Organic electrolyte solution and redox flow battery including the same

Patent metadata

Field	Value
Publication number	US-9692061-B2
Application number	US-201313888476-A
Country	US
Kind code	B2
Filing date	May 7, 2013
Priority date	Oct 4, 2012
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

An organic electrolyte solution including a metal-ligand coordination compound, wherein the ligand is an organic phosphate compound.

First claim

What is claimed is:

1. A redox flow battery comprising:
a cathode cell comprising a cathode and a catholyte;
an anode cell comprising an anode and an anolyte; and
an ion exchange membrane disposed between the cathode cell and the anode cell
wherein at least one of the catholyte and the anolyte is an organic electrolyte solution, the organic electrolyte solution comprising:
a metal-ligand coordination compound,
wherein the metal-ligand coordination compound includes a metal and an organic phosphate compound as a ligand,
wherein the metal-ligand coordination compound is prepared by heating a hydrated metal salt in the organic phosphate compound, and
wherein the metal-ligand coordination compound is in a hydrated form, and an amount of water in the metal-ligand coordination compound is greater than one equivalent based on the metal or is equal to an amount of water in the hydrated metal salt, and
wherein the organic phosphate compound is a compound of Formula 1:

wherein R 1 , R 2 , and R 3 are each independently selected from a C 1 -C 8 alkyl group, a C 2 -C 8 alkenyl group, a C 2 -C 8 alkynyl group, a C 3 -C 8 cycloalkyl group, a C 5 -C 12 aryl group, a C 6 -C 12 arylalkyl group, and a C 2 -C 8 acyl group.

2. The redox flow battery of claim 1 , wherein the metal is one selected from the group consisting of nickel, cobalt, iron, ruthenium, zinc, manganese, yttrium, zirconium, titanium, chromium, magnesium, cerium, copper, lead, and vanadium.

3. The redox flow battery of claim 1 , wherein the organic phosphate compound is trimethylphosphate, triethylphosphate, tri-n-propylphosphate, tri-iso-propylphosphate, tri-n-butylphosphate, tri-iso-butylphosphate, tri-tert-butylphosphate, triallylphosphate, tribenzylphosphate, or triphenylphosphate.

4. The redox flow battery of claim 1 , wherein 3 to 6 equivalents of the ligand are bound to the metal in the metal-ligand coordination compound.

5. The redox flow battery of claim 1 , wherein an oxidation-reduction reaction of the metal-ligand coordination compound is reversible.

6. The redox flow battery of claim 1 , wherein the metal-ligand coordination compound is selected from the group consisting of the compounds below:

7. The redox flow battery of claim 1 further comprising BF 4 − , PF 6 − , ClO 4 − , CF 3 SO 3 − , or (CF 3 SO 2 ) 2 N − as a counter anion of the metal-ligand coordination compound.

8. The redox flow battery of claim 7 , wherein the metal-ligand coordination compound is an ionic liquid.

9. The redox flow battery of claim 1 , wherein the metal-ligand coordination compound is dissolved in a solvent.

10. The redox flow battery of claim 9 , wherein the solvent is a non-aqueous solvent.

11. The redox flow battery of claim 10 , wherein the non-aqueous solvent is at least one selected from the group consisting of diethyl carbonate, dimethyl carbonate, dipropyl carbonate, acetonitrile, γ-butyrolactone, propylene carbonate, ethylene carbonate, butylene carbonate, N-methyl-2-pyrrolidone, fluoroethylene carbonate, N,N-dimethylformamide, dimethylsulfoxide, dichloromethane, chloroform, benzene, toluene, xylene, chlorobenzene, methyl acetate, ethyl acetate, acetone, methyl ethyl ketone, cyclohexanone, diethyl ether, 1,2-dimethoxyethane, tetrahydrofuran, 1,4-dioxane, methanol, ethanol, and N,N-dimethylacetamide.

12. The redox flow battery of claim 1 further comprising a supporting electrolyte.

13. The redox flow battery of claim 12 , wherein the supporting electrolyte is at least one selected from the group consisting of LiBF 4 , LiPF 6 , LiSbF 6 , LiAsF 6 , LiClO 4 , LiCF 3 SO 3 , Li(CF 3 SO 2 ) 2 N, LiC 4 F 9 SO 3 , LiAlO 2 , LiAlCl 4 , LiN(C x F 2x+1 SO 2 )(C y F 2y+1 SO 2 ), NaBF 4 , NaPF 6 , Na 2 SO 4 , TEAPF 6 , TBAPF 6 , TEABF 4 , and TBABF 4 ,
wherein x and y are natural numbers.

14. The redox flow battery of claim 1 , wherein the catholyte and the anolyte comprise a redox couple of Fe 2+ /Ni 0 .

15. The redox flow battery of claim 1 further comprising a catholyte tank and an anolyte tank respectively connected to the cathode cell and the anode cell to transfer a fluid.

16. The redox flow battery of claim 1 , wherein the ion exchange membrane is an anion exchange membrane.

Assignees

• Samsung Electronics Co Ltd
• Univ Seoul Nat R & Db Found

Inventors

• Oh Duk-Jin
• Mun Jun-Young
• Lee Doo-Yeon
• Kwon Oh-Min
• Kim Young-Gyu
• Kim Hyung-Tae

Classifications

• H01M8/02 Primary

  Details (electrodes H01M4/86 - H01M4/98) · CPC title

• H01M8/188 Primary

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M8/20

  Indirect fuel cells, e.g. fuel cells with redox couple being irreversible (H01M8/18 takes precedence) · CPC title

• H01M2300/0025

  Organic electrolyte · CPC title

• Y02E60/528

  Cross-Sectional Technologies · mapped topic