Waterborne coating composition useful for promoting adhesion to plastic surfaces

Patent metadata

Field	Value
Publication number	US-9688872-B2
Application number	US-201313767609-A
Country	US
Kind code	B2
Filing date	Feb 14, 2013
Priority date	Feb 14, 2012
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

The waterborne coating composition herein is useful for promoting adhesion of paint to a component such as a plastic automobile part or accessory. The waterborne coating composition is particularly useful for promoting adhesion of paint to a thermoplastic polyolefin surface. The waterborne coating composition is prepared from a mixture comprising at least one chlorinated polyolefin resin and at least one urethane acrylic hybrid resin. The waterborne coating composition provides not only good adhesion of a paint to a thermoplastic polyolefin surface, but also provides good appearance. The waterborne coating composition is also compatible with a wide variety of paint systems and can be rapidly dried under ambient conditions.

First claim

What is claimed is:

1. A coating on a plastic surface wherein:
The coating formed from a waterborne coating composition prepared from a mixture consisting essentially of:
at least one chlorinated polyolefin resin in an amount effective to promote adhesion of the coating to a plastic surface,
at least one urethane acrylic hybrid resin in an amount effective to counteract tackiness of the chlorinated polyolefin resin and promote rapid drying of the coating,
at least one coalescent solvent,
at least one surfactant,
at least one of:
a clay,
a hydrophobically-modified ethoxylated urethane, or
a hydrophobically-modified alkali swellable emulsion;

at least one base,
at least one propanediol, and
water, and
wherein the chlorinated polyolefin resin is present in the mixture at about 35.0 to 45.0 wt % based on total dry resin solids content; and
wherein the urethane acrylic hybrid resin is present in the mixture at about 55.0-65.0 wt % based on total dry resin solids content.

2. The coating according to claim 1 wherein the coating:
has a thickness of from about 0.01 to about 2.5 mils.

3. A coated plastic component, comprising:
a plastic substrate having a surface;
an adhesion promoting coating disposed on the surface of the plastic substrate, the coating formed from a waterborne coating composition prepared from a mixture consisting essentially of:
at least one chlorinated polyolefin resin in an amount effective to promote adhesion of the coating to a plastic surface,
at least one urethane acrylic hybrid resin in an amount effective to counteract tackiness of the chlorinated polyolefin resin and promote rapid drying of the coating, and
at least one coalescent solvent;
at least one surfactant;
at least one of:
a clay,
a hydrophobically-modified ethoxylated urethane, or
a hydrophobically-modified alkali swellable emulsion;

at least one base;
at least one propanediol; and
water; and
wherein the chlorinated polyolefin resin is present in the mixture at about 35.0 to 45.0 wt % based on total dry resin solids content;
wherein the urethane acrylic hybrid resin is present in the mixture at about 55.0-65.0 wt % based on total dry resin solids content.

4. The coated plastic component according to claim 3 further comprising an automotive paint on the adhesion promoting coating, wherein the plastic substrate is a plastic automotive component.

5. The coated plastic component according to claim 4 wherein:
the plastic automotive component is a bumper, a door, a fender, a body panel, a side-panel, a hood, a trunk, or a roof;
the adhesion promoting coating is on an exterior surface thereof;
and the automotive paint is a waterborne automotive paint.

6. The coated plastic component according to claim 4 wherein the plastic automotive component is formed at least partially from a thermoplastic olefin.

7. The coated plastic surface according to claim 6 wherein the plastic automotive component is a bumper.

8. A method of painting a plastic automotive component, comprising:
applying, to at least a portion of a surface of a plastic automotive component, a waterborne coating composition to form an adhesion-promoting coating, the waterborne coating composition prepared from a mixture consisting essentially of:
at least one chlorinated polyolefin resin in an amount effective to promote adhesion of the coating to a plastic surface,
at least one urethane acrylic hybrid resin in an amount effective to counteract tackiness of the chlorinated polyolefin resin and promote rapid drying of the coating, and
at least one coalescent solvent;
at least one surfactant;
at least one of:
a clay,
a hydrophobically-modified ethoxylated urethane, or
a hydrophobically-modified alkali swellable emulsion;

at least one base;
at least one propanediol; and
water; and
wherein the chlorinated polyolefin resin is present in the mixture at about 35.0 to 45.0 wt % based on total dry resin solids content; and
wherein the urethane acrylic hybrid resin is present in the mixture at about 55.0-65.0 wt % based on total dry resin solids content; and

painting the coated surface of the plastic automotive component with an automotive paint.

