Thermoplastic elastomer composition and composite molded body

Patent metadata

Field	Value
Publication number	US-9694522-B2
Application number	US-66916808-A
Country	US
Kind code	B2
Filing date	Jul 16, 2008
Priority date	Jul 18, 2007
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

Disclosed are a thermoplastic elastomer composition and a composite molded body. Specifically disclosed is a thermoplastic elastomer composition containing the following component (A1), component (B1) and component (C1). Component (A1): 70-90% by weight of a propylene polymer unit (α1) obtained in a first step by polymerizing a monomer mainly composed of propylene, and an ethylene copolymer unit obtained in a second step by copolymerizing ethylene with propylene and/or an α-olefin having 4 or more carbon atoms Component (B1): an ethylene-propylene copolymer rubber having a Mooney viscosity (ML 1+4 , 125° C.) of 20-100 and a weight ratio between the monomer unit derived from ethylene and the monomer unit derived from propylene of from 30/70 to 75/25 Component (C1): an ethylene copolymer as a copolymer of ethylene and an α-olefin having 4 or more carbon atoms.

First claim

The invention claimed is:

1. A method for producing a composite molded body, the method comprising vibration welding to join together a molded body comprised of the following polypropylene resin (A2) and a molded body comprised of the following thermoplastic elastomer composition (B2):
(A2): a polypropylene resin having a flexural modulus of 1500 MPa or more and a melting peak temperature of 163° C. or more, as measured by a differential scanning calorimeter; and
(B2): a thermoplastic elastomer composition containing a polypropylene polymer (component (b1)) having a melting peak temperature 7° C. or less lower than that of the polypropylene resin (A2) and an ethylene-propylene copolymer rubber (component (b2)) having a weight ratio of the monomer unit derived from ethylene to the monomer unit derived from propylene of from 30/70 to 75/25 (provided that the total of the monomer unit derived from ethylene and the monomer unit derived from propylene in the component (b2) is 100% wt) and having a flexural modulus of 330 to 800 MPa,
wherein the thermoplastic elastomer composition (B2) further contains, as a component (b3), an ethylene copolymer of ethylene and α-olefin having 4 or more carbon atoms having a density of 0.860 to 0.870 g/cm 3 and a melt flow rate of 0.3 to about 1.3 g/10 min as measured at 190° C. under a load of 21.18 N,
wherein the thermoplastic elastomer composition (B2) contains 100 parts by weight of the component (b1), 46.15 to 100 parts by weight of the component (b2) per 100 parts by weight of the component (b1) and 5 to 90 parts by weight of the component (b3) per 100 parts by weight of the component (b1),
wherein the component (b1) is the polypropylene polymer comprised of 70 to 90% by weight of the following propylene polymer unit (α2) and 10 to 30% by weight of the following ethylene copolymer unit (β2) (provided that the total amount of the component (b1) is 100% by weight):
(α2): the propylene polymer unit obtained by polymerizing a monomer composed mainly of propylene in the first step; and
(β2): the ethylene copolymer unit obtained by copolymerizing ethylene with propylene and/or an α-olefin having 4 or more carbon atoms in the second step, wherein the content of the monomer unit derived from ethylene is 20 to 80% by weight, provided that the amount of the ethylene copolymer unit is 100% by weight, and
wherein a 20° C. xylene soluble portion (CXS portion) contained in the component (b1) has an intrinsic viscosity [η] of 3.0 to 8.0 as measured in tetralin at 135° C.

2. The method according to claim 1 , wherein the composite molded body is an automobile interior part.

Assignees

• Ohtani Kohsuke
• Ijichi Yasuhito
• Sumitomo Chemical Co

Inventors

• Ohtani Kohsuke
• Ijichi Yasuhito

Classifications

• B29L2031/3038

  Air bag covers · CPC title

• B29C66/114

  Single butt joints · CPC title

• B29C66/112

  Single lapped joints · CPC title

• B29C65/8223

  Peel tests · CPC title

• B29C65/8215

  Tensile tests · CPC title