Curable film-forming compositions and method of mitigating dirt build-up on a substrate

Patent metadata

Field	Value
Publication number	US-9688873-B2
Application number	US-201414326820-A
Country	US
Kind code	B2
Filing date	Jul 9, 2014
Priority date	Jul 9, 2014
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

The present invention is directed to curable film-forming compositions comprising acrylic polymers, and to coated substrates comprising the curable film-forming composition applied to at least one surface of the substrates. The acrylic polymers comprise epoxy functional groups and polydialkylsiloxane functional groups. The present invention is also drawn to methods of mitigating dirt build-up on a substrate, comprising applying to at least a portion of the substrate the curable film-forming composition described above and at least partially curing the curable film-forming composition.

First claim

Therefore, we claim:

1. A curable film-forming composition comprising:
(a) a film-forming polymer comprising reactive epoxy functional groups;
(b) a curing agent comprising acid functional groups reactive with the reactive functional groups in (a); and
(c) an acrylic polymer component comprising:
(i) epoxy functional groups; and
(ii) polydialkylsiloxane functional groups;

wherein the components (a), (b) and (c) are different from one another.

2. The composition of claim 1 , wherein the acrylic polymer component (c) comprises an acrylic polymer prepared from a reaction mixture comprising:
(i) an ethylenically unsaturated monomer comprising epoxy functional groups; and
(ii) an ethylenically unsaturated monomer comprising polydialkylsiloxane functional groups.

3. The composition of claim 1 , wherein the film-forming polymer (a) comprises an acrylic polymer.

4. The composition of claim 1 , wherein the curing agent (b) comprises an addition polymer, a polyether polymer, a polyester polymer, a polyester acrylate polymer, a polyurethane polymer, and/or a polyurethane acrylate polymer.

5. The composition of claim 2 , wherein the ethylenically unsaturated monomer (i) comprising epoxy functional groups comprises glycidyl acrylate, glycidyl methacrylate, allyl glycidyl ether, and/or methallyl glycidyl ether.

6. The composition of claim 2 , wherein the ethylenically unsaturated monomer (ii) comprising polydialkylsiloxane functional groups has a weight average molecular weight of 1000 to 30000.

7. The composition of claim 1 , wherein the acrylic polymer (c) is present in the curable film-forming composition in an amount ranging from 0.5 to 10 percent by weight, based on the total weight of resin solids in the curable film-forming composition.

8. A coated substrate comprising:
A) a substrate having at least one coatable surface, and
B) a curable film-forming composition applied to at least one surface of the substrate, wherein the-film-forming composition is prepared from the curable film-forming composition of claim 1 .

9. A method of mitigating dirt build-up on a substrate, comprising:
(1) applying to at least a portion of the substrate a curable film-forming composition comprising:
(a) a film-forming polymer comprising reactive epoxy functional groups;
(b) a curing agent comprising acid functional groups reactive with the reactive functional groups in (a); and
(c) an acrylic polymer component comprising:
(i) epoxy functional groups; and
(ii) polydialkylsiloxane functional groups;

wherein the components (a), (b) and (c) are different from one another; and
(2) at least partially curing the curable film-forming composition.

10. The method of claim 9 , wherein the film-forming polymer (a) comprises an acrylic polymer.

11. The method of claim 9 , wherein the curing agent (b) comprises an addition polymer, a polyether polymer, a polyester polymer, a polyester acrylate polymer, a polyurethane polymer, and/or a polyurethane acrylate polymer.

12. The method of claim 9 , wherein the acrylic polymer component (c) comprises an acrylic polymer prepared from a reaction mixture comprising:
(i) an ethylenically unsaturated monomer comprising epoxy functional groups; and
(ii) an ethylenically unsaturated monomer comprising polydialkylsiloxane functional groups.

13. The method of claim 12 , wherein the ethylenically unsaturated monomer (i) comprising epoxy functional groups comprises glycidyl acrylate, glycidyl methacrylate, allyl glycidyl ether, and/or methallyl glycidyl ether.

14. The method of claim 12 , wherein the ethylenically unsaturated monomer (ii) comprising polydialkylsiloxane functional groups has a weight average molecular weight of 1000 to 30000.

15. The method of claim 9 , wherein the acrylic polymer component (c) is present in the curable film-forming composition in an amount ranging from 0.5 to 10 percent by weight, based on the total weight of resin solids in the curable film-forming composition.

Assignees

• Ppg Ind Ohio Inc

Inventors

• Swarup Shanti
• Polk W David

Classifications

• C09D4/06

  {Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond} in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00 · CPC title

• B05D5/00

  Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures · CPC title

• C08F220/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08L33/14

  of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen · CPC title

• C09D133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title