Thermal transfer film, and organic electroluminescent device prepared using same

Patent metadata

Field	Value
Publication number	US-9688088-B2
Application number	US-201314655687-A
Country	US
Kind code	B2
Filing date	Dec 27, 2013
Priority date	Dec 28, 2012
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

The present invention relates to a thermal transfer film comprising: a base layer; and a light-to-heat conversion layer which is laminated on top of the base layer and includes a first layer laminated on top of the base layer and a second layer laminated on top of the first layer in the thickness direction, wherein light-to-heat conversion materials are more omnipresent in the first layer than the second layer. The present invention also relates to an organic electroluminescent device prepared using said film.

First claim

The invention claimed is:

1. A thermal transfer film comprising:
a base layer; and
a light-to-heat conversion layer formed on the base layer, the light-to-heat conversion layer comprising a cured product of a composition for a light-to-heat conversion layer, the composition comprising a UV curable resin, a polyfunctional monomer, a light-to-heat conversion material and an initiator,
wherein the light-to-heat conversion layer includes a first layer stacked on the base layer and a second layer stacked on the first layer in a thickness direction,
the light-to-heat conversion material is more distributed in the first layer than in the second layer, and wherein the second layer has a surface roughness (Ra) of about 10 nm or less on its upper surface.

2. The thermal transfer film according to claim 1 , wherein a ratio (C1/C2) of concentration (C1) of the light-to-heat conversion material in the first layer to concentration (C2) of the light-to-heat conversion material in the second layer is about 1.5 or more.

3. The thermal transfer film according to claim 1 , wherein the first layer has a thickness of about 20% to about 90% of a total thickness of the light-to-heat conversion layer.

4. The thermal transfer film according to claim 1 , wherein the first layer has a thickness of about 0.1 μm to about 10 μm, and the second layer has a thickness of about 0.05 μm to about 10 μm.

5. The thermal transfer film according to claim 1 , wherein the light-to-heat conversion material is dispersed throughout the first layer.

6. The thermal transfer film according to claim 1 , wherein the first layer comprises a first region and a second region in the thickness direction, and the light-to-heat conversion material is more distributed in the first region than in the second region.

7. The thermal transfer film according to claim 6 , wherein a ratio (t12/t11) of thickness (t12) of the second region to thickness (t11) of the first region is about 5 or less.

8. The thermal transfer film according to claim 1 , wherein the light-to-heat conversion material has a gradually increasing concentration with increasing distance from an interface between the first layer and second layer to a lower surface of the first layer.

9. The thermal transfer film according to claim 1 , wherein the light-to-heat conversion material comprises at least one of a dye and a pigment.

10. The thermal transfer film according to claim 1 , wherein the light-to-heat conversion material has a particle shape.

11. A thermal transfer film comprising:
a base layer; and
a light-to-heat conversion layer formed on the base layer, the light-to-heat conversion layer comprising a cured product of a composition for a light-to-heat conversion layer, the composition comprising a UV curable resin, a polyfunctional monomer, a light-to-heat conversion material and an initiator,
wherein the light-to-heat conversion layer is a single layer having a first region adjacent the base layer in a thickness direction and a second region adjacent the first region in a thickness direction, and
the light-to-heat conversion material is more distributed in the first region than in the second region, and wherein the second region has a surface roughness (Ra) of about 10 nm or less on its upper surface.

12. The thermal transfer film according to claim 1 , wherein the composition comprises about 10 wt % to about 80 wt % of the UV curable resin, about 5 wt % to about 50 wt % of the polyfunctional monomer, about 5 wt % to about 50 wt % of the light-to-heat conversion material and about 0.1 wt % to about 10 wt % of the photo initiator in terms of solid content.

13. The thermal transfer film according to claim 1 , wherein the composition further comprises at least one of a curable fluorine compound and a curable siloxane compound.

14. The thermal transfer film according to claim 13 , wherein the curable fluorine compound is represented by Formula 1:
(CH 2 ═CR 1 COO) n R f ,  <Formula 1>

(wherein n is an integer of 2 or more;
R 1 is hydrogen, or a C 1 to C 5 linear or branched alkyl group; and
R f is represented by any one of Formulae a to e:

(wherein * is a bonding site;
R F1 is a C 1 to C 10 linear or branched perfluoroalkylene group; and
R F2 , R F3 , R F4 and R F5 are each hydrogen, or a C 1 to C 14 linear or branched perfluoroalkyl group)).

15. The thermal transfer film according to claim 13 , wherein the curable siloxane compound comprises polyether-modified dialkyl polysiloxane containing a (meth)acrylic group.

16. The thermal transfer film according to claim 13 , wherein the composition comprises about 10 wt % to about 80 wt % of the UV curable resin, about 5 wt % to about 50 wt % of the polyfunctional monomer, about 5 wt % to about 50 wt % of the light-to-heat conversion material, about 0.1 wt % to about 10 wt % of the photo initiator and about 0.01 wt % to about 10 wt % of the at least one of the curable fluorine compound and the curable siloxane compound in terms of solid content.

17. The thermal transfer film according to claim 1 , wherein the base layer comprises a film formed of at least one of polyester resins, polyacrylic resins, polyepoxy resins, polyolefin resins, and polystyrene resins.

18. The thermal transfer film according to claim 1 , wherein the light-to-heat conversion layer comprises a transfer layer stacked thereon.

19. The thermal transfer film according to claim 1 , wherein the light-to-heat conversion material comprises at least one of carbon black and tungsten oxide.

20. An organic electroluminescent device prepared using the thermal transfer film according to claim 1 as a donor film.

Assignees

• Cheil Ind Inc
• Samsung Sdi Co Ltd

Inventors

• Lee Jung Hyo
• Kang Kyoung Ku
• Park Si Kyun
• Cho Seong Heun
• Kim Sung Han
• Park Se Hyun
• Lee Eun Su
• Choi Jin Hee

Classifications

• B41M5/465 Primary

  Infrared radiation-absorbing materials, e.g. dyes, metals, silicates, C black · CPC title

• B41M2205/36

  Backcoats; Back layers · CPC title

• B41M5/446

  Fluorine-containing polymers · CPC title

• H01L51/0013

  Electricity · mapped topic

• B41M5/443

  Silicon-containing polymers, e.g. silicones, siloxanes · CPC title