Method and apparatus for measuring asphaltene onset conditions and yields of crude oils

Patent metadata

Field	Value
Publication number	US-9689858-B2
Application number	US-201514919504-A
Country	US
Kind code	B2
Filing date	Oct 21, 2015
Priority date	Oct 21, 2015
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

A method for determining an asphaltene onset condition of a crude oil is provided. The method includes receiving a crude oil within a downhole tool inside a well and taking a first measurement of an optical property of the received crude oil. The method also includes lowering the pressure or temperature of the crude oil after taking the first measurement of the optical property to cause aggregation of asphaltenes in the crude oil, and then separating aggregated asphaltenes from the crude oil. Further, the method includes taking a second measurement of the optical property of the crude oil within the downhole tool after separating aggregated asphaltenes from the crude oil and determining an asphaltene onset condition of the crude oil through comparison of the first and second measurements of the optical property. Additional methods, systems, and devices are also disclosed.

First claim

The invention claimed is:

1. A method comprising:
receiving a crude oil having an initial pressure and temperature within a downhole tool inside a well;
taking a first measurement of an optical density of the crude oil within the downhole tool;
causing aggregation of asphaltenes in the crude oil by lowering the pressure of the crude oil within the downhole tool after taking the first measurement of the optical property;
separating aggregated asphaltenes from the crude oil after lowering the pressure of the crude oil within the downhole tool, wherein separating aggregated asphaltenes from the crude oil includes routing the crude oil through a filter within the downhole tool to filter the aggregated asphaltenes from the crude oil;
taking a second measurement of the density of the crude oil within the downhole tool after separating aggregated asphaltenes from the crude oil;
determining an asphaltene onset condition of the crude oil through comparison of the first and second measurements of the optical property, wherein determining the asphaltene onset condition of the crude oil includes determining an asphaltene onset pressure of the crude oil;
determining asphaltene yield of the crude oil at the initial pressure through comparison of the optical density of the filtered crude oil at the initial pressure to the optical density of the crude oil in which asphaltenes have not been removed by the filter;
changing pressure of the received crude oil to a second pressure that causes aggregation of asphaltenes in the crude oil and is lower than the initial pressure of the crude oil received within the downhole tool;
passing the crude oil through a filter of the measurement apparatus, causing aggregated asphaltenes in the crude oil at the second pressure to be filtered from the crude oil; and
determining asphaltene yield of the crude oil at the second pressure.

2. The method of claim 1 , wherein the aggregation of asphaltenes in the crude oil is caused by lowering the pressure of the crude oil within the downhole tool after taking the first measurement of the optical property.

3. The method of claim 2 , wherein lowering the pressure of the crude oil within the downhole tool includes moving a piston to increase a volume of the crude oil within the downhole tool.

4. The method of claim 1 , comprising flushing the aggregated asphaltenes from the downhole tool using a solvent.

5. The method of claim 4 , wherein flushing the aggregated asphaltenes from the downhole tool using the solvent is performed while the downhole tool is within the well.

6. A method comprising:
receiving crude oil within a measurement apparatus;
changing pressure of the received crude oil within the measurement apparatus to a first pressure that causes aggregation of asphaltenes in the crude oil;
passing the crude oil through a filter of the measurement apparatus, causing aggregated asphaltenes in the crude oil to be filtered from the crude oil;
tracking the optical density of the crude oil after the crude oil has passed through the filter over different pressures, and
identifying an asphaltene onset pressure from the tracked optical density over the different pressures;
determining the asphaltene weight concentration within the crude oil at the first pressure through comparison of the optical density of the filtered crude oil at the first pressure to the optical density of the crude oil in which asphaltenes have not been removed by the filter;
changing pressure of the received crude oil to a second pressure that causes aggregation of asphaltenes in the crude oil;
passing the crude oil through a filter of the measurement apparatus, causing aggregated asphaltenes in the crude oil at the second pressure to be filtered from the crude oil; and
determining the asphaltene weight concentration within the crude oil at the second pressure.

7. The method of claim 6 , comprising measuring the optical density of the filtered crude oil at the first pressure and the optical density of the crude oil in which asphaltenes have not been removed by the filter with different spectrometers of the measurement apparatus that are on opposite sides of the filter.

8. The method of claim 6 , wherein tracking the optical density of the crude oil includes measuring the optical density of the crude oil with a spectrometer of a downhole tool that includes the measurement apparatus.

9. An apparatus comprising:
a downhole sampling tool including an intake configured to receive a formation fluid within the downhole sampling tool and a downhole fluid analysis module having a spectrometer and configured to enable measurement of an optical property of the received formation fluid, wherein the downhole fluid analysis module includes a filter that is configured to remove aggregated asphaltenes within the downhole sampling tool from the formation fluid;
a controller operable to:
cause aggregation of asphaltenes in the received formation fluid within the downhole sampling tool by lowering a pressure of the received formation fluid to a first pressure;
pass the crude oil through a filter of the downhole fluid analysis module, causing aggregated asphaltenes in the crude oil to be filtered from the formation fluid;
measure the optical density of the formation fluid after the formation fluid has passed through the filter over different pressures;
identify an asphaltene onset pressure from the measured optical density over the different pressures;
determine asphaltene content of the received formation fluid at the first pressure through comparison of the optical density of the filtered received formation fluid at the first pressure to the optical density of the formation fluid in which asphaltenes have not been removed by the filter;
change pressure of the received formation fluid to a second pressure that causes aggregation of asphaltenes in the formation fluid;
pass the formation fluid through a filter of the measurement apparatus, causing aggregated asphaltenes in the crude oil at the second pressure to be filtered from the crude oil; and
determine asphaltene content within the crude oil at the second pressure.

10. The apparatus of claim 9 , wherein the controller is operable to lower the pressure of the received formation fluid by increasing the volume of a region holding the received formation fluid.

11. The apparatus of claim 9 , wherein the controller is provided within the downhole sampling tool.

Assignees

• Schlumberger Technology Corp

Inventors

• Ratulowski John
• Molla Shahnawaz
• Sieben Vincent
• Mostowfi Farshid
• Taylor Shawn
• Harrison Christopher
• Fukagawa Shunsuke
• Smythe Elizabeth
• Sullivan Matthew
• Meier John

Classifications

• G01N33/2823 Primary

  Raw oil, drilling fluid or polyphasic mixtures · CPC title

• G01N33/2835

  Specific substances contained in the oils or fuels · CPC title

• G01V8/02

  Prospecting · CPC title

• G01N21/00

  Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light (G01N3/00 - G01N19/00 take precedence) · CPC title

• E21B49/10

  using side-wall fluid samplers or testers · CPC title