Boronated biopolymer crosslinking agents and methods relating thereto

Patent metadata

Field	Value
Publication number	US-9688906-B2
Application number	US-201414362605-A
Country	US
Kind code	B2
Filing date	Jan 23, 2014
Priority date	Jul 1, 2013
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

Boronated biopolymer crosslinking agents useful in producing viscosified treatment fluids that include an aqueous fluid, a base polymer, and the boronated biopolymer crosslinking agent, wherein the boronated biopolymer crosslinking agent comprises a biopolymer derivatized with a boronic acid, a boronate ester, or both. Such viscosified treatment fluids may be useful in fracturing operations, gravel packing operations, drilling operations, and the like.

First claim

The invention claimed is:

1. A method comprising:
introducing a viscosified treatment fluid into a wellbore penetrating a subterranean formation, the viscosified treatment fluid comprising an aqueous fluid, a base polymer, and a boronated biopolymer crosslinking agent,
wherein the boronated biopolymer crosslinking agent consists of a biopolymer derivatized with a boronic acid, a boronate ester, or both formed by reacting the biopolymer and the boronic acid, the boronate ester, or both in the presence of a coupling agent selected from the group consisting of N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride (EDC) and N,N′-dicyclohexylcarbodiimide (DCC),
wherein the biopolymer is selected from the group consisting of guar gum, oxidized guar, hydroxyethyl guar, hydroxypropyl guar, carboxymethyl guar, carboxymethylhydroxvethyl guar, carboxymethylhydroxypropyl guar, a cellulose, a cellulose derivative selected from hydroxyethyl cellulose, carboxyethylcellulose, carboxymethylcellulose, carboxymethylhydroxvethylcellulose, methyl cellulose, ethylcellulose, methylhydroxyethyl cellulose, xanthan, scleroglucan, succinoglycan, diutan, an alginate, a pectinate, chitosan, a hyaluronic acid, a polysaccharide, a polypeptide, and any combination thereof,
wherein the boronic acid or boronate ester is selected from the group consisting of bromopentyl boronic acid, chloromethylvinyl boronic acid, 4-cyanophenylboronic acid, esters with pinacol, formylphenyl boronic acids, carboxyphenyl boronic acids, bromomethyl boronic acid, alkoxycarbonyl boronic acids, formylphenyl boronic acid pinacol ester, and any combination thereof, and

wherein the boronated biopolymer crosslinking agent in the viscosified treatment fluid requires about 25% to about 50% lower base polymer concentration to produce the same viscosity as a viscosified treatment fluid comprising the same base polymer and sodium pentaborate crosslinking agent.

2. The method of claim 1 , wherein the base polymer a natural polymer selected from the group consisting of guar, a guar derivative, hydroxypropylguar, oxidized guar, carboxymethylhydroxypropylguar, carboxymethyl guar, hydrophobically modified guar derivative, locust bean gum, a locust bean gum derivative, fenugreek gum, a fenugreek gum derivative, tara gum, a tara gum derivative, and any combination thereof.

3. The method of claim 1 , wherein the base polymer comprises a synthetic polymer selected from the group consisting of a polyol, a polyvinyl alcohol, a polymer comprising a monomer having a 1,4 diol substitution, a polymer comprising a monomer having a 1,3 diol substitution, a polymer comprising a monomer having a 1,2 diol substitution, and any combination thereof.

4. The method of claim 1 , wherein the base polymer has a molecular weight of about 100,000 g/mol to about 5,000,000 g/mol.

5. The method of claim 1 , wherein the base polymer is at about 0.1% to about 10% by weight of the viscosified treatment fluid.

6. The method of claim 1 , wherein the boronated biopolymer crosslinking agent has a molecular weight of about 1,000 g/mol to about 5,000,000 g/mol.

7. The method of claim 1 , wherein the boronated biopolymer crosslinking agent has a boron weight percent of about 0.005% to about 0.05% by weight of the boronated biopolymer crosslinking agent.

8. The method of claim 1 , wherein the boronated biopolymer crosslinking agent and the base polymer are each at about 10 lb/gal in the viscosified treatment fluid.

9. The method of claim 1 , wherein the treatment fluid is an invert emulsion.

10. The method of claim 1 , wherein introducing is at a pressure sufficient to create or extend at least one fracture in the subterranean formation.

11. The method of claim 1 further comprising:
drilling at least a portion of the wellbore with the viscosified treatment fluid.

12. The method of claim 1 , wherein the viscosified treatment fluid further comprises a plurality of particulates; and the method further comprises forming a gravel pack comprising the particulates in an annulus within the wellbore.

13. The method of claim 1 further comprising:
breaking the viscosified treatment fluid so as to reduce the viscosity of the viscosified treatment fluid.

14. A method comprising:
introducing a first treatment fluid into a wellbore penetrating a subterranean formation at a pressure sufficient to create or extend at least one fracture in the subterranean formation; and
forming a particulate pack in the fracture with a second treatment fluid, the second treatment fluid comprising an aqueous fluid, a base polymer, a boronated biopolymer crosslinking agent, and a plurality of particulates,
wherein the boronated biopolymer crosslinking agent consists of a biopolymer derivatized with a boronic acid, a boronate ester, or both by reacting the biopolymer and the boronic acid, the boronate ester or both in the presence of a coupling agent selected from the group consisting of N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride (EDC) and N,N′-dicyclohexylcarbodiimide (DCC),
wherein the biopolymer is selected from the group consisting of guar gum, oxidized guar, hydroxyethyl guar, hydroxypropyl guar, carboxymethyl guar, carboxymethylhydroxvethyl guar, carboxymethylhydroxypropyl guar, a cellulose, a cellulose derivative selected from hydroxyethyl cellulose, carboxyethylcellulose, carboxymethylcellulose, carboxymethylhydroxvethylcellulose, methyl cellulose, ethylcellulose, methylhydroxyethyl cellulose, xanthan, scleroglucan, succinoglycan, diutan, an alginate, a pectinate, chitosan, a hyaluronic acid, a polysaccharide, a polypeptide, and any combination thereof,
wherein the boronic acid or boronate ester is selected from the group consisting of bromopentyl boronic acid, chloromethylvinyl boronic acid, 4-cyanophenylboronic acid, esters with pinacol, formylphenyl boronic acids, carboxyphenyl boronic acids, bromomethyl boronic acid, alkoxycarbonyl boronic acids, formylphenyl boronic acid pinacol ester, and any combination thereof, and

wherein the boronated biopolymer crosslinking agent in the viscosified treatment fluid requires about 25% to about 50% lower base polymer concentration to produce the same viscosity as a viscosified treatment fluid comprising the same base polymer and sodium pentaborate crosslinking agent.

15. The method of claim 14 further comprising:
breaking the second treatment fluid so as to reduce the viscosity of the second treatment fluid.

Assignees

• Halliburton Energy Services Inc
• Halliburton Energy Servics Inc

Inventors

• Singh Dipti
• Holtsclaw Jeremy
• Reddy B Raghava

Classifications

• C09K8/725

  Compositions containing polymers · CPC title

• E21B43/04

  Gravelling of wells · CPC title

• C09K8/887

  containing cross-linking agents · CPC title

• C09K8/90

  of natural origin, e.g. polysaccharides, cellulose · CPC title

• C09K8/685 Primary

  containing cross-linking agents · CPC title