherein the catalyst comprises a Ni and Sn and a crystalline alumina support.

8. The method of claim 1 , wherein the support is a transitional alumina support.

9. The method of claim 8 , wherein the support is a theta-alumina support.

10. The method of claim 3 , wherein the catalyst comprises Pd, Mo, and Sn on a crystalline alumina support.

11. The method of claim 3 , wherein the catalyst comprises a Ni and Sn and a crystalline alumina support.

12. The method of claim 3 , wherein the support is a transitional alumina support.

13. The method of claim 12 , wherein the support is a theta-alumina support.

Assignees

• Virent Inc

Inventors

• Beck Taylor
• Blank Brian
• Jones Casey
• Woods Elizabeth
• Cortright Randy

Classifications

• B01J23/14 Primary

  of germanium, tin or lead · CPC title

• B01J38/02

  Heat treatment · CPC title

• C10G3/50 Primary

  in the presence of hydrogen, hydrogen donors or hydrogen generating compounds · CPC title

• B01J23/755

  Nickel · CPC title

• B01J23/6527

  Tungsten · CPC title