Method for carbon dioxide hydrogenation of syngas and the integration of the process with syngas conversion processes

Patent metadata

Field	Value
Publication number	US-9688593-B2
Application number	US-201415033255-A
Country	US
Kind code	B2
Filing date	Oct 29, 2014
Priority date	Oct 29, 2013
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

Techniques for synthesizing methanol are provided. In an exemplary embodiment, the processes include obtaining a syngas mixture from an integrated carbon dioxide hydrogenation process and a methane steam reforming process, and contacting the syngas mixture with a methanol catalyst to obtain a product stream comprising methanol.

First claim

The invention claimed is:

1. A process of synthesizing methanol, comprising:
obtaining a syngas mixture from an integrated carbon dioxide hydrogenation process and a methane steam reforming process, wherein the carbon dioxide hydrogenation process comprises contacting a gaseous feed mixture comprising carbon dioxide and hydrogen with a carbon dioxide hydrogenation catalyst; and the methane steam reforming process comprises contacting a desulphurised gaseous hydrocarbon feedstock and steam with a methane reforming catalyst; and
contacting the syngas mixture with a methanol catalyst to obtain a product stream comprising methanol.

2. The process of claim 1 , further comprising removing water from the syngas mixture prior to contacting the syngas mixture with the methanol catalyst.

3. The process of claim 1 , wherein the desulphurised gaseous hydrocarbon feedstock is a methane-rich feedstock comprising at least about 75 mol % of methane.

4. The process of claim 1 , wherein the desulphurised gaseous hydrocarbon feedstock is mixed with the steam at a steam/carbon ratio of from about 2.0 to about 3.5.

5. The process of claim 1 , wherein the desulphurised gaseous hydrocarbon feedstock mixed with the steam is fed to a gas heated reformer and a steam methane reformer operated in series.

6. The process of claim 1 , wherein the desulphurised gaseous hydrocarbon feedstock mixed with the steam is pre-heated to from about 500° C. to about 550° C. and then fed to the gas heated reformer.

7. The process of claim 1 , wherein the syngas mixture comprises carbon monoxide, carbon dioxide, and hydrogen.

8. The process of claim 1 , wherein the syngas mixture has a stoichiometric number of about 2.0.

9. The process of claim 1 , wherein the methane reforming catalyst comprises nickel.

10. The process of claim 1 , wherein the carbon dioxide hydrogenation process is carried out in a temperature of about 300° C. to about 900° C., at a pressure of about 0.1 mPa to about 5 MPa, and with a contact time of about 0.5 s to about 6 s.

11. The process of claim 1 , wherein the gaseous feed mixture comprises hydrogen and carbon dioxide in a ratio of from about 1 to about 5.

12. The process of claim 1 , wherein a first syngas mixture is produced from the methane steam reforming process, wherein the first syngas mixture produced from the methane steam reforming process has a temperature of from about 450° C. to about 900° C. s.

13. The process of claim 12 , wherein the first syngas mixture produced from the methane steam reforming process has a temperature of about 850° C.

14. The process of claim 12 , wherein a second syngas mixture is produced from the carbon dioxide hydrogenation process.

15. The process of claim 14 , comprising mixing the first syngas mixture produced from the methane steam reforming process and the second syngas mixture produced from the carbon dioxide hydrogenation process.

16. The process of claim 12 , comprising mixing the first syngas mixture produced from the methane steam reforming process with the gaseous feed mixture prior to the carbon dioxide hydrogenation process.

17. The process of claim 12 , wherein the first syngas mixture produced from the methane steam reforming process and the heated the gaseous feed mixture are subject to the carbon dioxide hydrogenation process.

18. The process of claim 1 , wherein the integrated process reduces energy consumption as compared to a methane steam reforming process.

19. The process of claim 1 , wherein the gaseous feed mixture is contacted with the carbon dioxide hydrogenation catalyst at a temperature of about 300° C. to about 600° C.

20. The process of claim 1 , wherein the carbon dioxide hydrogenation catalyst is selected from:
a catalyst comprising manganese oxide, and an oxide of at least one member selected from the group consisting of calcium, potassium, copper, aluminum, chromium, nickel, lanthanum, cerium, tungsten and platinum;
a catalyst comprising nickel;
a catalyst comprising chromium;
a catalyst comprising molybdenum and nickel; or
a combination comprising at least one of the foregoing.

Assignees

• Saudi Basic Ind Corp

Inventors

• Mamedov Aghaddin
• Rea Clark

Classifications

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title

• C01B2203/1058

  Nickel catalysts · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• B01J23/34

  Manganese · CPC title

• Y02P20/142

  Cross-Sectional Technologies · mapped topic