Method and device for treating wastewater containing tetramethylammonium hydroxide and ammonium nitrogen
US-2015076060-A1 · Mar 19, 2015 · US
US9695075B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9695075-B2 |
| Application number | US-201514667150-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 24, 2015 |
| Priority date | Jan 15, 2015 |
| Publication date | Jul 4, 2017 |
| Grant date | Jul 4, 2017 |
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A fluidized bed reactor for ammonia laden wastewater includes a column, a plurality of carrier particles, a first settling tank and a fluidizing means. The column defines a fluidizing chamber therein, and the fluidizing means is adapted for introducing the ammonia laden wastewater into the fluidizing chamber and further into the first settling tank. The reactor is further provided with microorganisms including nitrifying bacteria, anammox bacteria and heterotrophic denitrifying bacteria attached to the carrier particles. Nitrification reaction, anammox reaction and heterotrophic denitrification reaction are simultaneously taking place in the fluidizing chamber to transform ammonia into nitrogen by the microorganisms. A method for treating ammonia laden wastewater is also provided. The fluidized bed reactor is advantageous in the fact that its start-up is significantly shortened and it is adapted to efficiently treat thin ammonia laden wastewater.
Opening claim text (preview).
What is claimed is: 1. A fluidized bed reactor for ammonia laden wastewater, comprising: a column, defining a fluidizing chamber therein, the column having an upper opening and a lower opening, the upper and lower openings being in communication with the fluidizing chamber, respectively; a plurality of carrier particles, partially filled in the fluidizing chamber; a first settling tank, having a bottom opening and a first outlet located at a position higher than the bottom opening, the bottom opening being in communication with the upper opening of the column; a fluidizing means for introducing the ammonia laden wastewater into the fluidizing chamber via the lower opening, and for further fluidizing the carrier particles within the fluidizing chamber, the ammonia laden wastewater so introduced further having COD; and microorganisms, comprising nitrifying bacteria, anammox bacteria and heterotrophic denitrifying bacteria, at least a part of the microorganisms being attached to the carrier particles, the nitrifying bacteria being adapted to perform nitrification reaction and transform ammonia into nitrite, the anammox bacteria being adapted to perform anammox reaction and transform ammonia and nitrite into nitrogen gas and nitrate, the heterotrophic denitrifying bacteria being adapted to perform heterotrophic denitrification reaction and transform nitrate and COD into nitrogen gas, wherein the first settling tank is disposed atop the column. 2. The fluidized bed reactor of claim 1 , wherein a concentration of dissolved oxygen within the fluidizing chamber is 0.1-0.5 mg/L. 3. The fluidized bed reactor of claim 1 , wherein the first settling tank has a top portion formed with a gas outlet. 4. The fluidized bed reactor of claim 1 , further comprising a second settling tank, the second settling tank having an inlet and a second outlet, the inlet being in communication with the first outlet of the first settling tank. 5. A method for treating ammonia laden wastewater applying the fluidized bed reactor of claim 1 , the nitrification reaction, the anammox reaction and the heterotrophic denitrification reaction being simultaneously taking place within the fluidizing chamber, the ammonia laden wastewater being introduced into the fluidizing chamber via the lower opening and then flowing through, in sequence, the upper opening, the bottom opening and the first outlet. 6. The method of claim 5 , wherein the concentration of dissolved oxygen within the fluidizing chamber is 0.1-0.5 mg/L. 7. The method of claim 5 , wherein the first settling tank has a top portion formed with a gas outlet. 8. The method of claim 5 , wherein the fluidized bed reactor further comprises a second settling tank, the second settling tank has an inlet and a second outlet, the inlet is in communication with the first outlet and the first settling tank, the ammonia laden wastewater further flows through, in sequence, the inlet and the second outlet after flowing through the first outlet. 9. The method of claim 5 , wherein a hydraulic retention time of the ammonia laden wastewater in the fluidizing chamber is 12-24 hours. 10. The method of claim 6 , wherein a concentration of the ammonia in the ammonia laden wastewater is 20-85 mg/L.
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