Deposition and post-processing techniques for transparent conductive films

Patent metadata

Field	Value
Publication number	US-9694422-B2
Application number	US-201514593840-A
Country	US
Kind code	B2
Filing date	Jan 9, 2015
Priority date	Jan 14, 2011
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

In one embodiment, a method is provided for fabrication of a semitransparent conductive mesh. A first solution having conductive nanowires suspended therein and a second solution having nanoparticles suspended therein are sprayed toward a substrate, the spraying forming a mist. The mist is processed, while on the substrate, to provide a semitransparent conductive material in the form of a mesh having the conductive nanowires and nanoparticles. The nanoparticles are configured and arranged to direct light passing through the mesh. Connections between the nanowires provide conductivity through the mesh.

First claim

What is claimed is:

1. An apparatus, comprising
a substrate;
a layer of one or more photovoltaic cells formed on the substrate; and
a semitransparent conductive film formed on the layer of the one or more photovoltaic cells, the semitransparent conductive film having a mesh of conductive nanowires and nanoparticles pseudo-randomly oriented on the surface of the layer, the nanoparticles arranged throughout the mesh of conductive nanowires at a concentration to cause light scattering through the mesh and wherein connections between the conductive nanowires provide conductivity through the semitransparent conductive film.

2. The apparatus of claim 1 , wherein the conductive nanowires are silver.

3. The apparatus of claim 1 , wherein the nanoparticles are zinc oxide.

4. The apparatus of claim 1 , wherein the photovoltaic cells are organic.

5. The apparatus of claim 1 , wherein the conductive nanowires are joined at points at which the nanowires cross.

6. The apparatus of claim 1 , wherein a portion of the semitransparent conductive film includes silver spheres that are electrically disconnected, and does not include conductive nanowires.

7. The apparatus of claim 1 , wherein the nanoparticles are distributed throughout the mesh and are further configured to scatter light at wavelength ranges that are particular to a material forming the nanoparticles.

8. The apparatus of claim 1 , wherein the conductive nanowires form the mesh with the nanoparticles distributed throughout the mesh and are configured to provide conductivity at the connections between the conductive nanowires and allow light to pass through areas of the mesh between the conductive nanowires.

9. The apparatus of claim 1 , wherein the nanoparticles scatter light of an infrared and/or near-infrared wavelength range through the semitransparent conductive film.

10. An apparatus, comprising
a substrate;
a layer of one or more photovoltaic cells formed on the substrate; and
a semitransparent conductive film formed on the layer of the one or more photovoltaic cells, the semitransparent conductive film having a mesh of conductive nanowires oriented on the surface of the layer and having nanoparticles pseudo-randomly oriented throughout the mesh, the nanoparticles configured to scatter light of a wavelength range that is particular to a material forming the nanoparticles, and wherein connections between the conductive nanowires provide conductivity through the semitransparent conductive film.

11. The apparatus of claim 10 , wherein the conductive nanowires are silver and the nanoparticles are zinc oxide.

12. The apparatus of claim 10 , wherein a first portion of the semitransparent conductive film includes the conductive nanowires, and a second portion of the semitransparent conductive film includes silver spheres that are electrically disconnected, and does not include conductive nanowires.

13. The apparatus of claim 10 , wherein the conductivity through the semitransparent conductive film is set by an overlap of the conductive nanowires and light scatter is set by the nanoparticles distributed throughout the mesh.

14. The apparatus of claim 10 , wherein the nanoparticles are configured to scatter the particular wavelength range to increase a path length of sub-band gap photons in the layer of the one or more photovoltaic cells.

15. The apparatus of claim 10 , wherein the semitransparent conductive film has a sheet resistance of less than 100 Ω/sq.

16. The apparatus of claim 1 , wherein the semitransparent conductive film has a sheet resistance of less than 5 Ω/sq.

17. The apparatus of claim 1 , wherein the semitransparent conductive film has a transmission of greater than 90 percent.

18. The apparatus of claim 1 , wherein the nanoparticles are distributed throughout the mesh of conductive nanowires at a concentration to provide a haze factor at infrared and/or near-infrared wavelengths of greater than 30 percent.

19. The apparatus of claim 1 , wherein the semitransparent conductive film has at least two of: a sheet resistance of less than 5 Ω/sq, a transmission of greater than 90 percent, and a haze factor at infrared and/or near-infrared wavelengths of greater than 30 percent.

20. The apparatus of claim 1 , wherein the semitransparent conductive film has a sheet resistance of less than 5 Ω/sq, a transmission of greater than 90 percent, and a haze factor at infrared and/or near-infrared wavelengths of greater than 30 percent.

Assignees

• Univ Leland Stanford Junior

Inventors

• Christoforo Mark Greyson
• Mehra Saahil
• Salleo Alberto
• Peumans Peter

Classifications

• B22F1/0547

  Nanofibres or nanotubes · CPC title

• B22F1/10

  Metallic powder containing lubricating or binding agents; Metallic powder containing organic material · CPC title

• H01L51/5268

  Electricity · mapped topic

• B22F7/004

  comprising at least one non-porous part · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title