Sequentially polymerized hybrid latex

Patent metadata

Field	Value
Publication number	US-9688800-B2
Application number	US-201414324826-A
Country	US
Kind code	B2
Filing date	Jul 7, 2014
Priority date	Jul 7, 2014
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

The present invention relates to a hybrid latex composition containing polymer particles that are polymerized in at least two stages including a first phase acrylic core polymer, and a second phase vinyl acrylic shell polymer including a monomer that is crosslinkable under ambient conditions. Paint compositions and architectural coatings containing the latex composition according to the invention are also described herein, as well as methods for making the same.

First claim

What is claimed is:

1. An aqueous latex composition comprising latex particles comprising a first phase polymer, and a second phase polymer, wherein
the first phase polymer is polymerized from a first set of monomers comprising at least about 95 wt. % of one or more acrylic monomers in the first phase polymer; and
the second phase polymer is polymerized from a second set of monomers comprising at least one acrylic monomer, at least one vinyl monomer and from about 0.5 wt. % to about 6 wt. % of a crosslinkable monomer in the second phase polymer;
wherein the second phase polymer comprises from about 50 wt. % to about 95 wt. % based on the total weight of the polymers in the latex particles; and
wherein the crosslinkable monomer is selected from the group consisting of diacetone acrylamide, diacetone methacrylamide and acetoacetoxyethyl methacrylate or a combination thereof, and
wherein the aqueous latex composition further comprises a cross-linking agent in an aqueous phase to crosslink with the crosslinkable monomer when water evaporates, and
wherein a total amount of vinyl monomer in the latex particles is greater than about 50 wt. % of the latex particles and a ratio of vinyl monomer to acrylic monomer in the latex particles is less than about 95:5.

2. The aqueous latex composition of claim 1 , wherein the first set of monomers further comprises about 1 wt. % to about 5 wt. % of the crosslinkable monomer in the first phase polymer.

3. The aqueous latex composition of claim 2 , wherein the crosslinkable monomer comprises diacetone acrylamide.

4. The aqueous latex composition of claim 1 , wherein the second set of monomers includes from about 1 wt. % to about 4 wt. % of the crosslinkable monomer in the second phase polymer.

5. The aqueous latex composition of claim 1 , wherein the cross-linking agent comprises adipic dihydrazide.

6. The aqueous latex composition of claim 1 , wherein the at least one vinyl monomer in the second set of monomers comprises vinyl acetate.

7. The aqueous latex composition of claim 6 , wherein the at least one acrylic monomer in the second set of monomers comprises butyl acrylate or 2-hexyl ethyl acetate.

8. The aqueous latex composition of claim 1 , wherein the second phase polymer comprises from about 60 wt. % to about 80 wt. % based on the total weight of the latex particles.

9. The latex aqueous composition of claim 1 , wherein the ratio of vinyl monomer to acrylic monomer in the latex particles ranges from about 60:40 to about 90:10.

10. The aqueous latex composition of claim 1 , wherein the ratio of vinyl monomer to acrylic monomer in the latex particles is less than about 90:10.

11. The aqueous latex composition of claim 1 , wherein the ratio of vinyl monomer to acrylic monomer in the latex particles is less than about 80:20.

12. The aqueous latex composition of claim 1 having a minimum film faulting temperature from about 4° C. to about 15° C.

13. The aqueous latex composition of claim 1 , wherein the first set of monomers further comprises a crosslinking monomer.

14. The aqueous latex composition of claim 13 , wherein the crosslinking monomer comprises 1,4-butanediol diacrylate.

15. A paint composition comprising the aqueous latex composition of claim 1 .

16. The aqueous latex composition of claim 1 , wherein the latex particles are sequentially polymerized latex particles.

17. The aqueous latex composition of claim 16 , wherein a volume average particle size of the sequentially polymerized latex particles ranges from about 120 nm to about 165 nm in diameter.

18. The aqueous latex composition of claim 16 , wherein the first phase polymer forms a core and the second phase polymer forms a shell.

19. The aqueous latex composition of claim 16 , wherein the first phase polymer forms a shell and the second phase polymer forms a core.

20. The aqueous latex composition of claim 16 , wherein the first phase polymer and the second phase polymer form side-by-side latex particles.

21. The aqueous latex composition of claim 8 , wherein the second phase polymer comprises from about 65 wt. % to about 75 wt. % based on the total weight of the latex particles.

22. The aqueous latex composition of claim 1 , wherein the total amount of vinyl monomer in the latex particles is greater than about 60 wt. % of the latex particles.

23. The aqueous latex composition of claim 1 , wherein the total amount of vinyl monomer in the latex particles is greater than about 70 wt. % of the latex particles.

Assignees

• Columbia Insurance Co

Inventors

• Sheerin Robert J
• Gharapetian Hrire
• Tilara Navin
• Hamilton Kimberly

Classifications

• C08F265/00 Primary

  Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 · CPC title

• C09D151/003

  grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds (C09D151/04, C09D151/06 take precedence) · CPC title

• C08F222/385

  Monomers containing two or more (meth)acrylamide groups, e.g. N,N'-methylenebisacrylamide · CPC title

• C08F265/06

  Polymerisation of acrylate or methacrylate esters on to polymers thereof · CPC title

• C08F2/22

  Emulsion polymerisation · CPC title