Triarylamine derivative, electrophotographic photosensitive member, and image forming apparatus

Patent metadata

Field	Value
Publication number	US-9690217-B2
Application number	US-201514837298-A
Country	US
Kind code	B2
Filing date	Aug 27, 2015
Priority date	Aug 28, 2014
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

A triarylamine derivative is represented by general formula (I). In general formula (I), R 1 and R 2 each represent, independently of one another, a chemical group selected from the group consisting of a halogen atom, an optionally substituted alkyl group having a carbon number of 1-6, an optionally substituted alkoxy group having a carbon number of 1-6, and an optionally substituted aryl group having a carbon number of 6-12. In general formula (I), k and l each represent an integer of at least 0 and no greater than 4. When k and l represent integers greater than 1, chemical groups R 1 bonded to the same aromatic ring and chemical groups R 2 bonded to the same aromatic ring may be the same or different to one another. In general formula (I), m and n each represent a different integer of at least 1 and no greater than 3.

First claim

What is claimed is:

1. A triarylamine derivative represented by general formula (I)

where, in the general formula (I),
R 1 and R 2 each represent, independently of one another, a chemical group selected from the group consisting of a halogen atom, an optionally substituted alkyl group having a carbon number of at least 1 and no greater than 6, an optionally substituted alkoxy group having a carbon number of at least 1 and no greater than 6, and an optionally substituted aryl group having a carbon number of at least 6 and no greater than 12,
k represents 0 or 1,
l represents 0,
m and n each represent, independently of one another, an integer of at least 1 and no greater than 3,
m and n represent different integers to one another,
when k represents 0, m represents 1 and n represents 3, and
when k represents 1, n represents a larger integer than m.

2. An electrophotographic photosensitive member comprising
a photosensitive layer containing a charge generating material and a hole transport material, wherein
the photosensitive layer is either a multi-layer type photosensitive layer or a single-layer type photosensitive layer,
the multi-layer type photosensitive layer includes a charge generating layer that contains the charge generating material and a charge transport layer on the charge generating layer, the charge transport layer contains the hole transport material,
the single-layer type photosensitive layer contains the charge generating material and the hole transport material, and
the hole transport material is a triarylamine derivative represented by general formula (I)

where, in the general formula (I),
R 1 and R 2 each represent, independently of one another, a chemical group selected from the group consisting of a halogen atom, an optionally substituted alkyl group having a carbon number of at least 1 and no greater than 6, an optionally substituted alkoxy group having a carbon number of at least 1 and no greater than 6, and an optionally substituted aryl group having a carbon number of at least 6 and no greater than 12,
k and l each represent, independently of one another, an integer of at least 0 and no greater than 4,
when k represents an integer greater than 1, chemical groups R 1 bonded to the same aromatic ring may be the same or different to one another,
when l represents an integer greater than 1, chemical groups R 2 bonded to the same aromatic ring may be the same or different to one another,
m and n each represent, independently of one another, an integer of at least 1 and no greater than 3, and
m and n represent different integers to one another.

3. An image forming apparatus comprising;
an image bearing member;
a charging section configured to charge a surface of the image bearing member;
a light exposure section configured to form an electrostatic latent image on the surface of the image bearing member by exposing the surface of the image bearing member to light while in a charged state;
a developing section configured to develop the electrostatic latent image into a toner image; and
a transfer section configured to transfer the toner image onto a transfer target from the image bearing member, wherein
the image bearing member is the electrophotographic photosensitive member according to claim 2 .

4. The image forming apparatus according to claim 3 , wherein
the charging section applies a direct current voltage to the image bearing member while in contact with the image bearing member,
the charging section charges the surface of the image bearing member to a positive polarity, and
the photosensitive layer is the single-layer type photosensitive layer.

5. The image forming apparatus according to claim 3 , wherein
the transfer target is a recording medium, and
the image bearing member is in contact with the recording medium during transfer of the toner image onto the recording medium from the image bearing member by the transfer section.

6. The image forming apparatus according to claim 3 , wherein
the transfer section includes a primary transfer roller and a secondary transfer roller,
the transfer target is an intermediate transfer belt and a recording medium,
the primary transfer roller transfers the toner image onto the intermediate transfer belt from the image bearing member, and
the secondary transfer roller transfers the toner image onto the recording medium from the intermediate transfer belt.

7. The electrophotographic photosensitive member according to claim 2 , wherein
the photosensitive layer is a multi-layer type photosensitive layer,
the hole transport material contains a triarylamine derivative, and
the triarylamine derivative is represented by any one of chemical formulae (HT-1), (HT-2), (HT-3), and (HT-9):

8. The electrophotographic photosensitive member according to claim 2 , wherein
the photosensitive layer is a single-layer type photosensitive layer,
the hole transport material contains a triarylamine derivative, and
the triarylamine derivative is represented by any one of chemical formulae (HT-1), (HT-2), and (HT-9):

Assignees

• Kyocera Document Solutions Inc
• Kyocera Document Solutions Inc

Inventors

• Okada Hideki
• Sugai Fumio
• Kojima Kensuke
• Tsurumi Hiroki
• Yamamoto Yohei
• Miyamoto Eiichi

Classifications

• G03G5/04

  Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor · CPC title

• G03G5/0672 Primary

  containing two or more methine or polymethine groups · CPC title

• C07C217/80

  having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings · CPC title

• C07C211/54

  having amino groups bound to two or three six-membered aromatic rings · CPC title

• G03G5/0614 Primary

  Amines · CPC title