Anode containing composite anode active material including water-soluble polymer coating and lithium secondary battery including the same

Patent metadata

Field	Value
Publication number	US-9692049-B2
Application number	US-201314080033-A
Country	US
Kind code	B2
Filing date	Nov 14, 2013
Priority date	Feb 26, 2013
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

An anode for a lithium secondary battery including: a composite anode active material including an anode active material, and a water-soluble polymer disposed on a surface of the anode active material; and a binder disposed on the composite anode active material, the binder including one or more selected from a polyimide, a polyamideimide, a polyamide, and a polyetherimide.

First claim

What is claimed is:

1. An anode for a lithium secondary battery comprising:
a composite anode active material comprising
an anode active material including a metal-carbon composite consisting of a plurality of metal particles and a carbon material, wherein the carbon material is one or more selected from carbon nanotubes, natural graphite, artificial graphite, carbon fibers, spherical carbon, or graphene, and
a water-soluble polymer disposed on an outer surface of the metal-carbon composite; and

a binder disposed on the composite anode active material, the binder comprising one or more selected from a polyimide, a polyamideimide, a polyamide, and a polyetherimide,
wherein the water-soluble polymer comprises one or more selected from carboxymethyl cellulose, a carboxymethyl cellulose salt, methyl cellulose, hydroxymethyl cellulose, hydroxypropyl cellulose, ethyl cellulose, polyvinyl alcohol, polyacrylic acid substituted with an alkaline earth metal cation, polyacrylic acid substituted with an alkali metal cation, polyacrylic acid substituted with an ammonium ion, a poly(alkylene-maleic anhydride) copolymer, a poly(alkylene-maleic acid) copolymer salt, polyethylene oxide, alginic acid, hyaluronic acid, a pectic acid salt, a hyaluronic acid salt, and an alginic acid salt, and
wherein the water-soluble polymer is present in an amount ranging from about 3.6 weight percent to about 20 weight percent, based on a total weight of the composite anode active material.

2. The anode for a lithium secondary battery of claim 1 , wherein the binder is included in an amount ranging from about 5 weight percent to about 30 weight percent, based on a total weight of the anode.

3. The anode for a lithium secondary battery of claim 1 , wherein the binder is one or more selected from a polyamideimide, a polyamide, and a polyimide.

4. The anode for a lithium secondary battery of claim 1 , wherein the water-soluble polymer is included in an amount ranging from about 3.6 weight percent to about 10 weight percent, based on a total weight of the composite anode active material.

5. The anode for a lithium secondary battery of claim 1 , wherein the metal particles comprise one or more metals selected from silicon (Si), tin (Sn), aluminum (Al), germanium (Ge), lead (Pb), zinc (Zn), silver (Ag), and gold (Au), and an alloy thereof.

6. The anode for a lithium secondary battery of claim 5 , wherein the metal particles comprise one or more selected from silicon, silicon oxide, a silicon alloy, tin, a tin alloy, germanium, and a germanium alloy.

7. The anode for a lithium secondary battery of claim 1 , further comprising a metal oxide material disposed on a surface of the anode active material.

8. The anode for a lithium secondary battery of claim 7 , wherein the metal oxide material is one or more selected from lithium titanium oxide, aluminum oxide, silicon oxide, titanium oxide, and zinc oxide.

9. The anode for a lithium secondary battery of claim 1 , wherein
the carboxymethyl cellulose salt is a carboxymethyl cellulose sodium salt or a carboxymethyl cellulose ammonium salt,
the polyacrylic acid substituted with an alkali cation is a polyacrylic acid lithium salt,
the poly(alkylene-maleic anhydride) copolymer salt is a poly(isobutylene-maleic anhydride) copolymer lithium salt or a poly(isobutylene-maleic anhydride) copolymer ammonium salt, and
the alginic acid salt is sodium alginate.

10. The anode for a lithium secondary battery of claim 9 , wherein the binder is a polyamideimide.

11. The anode for a lithium secondary battery of claim 9 , wherein the water-soluble polymer comprises a carboxymethyl cellulose salt.

12. The anode for a lithium secondary battery of claim 9 , wherein the water-soluble polymer comprises polyacrylic acid substituted with an alkali metal cation.

13. The anode for a lithium secondary battery of claim 9 , wherein the water-soluble polymer comprises polyvinyl alcohol.

14. The anode for a lithium secondary battery of claim 9 , wherein the water-soluble polymer comprises an alginic acid salt.

15. A lithium secondary battery comprising:
a cathode;
the anode of claim 1 ;
a separator disposed between the cathode and the anode; and
an electrolyte.

16. A method of preparing an anode for a lithium secondary battery, the method comprising:
contacting an anode active material including a metal-carbon composite, a water-soluble polymer, and water to prepare a mixture;
drying the mixture to prepare a composite anode active material;
contacting the composite anode active material, a binder comprising one or more selected from a polyimide, a polyamideimide, a polyamide and a polyetherimide, and an organic solvent to prepare a slurry; and
disposing the slurry on a current collector to prepare the anode,
wherein the metal-carbon composite consists of a plurality of metal particles and a carbon material, wherein the carbon material is one or more selected from carbon nanotubes, natural graphite, artificial graphite, carbon fibers, spherical carbon, or graphene,
wherein the water-soluble polymer comprises one or more selected from carboxymethyl cellulose, a carboxymethyl cellulose salt, methyl cellulose, hydroxymethyl cellulose, hydroxypropyl cellulose, ethyl cellulose, polyvinyl alcohol, polyacrylic acid substituted with an alkaline earth metal cation, polyacrylic acid substituted with an alkali cation, polyacrylic acid substituted with an ammonium ion, a poly(alkylene-maleic anhydride) copolymer, a poly(alkylene-maleic acid) copolymer salt, polyethylene oxide, alginic acid, hyaluronic acid, a pectic acid salt, a hyaluronic acid salt, and an alginic acid salt,
wherein the water-soluble polymer is disposed on an outer surface of the metal-carbon composite, and
wherein the water-soluble polymer is present in an amount ranging from about 3.6 weight percent to about 20 weight percent, based on a total weight of the composite anode active material.

17. The method of claim 16 , wherein the binder is a polyamideimide.

18. The method of claim 16 , wherein the composite anode active material comprises a coating of the water-soluble polymer on the anode active material.

Assignees

• Samsung Electronics Co Ltd
• Samsung Sdi Co Ltd

Inventors

• Hwang Seung-Sik
• Ha Hyung-Wook
• Park Jin-Hwan
• Jung Hee-Chul

Classifications

• H01M4/1395

  of electrodes based on metals, Si or alloys · CPC title

• H01M4/622

  being polymers · CPC title

• H01M4/0404

  by coating on electrode collectors · CPC title

• H01M4/366 Primary

  as layered products · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title