Antistatic non-crosslinked foamed polyethylene resin particles and molded non-crosslinked foamed polyethylene resin body

Patent metadata

Field	Value
Publication number	US-9688828-B2
Application number	US-201214232687-A
Country	US
Kind code	B2
Filing date	Jul 13, 2012
Priority date	Jul 15, 2011
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

Provided are non-crosslinked foamed polyethylene resin particles that have a bulk density BD of 10 g/L or more and 100 g/L or less and are obtained by foaming polyethylene resin particles containing an antistatic agent in an amount of 0.1 part by weight or more and 3 parts by weight or less with respect to 100 parts by weight of a polyethylene resin and having a density of 0.920 g/cm 3 or more and less than 0.940 g/cm 3 , and the non-crosslinked foamed polyethylene resin particles have a shrinkage ratio of 3% or more and 30% or less determined in accordance with Formula (1). The non-crosslinked foamed polyethylene resin particles can simply afford an antistatic molded non-crosslinked foamed polyethylene resin body that has a small shrinkage ratio with respect to mold dimension, is deformed in a small degree, and has good surface stretch.

First claim

The invention claimed is:

1. Non-crosslinked foamed polyethylene resin particles having a bulk density BD of 10 g/L or more and 100 g/L or less and obtained by foaming polyethylene resin particles, the polyethylene resin particles containing an antistatic agent in an amount of 0.1 part by weight or more and 3 parts by weight or less and a hydrophilic compound in an amount of 0.01 part by weight or more and 10 parts by weight or less respectively with respect to 100 parts by weight of a polyethylene resin and having a density of 0.920 g/cm 3 or more and less than 0.940 g/cm 3 ,
the non-crosslinked foamed polyethylene resin particles having a shrinkage ratio of 3% or more and 30% or less determined in accordance with Formula (1):
Shrinkage ratio=(BD− V BD)×100 /V BD  (1)

where BD is a bulk density of the non-crosslinked foamed polyethylene resin particles at 23° C. and 0.1 MPa (under standard atmospheric pressure), and VBD is a bulk density of the non-crosslinked foamed polyethylene resin particles at 23° C. under a reduced pressure of 0.002 MPa or less.

2. The non-crosslinked foamed polyethylene resin particles according to claim 1 , wherein the antistatic agent contains at least one compound selected from the group consisting of a glyceryl ester of a fatty acid having a carbon number of 6 or more and 24 or less and an aliphatic ethanolamine compound.

3. The non-crosslinked foamed polyethylene resin particles according to claim 1 , wherein the antistatic agent contains at least one compound selected from the group consisting of glyceryl stearate, hydroxyalkylethanolamine, stearyldiethanolamine monostearate, and stearyldiethanolamine.

4. The non-crosslinked foamed polyethylene resin particles according to claim 1 , wherein the hydrophilic compound contains at least one compound selected from the group consisting of glycerin, polyethylene glycol, and polypropylene glycol.

5. The non-crosslinked foamed polyethylene resin particles according to claim 4 , wherein at least one compound selected from the group consisting of glycerin, polyethylene glycol, and polypropylene glycol is contained in an amount of 0.5 part by weight or more and 2 parts by weight or less with respect to 100 parts by weight of the polyethylene resin.

6. The non-crosslinked foamed polyethylene resin particles according to claim 1 , wherein an inorganic gas is used as a foaming agent and the non-crosslinked foamed polyethylene resin particles have an average cell size of 200 □m or more and 700 □m or less.

7. A molded non-crosslinked foamed polyethylene resin body obtained by filling a mold with the non-crosslinked foamed polyethylene resin particles according to claim 1 and then in-mold foam molding the non-crosslinked foamed polyethylene resin particles.

8. A method for producing non-crosslinked foamed polyethylene resin particles according to claim 1 , the method comprising:
introducing polyethylene resin particles containing an antistatic agent in an amount of 0.1 part by weight or more and 3 parts by weight or less and a hydrophilic compound in an amount of 0.01 part by weight or more and 10 parts by weight or less respectively with respect to 100 parts by weight of a polyethylene resin and having a density of 0.920 g/cm 3 or more and less than 0.940 g/cm 3 into a pressure-resistant container together with water, a foaming agent, and a dispersant;
warming and pressurizing the mixture; then
discharging the polyethylene resin particles into an atmosphere at a lower pressure than that in the pressure-resistant container to afford non-crosslinked foamed polyethylene resin particles;
applying internal pressure to the non-crosslinked foamed polyethylene resin particles by at least one inorganic gas selected from air, nitrogen, and carbon dioxide; and then
heating the non-crosslinked foamed polyethylene resin particles with water vapor having a water vapor pressure of 0.045 MPa (gauge pressure) or more and 0.10 MPa (gauge pressure) or less to further foam the particles, thus producing non-crosslinked foamed polyethylene resin particles having a higher expansion ratio.

