Functionalized polyoxymethylene block copolymers

Patent metadata

Field	Value
Publication number	US-9688814-B2
Application number	US-201314654725-A
Country	US
Kind code	B2
Filing date	Dec 18, 2013
Priority date	Dec 21, 2012
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

The invention relates to a method for producing functionalized polyoxymethylene block copolymers comprising the step of polymerizing formaldehyde in a reaction vessel in the presence of a catalyst, the polymerization of formaldehyde in addition taking place in the presence of a starter compound comprising at least 2 Zerewitinoff active H atoms, to obtain an intermediate product. The intermediate product obtained is subsequently reacted with a cyclic carboxylic acid ester or carbonic acid ester, thus obtaining a functionalized polyoxymethylene block copolymer. The invention further relates to functionalized polyoxymethylene block copolymers obtained by such a method and to the use of said copolymers.

First claim

The invention claimed is:

1. A process for preparing functionalized polyoxymethylene block copolymers, comprising the step of
polymerizing formaldehyde in a reaction vessel in the presence of a catalyst, wherein the polymerization of formaldehyde is effected in the presence of a starter compound having at least 2 Zerewitinoff-active hydrogen atoms, and wherein the polymerizing step produces an intermediate having a number-average molecular weight of <4500 g/mol, and
the intermediate is reacted with a cyclic carboxylic or carbonic ester, giving a functionalized polyoxymethylene block copolymer.

2. The process as claimed in claim 1 , wherein the catalyst is selected from the group consisting of basic catalysts, Lewis-acidic catalysts, and combinations thereof.

3. The process as claimed in claim 1 , wherein the reaction of the intermediate with the cyclic carboxylic or carbonic ester is conducted in the presence of a catalyst which is the same catalyst as in the preceding polymerization of formaldehyde.

4. The process as claimed in claim 1 , wherein the starter compound has a number-average molecular weight of ≧62 g/mol to ≦4470 g/mol.

5. The process as claimed in claim 4 , wherein the starter compound has a number-average molecular weight of ≧100 g/mol to ≦3000 g/mol.

6. The process as claimed in claim 1 , wherein the starter compound is selected from the group consisting of polyether polyols, polyester polyols, polyether ester polyols, polycarbonate polyols, polyacrylate polyols, and combinations thereof.

7. The process as claimed in claim 1 , wherein the cyclic carboxylic or carbonic ester is selected from the group consisting of aliphatic lactones, aromatic lactones, lactides, cyclic carbonates, cyclic anhydrides, and combinations thereof.

8. The process as claimed in claim 1 , wherein the formaldehyde is introduced into the reaction vessel as gaseous formaldehyde.

9. The process as claimed in claim 1 , wherein the polymerization is effected in the presence of a comonomer.

10. A functionalized polyoxymethylene block copolymer prepared by a process as claimed in claim 1 .

11. A functionalized polyoxymethylene block copolymer as claimed in claim 10 having a number-average molecular weight of ≦12 000 g/mol.

12. A functionalized polyoxymethylene block copolymer as claimed in claim 10 having a viscosity at 20° C. of ≦100 000 mPa s.

13. A composition comprising the functionalized polyoxymethylene block copolymer as claimed in claim 10 , wherein the composition is selected from the group consisting of polyamides, polyurethanes, washing and cleaning composition formulations, drilling fluids, fuel additives, ionic and nonionic surfactants, lubricants, process chemicals for papermaking or textile production, and cosmetic formulations.

Assignees

• Covestro Deutschland Ag

Inventors

• Müller Thomas Ernst
• Gürtler Christoph
• Leitner Walter
• Vogt Henning
• Barath Gabor

Classifications

• C08G2/38 Primary

  Block or graft polymers prepared by polymerisation of aldehydes or ketones on to macromolecular compounds · CPC title

• C08G18/4887

  containing carboxylic ester groups derived from carboxylic acids other than acids of higher fatty oils or other than resin acids · CPC title

• C08G18/4825

  Polyethers containing two hydroxy groups (C08G18/4833 - C08G18/5096 take precedence) · CPC title

• C08G18/48

  Polyethers · CPC title

• C08G18/4829

  Polyethers containing at least three hydroxy groups (C08G18/4833 - C08G18/5096 take precedence) · CPC title