9. The method according to claim 8 , further comprising:
cleaning at least a portion of the surface of the plastic automotive component to remove dust, debris and contaminants from the surface of the plastic automotive component; and
applying the waterborne coating composition on a cleaned portion of the surface.

10. The method according to claim 8 , further comprising drying the adhesion-promoting coating for about 20 minutes or less under ambient conditions prior to painting the coated surface with an automotive paint.

11. The method according to claim 8 , further comprising heating the adhesion-promoting coating for less than about 5 minutes.

12. The method according to claim 8 wherein applying the waterborne coating composition comprises spraying, brushing or rolling.

13. A method of making a waterborne coating composition for forming a coating that promotes adhesion of paint to plastic surfaces, comprising:
mixing:
at least one chlorinated polyolefin resin in an amount effective to promote adhesion of the coating to a plastic surface, and
at least one urethane acrylic hybrid resin in an amount effective to counteract tackiness of the chlorinated polyolefin resin and promote rapid drying of the coating
at least one coalescent solvent;
at least one surfactant;
at least one of:
a clay,
a hydrophobically-modified ethoxylated urethane, or
a hydrophobically-modified alkali swellable emulsion;

at least one base;
at least one propanediol; and
water; and
wherein the chlorinated polyolefin resin is present in the mixture at about 35.0 to 45.0 wt % based on total dry resin solids content;
wherein the urethane acrylic hybrid resin is present in the mixture at about 55.0-65.0 wt % based on total dry resin solids content.

14. A waterborne coating composition for forming a paint adhesion-promoting coating on a plastic surface, the waterborne coating composition prepared from a mixture consisting essentially of:
at least one chlorinated polyolefin resin in an amount effective to promote adhesion of the coating to a plastic surface;
at least one urethane acrylic hybrid resin in an amount effective to counteract tackiness of the chlorinated polyolefin resin and promote rapid drying of the coating;
at least one coalescent solvent;
at least one surfactant;
at least one of:
a clay,
a hydrophobically-modified ethoxylated urethane, or
a hydrophobically-modified alkali swellable emulsion;

at least one base;
at least one propanediol; and
water; and
wherein the chlorinated polyolefin resin is present in the mixture at about 35.0 to 45.0 wt % based on total dry resin solids content;
wherein the urethane acrylic hybrid resin is present in the mixture at about 55.0-65.0 wt % based on total dry resin solids content, and
wherein the coating formed by the waterborne coating composition is ready to have a paint layer applied thereon after drying for about 20 minutes or less under ambient conditions.

15. A waterborne coating composition for forming a paint adhesion-promoting coating on a plastic surface, the waterborne coating composition prepared from a mixture consisting essentially of:
at least one chlorinated polyolefin resin in an amount effective to promote adhesion of the coating to a plastic surface;
at least one urethane acrylic hybrid resin in an amount effective to counteract tackiness of the chlorinated polyolefin resin and promote

Assignees

• W M Barr & Company
• Wm Barr & Co Inc

Inventors

• Power John W
• Thompson Mark

Classifications

• Y10T428/31573

  Next to addition polymer of ethylenically unsaturated monomer · CPC title

• C09D5/002

  Priming paints (C09D5/08 takes precedence) · CPC title

• C09D123/28 Primary

  by reaction with halogens or compounds containing halogen (C09D123/32 takes precedence) · CPC title

• Y10T428/31551

  Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.] · CPC title

• Y10T428/264

  Up to 3 mils · CPC title