9. Non-crosslinked foamed polyethylene resin particles having a bulk density BD of 10 g/L or more and 100 g/L or less and obtainable by foaming polyethylene resin particles, the polyethylene resin particles containing an antistatic agent in an amount of 0.1 part by weight or more and 3 parts by weight or less with respect to 100 parts by weight of a polyethylene resin and having a density of 0.920 g/cm 3 or more and less than 0.940 g/cm 3 ,
the non-crosslinked foamed polyethylene resin particles having a shrinkage ratio of 3% or more and 30% or less determined in accordance with Formula (1):
Shrinkage ratio=(BD− V BD)×100 /V BD  (1)

where BD is a bulk density of the non-crosslinked foamed polyethylene resin particles at 23° C. and 0.1 MPa (under standard atmospheric pressure), and VBD is a bulk density of the non-crosslinked foamed polyethylene resin particles at 23° C. under a reduced pressure of 0.002 MPa or less,
the non-crosslinked foamed polyethylene resin particles being obtained by:
introducing the polyethylene resin particles containing the antistatic agent in an amount of 0.1 part by weight or more and 3 parts by weight or less with respect to 100 parts by weight of a polyethylene resin and having a density of 0.920 g/cm 3 or more and less than 0.940 g/cm 3 into a pressure-resistant container together with water, a foaming agent, and a dispersant;
warming and pressurizing the mixture; then
discharging the polyethylene resin particles into an atmosphere at a lower pressure than that in the pressure-resistant container to afford non-crosslinked foamed polyethylene resin particles;
applying internal pressure to the non-crosslinked foamed polyethylene resin particles by at least one inorganic gas selected from air, nitrogen, and carbon dioxide; and then
heating the non-crosslinked foamed polyethylene resin particles with water vapor having a water vapor pressure of 0.045 MPa (gauge pressure) or more and 0.10 MPa (gauge pressure) or less to further foam the particles, thus obtaining non-crosslinked foamed polyethylene resin particles having a higher expansion ratio.

10. Non-crosslinked foamed polyethylene resin particles having a bulk density BD of 10 g/L or more and 100 g/L or less and obtainable by foaming polyethylene resin particles, the polyethylene resin particles containing an antistatic agent in an amount of 0.1 part by weight or more and 3 parts by weight or less and a hydrophilic compound in an amount of 0.01 part by weight or more and 10 parts by weight or less respectively with respect to 100 parts by weight of a polyethylene resin and having a density of 0.920 g/cm 3 or more and less than 0.940 g/cm 3 ,
the non-crosslinked foamed polyethylene resin particles having a shrinkage ratio of 3% or more and 30% or less determined in accordance with Formula (1):
Shrinkage ratio=(BD− V BD)×100 /V BD  (1)

where BD is a bulk density of the non-crosslinked foamed polyethylene resin particles at 23° C. and 0.1 MPa (under standard atmospheric pressure), and VBD is a bulk density of the non-crosslinked foamed polyethylene resin particles at 23° C. under a reduced pressure of 0.002 MPa or less,
the non-crosslinked foamed polyethylene resin particles being obtained by:
introducing the polyethylene resin particles containing the antistatic agent in an amount of 0.1 part by weight or more and 3 parts by weight or less and a hydrophilic compound in an amount of 0.01 part by weight or more and 10 parts by weight or less respectively with respect to 100 parts by weight of a polyethylene resin and having a density of 0.920 g/cm 3 or more and less than 0

Assignees

• Nakayama Kiyotaka
• Kaneka Corp

Inventors

• Nakayama Kiyotaka

Classifications

• C08J2323/06

  Polyethene · CPC title

• C08J2201/034

  Post-expanding of foam beads or sheets · CPC title

• C08J9/0028

  containing nitrogen · CPC title

• C08J9/232

  by sintering expandable particles · CPC title

• C08J2203/06

  CO2, N2 or noble gases · CPC title