Negative-type photosensitive white composition for touch panel, touch panel and touch panel production method

Patent metadata

Field	Value
Publication number	US-9690197-B2
Application number	US-201414907137-A
Country	US
Kind code	B2
Filing date	Jul 18, 2014
Priority date	Jul 25, 2013
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

The present invention provides a negative-type photosensitive white composition for a touch panel, the composition including: (A) a white pigment; (B) an alkali-soluble resin; (C) a polyfunctional monomer; and (D) a photopolymerization initiator.

First claim

The invention claimed is:

1. A method for manufacturing a touch panel, comprising a step of forming a white light-shielding cured film pattern by using a negative-type photosensitive white composition for a touch panel comprising (A) a white pigment; (B) an alkali-soluble resin; (C) a polyfunctional monomer; and (D) a photopolymerization initiator, and (E) a thiol compound, wherein (E) the thiol compound is present in an amount ranging from 0.3 to 20 parts by mass with respect to 100 parts by mass of a total of (B) the alkali-soluble resin and (C) the polyfunctional monomer, wherein the step of forming a white light-shielding cured film pattern is repeated n times, and step of forming an nth layer (n is an integer of 2 or more) is a step of forming the nth layer whose line width is wider and thickness is smaller than those of a (n−1)th layer.

2. The method for manufacturing a touch panel according to claim 1 , wherein (b-1) a siloxane resin is contained as (B) the alkali-soluble resin.

3. The method for manufacturing a touch panel according to claim 1 , wherein (b-2) an acrylic resin is contained as (B) the alkali-soluble resin.

4. The method for manufacturing a touch panel according to claim 1 , comprising titanium oxide as (A) the white pigment.

5. The method for manufacturing a touch panel according to claim 1 , comprising, as (C) the polyfunctional monomer, a compound having a structure represented by the following general formula (1), and/or a compound having a structure represented by the following general formula (2):

wherein R 1 s each independently represent a hydrogen atom, a methyl group, an ethyl group, a propyl group or a phenyl group, and n represents an integer of 1 to 30,

6. The method for manufacturing a touch panel according to claim 1 , comprising an acylphosphine oxide-based photopolymerization initiator as (D) the photopolymerization initiator.

7. The method for manufacturing a touch panel-according to claim 1 , further comprising (F) an antioxidant.

8. The method for manufacturing a touch panel according to claim 1 , further comprising (G) a silane coupling agent represented by the following general formula (3):

wherein R 2 s each independently represent an alkyl group having 1 to 6 carbon atoms or a substituted group thereof, I represents 0 or 1, R 3 represents a trivalent organic group having 3 to 30 carbon atoms, and R 4 s each independently represent an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a phenyl group or a phenoxy group, or substituted groups thereof.

9. The method for manufacturing a touch panel according to claim 1 , further comprising (H) a ultraviolet absorber.

10. The method for manufacturing a touch panel according to claim 1 , further comprising (I) a coloring agent.

11. The method for manufacturing a touch panel according to claim 1 , comprising at least one step of forming the white light-shielding cured film pattern, and at least one step of forming a cured film by pattern-printing a non-photosensitive white composition.

12. The method for manufacturing a touch panel according to claim 1 , further comprising a step of forming a black light-shielding cured film above the white light-shielding cured film pattern.

13. The method for manufacturing a touch panel according to claim 1 , further comprising a step of forming a transparent film above the white light-shielding cured film pattern.

14. The method for manufacturing a touch panel according to claim 1 , further comprising a step of forming a color adjustment layer above the white light-shielding cured film pattern.

15. The method for manufacturing a touch panel according to claim 1 , further comprising a step of forming a color adjustment layer below the white light-shielding cured film pattern.

16. The method for manufacturing a touch panel according to claim 1 , wherein (E) the thiol compound is a polyfunctional thiol.

Assignees

• Toray Industries

Inventors

• Araki Hitoshi
• Suwa Mitsuhito
• Mitsui Hiroko
• Okazawa Toru

Classifications

• G03F7/027

  Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds (G03F7/075 takes precedence) · CPC title

• G03F7/0035

  Multiple processes, e.g. applying a further resist layer on an already in a previously step, processed pattern or textured surface · CPC title

• G03F7/033

  the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers · CPC title

• G03F7/0757 Primary

  Macromolecular compounds containing Si-O, Si-C or Si-N bonds (G03F7/0752 takes precedence) · CPC title

• G03F7/0755

  Non-macromolecular compounds containing Si-O, Si-C or Si-N bonds (G03F7/0752 takes precedence) · CPC title