Biaxially stretched polyester film and method for producing same

Patent metadata

Field	Value
Publication number	US-9688826-B2
Application number	US-201314442769-A
Country	US
Kind code	B2
Filing date	Nov 8, 2013
Priority date	Nov 16, 2012
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

It is provided that a biaxially stretched polyester film suitable for uses for which nylon films and other flexible films have conventionally been used and a method for producing the film. A biaxially stretched polyester film made of a polyester resin composition (A) containing not less than 60 mass % of polybutylene terephthalate and having yield stress in a MD of not more than 70 MPa, yield stress in a TD of not more than 70 MPa, rupture strength in the MD of not less than 160 MPa, rupture strength in the TD of not less than 160 MPa, and rupture elongation in the MD and TD of not less than 100%.

First claim

The invention claimed is:

1. A biaxially stretched polyester film made of a polyester composition (A) containing not less than 60 mass % of a polybutylene terephthalate; wherein the biaxially stretched polyester film has a yield stress in a MD of not more than 70 MPa, yield stress in a TD of not more than 70 MPa, rupture strength in the MD of 160 MPa to 300 MPa, rupture strength in the TD of 160 MPa to 300 MPa, and rupture elongation in the MD and TD of 100% to 200%.

2. The biaxially stretched polyester film according to claim 1 , wherein the polyester resin (A) contains a polyester resin (B) other than polybutylene terephthalate.

3. A method for producing the biaxially stretched polyester film according to claim 2 , wherein the biaxially stretched polyester film is obtained by biaxially stretching an un-stretched polyester sheet with a thickness of 15 to 2500 μm which is obtained by multi-layering a same composition in not less than 60 layers and casting the layered body.

4. A method for producing the biaxially stretched polyester film according to claim 2 , obtained by bringing an un-stretched polyester sheet into contact with a chill roll at not more than 20° C. to cool the sheet and biaxially stretching the sheet.

5. A method for producing the biaxially stretched polyester film according to claim 2 , wherein the biaxially stretched polyester film is obtained by biaxially stretching an un-stretched polyester sheet containing spherulites with diameter of not more than 500 nm in the un-stretched polyester sheet.

6. The biaxially stretched polyester film according to claim 2 , having a ratio of the rupture strength in the MD and the rupture strength in the TD of not more than 1.5 and a ratio of the rupture elongation in the MD and the rupture elongation in the TD of not more than 1.5.

7. A method for producing the biaxially stretched polyester film according to claim 4 , wherein the biaxially stretched polyester film is obtained by sequentially biaxially stretching the un-stretched polyester sheet.

8. A method for producing the biaxially stretched polyester film according to claim 5 , wherein the biaxially stretched polyester film is obtained by sequentially biaxially stretching the un-stretched polyester sheet.

9. A method for producing the biaxially stretched polyester film according to claim 1 , wherein the biaxially stretched polyester film is obtained by biaxially stretching an un-stretched polyester sheet with a thickness of 15 to 2500 μm which is obtained by multi-layering a same composition in not less than 60 layers and casting the layered body.

10. A method for producing the biaxially stretched polyester film according to claim 1 , obtained by bringing an un-stretched polyester sheet into contact with a chill roll at not more than 20° C. to cool the sheet and biaxially stretching the sheet.

11. A method for producing the biaxially stretched polyester film according to claim 10 , wherein the biaxially stretched polyester film is obtained by sequentially biaxially stretching the un-stretched polyester sheet.

12. A method for producing the biaxially stretched polyester film according to claim 1 , wherein the biaxially stretched polyester film is obtained by biaxially stretching an un-stretched polyester sheet containing spherulites with diameter of not more than 500 nm in the un-stretched polyester sheet.

13. A method for producing the biaxially stretched polyester film according to claim 12 , wherein the biaxially stretched polyester film is obtained by sequentially biaxially stretching the un-stretched polyester sheet.

14. The biaxially stretched polyester film according to claim 1 , having a ratio of the rupture strength in the MD and the rupture strength in the TD of not more than 1.5 and a ratio of the rupture elongation in the MD and the rupture elongation in the TD of not more than 1.5.

Assignees

• Toyo Boseki

Inventors

• Gotou Takamichi
• Shimizu Toshiyuki
• Nakaya Tadashi
• Ikehata Yoshitomo

Classifications

• C08J2467/00

  Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers · CPC title

• B29K2995/0077

  Yield strength; Tensile strength · CPC title

• C08J2367/03

  the dicarboxylic acids and dihydroxy compounds having the hydroxy and the carboxyl groups directly linked to aromatic rings · CPC title

• B29C55/023

  using multilayered plates or sheets · CPC title

• B29K2995/0089

  Impact strength or toughness · CPC title