Catalyst for pyrolysis of feedstock

Patent metadata

Field	Value
Publication number	US-9687829-B2
Application number	US-201514616028-A
Country	US
Kind code	B2
Filing date	Feb 6, 2015
Priority date	Feb 7, 2014
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

A novel catalyst blend for processing of feedstocks into monoaromatics in a single stage, comprising at least one cracking catalyst, one heterogeneous transition metal catalyst, and optionally at least one hydrogenation catalyst. The process occurs in one-step or single stage with substantially no solvents or external additives, or when the feedstock contains less than 15% oxygen, the process includes additional water or steam to enable sufficient amounts of H 2 being produced in-situ.

First claim

The invention claimed is:

1. A catalyst blend for single stage catalytic fast pyrolysis of a feedstock comprising:
about 40-85 wt % of a zeolite cracking catalyst comprising a mixture of at least one large pore zeolite and at least one intermediate or small pore zeolite in a ratio of 5:1 to 1:5;
about 4-40 wt % of a heterogeneous transition metal water-gas shift catalyst comprising at least one metal oxide and a support that is optionally promoted; and
optionally about 3-20 wt % of at least one hydrogenation catalyst.

2. The catalyst blend of claim 1 , wherein said at least one large pore zeolite and at least one intermediate or small pore zeolite are selected from the group consisting of FAU, CHA, MOR framework types, ACO, AEI, AEN, AFN, AFT, AFX, ANA, APC, APD, ATT, CDO, DDR, DFT, EAB, EDI, EPI, EM, GIS, GOO, IHW, ITE, ITW, LEV, KFI, MER, MON, NSI, OWE, PAU, PHI, RHO, TH, SAT, SAV, SIV, THO, TSC, UEI, UFI, VNI, YUG, ZON, MFI, LTA, BEA framework types, ZSM-5, ferriente, zeolite Y, zeolite beta, mordenite, MCM-22, ZSM-23, ZSM-57, SUZ-4, EU-1, ZSM-11, (S)A1PO-31, SSZ-23, SAPO, ALPA, and MeALPO.

3. The catalyst blend of claim 2 , wherein said at least one large pore zeolite is selected from the group consisting of zeolite Y, and mixtures thereof, and said at least one intermediate or small pore zeolite is selected from the group consisting of CHA, ZSM-5, DDR, and SAPO.

4. The catalyst blend of claim 1 , wherein said metal oxide is selected from the group consisting of platinum, rhenium, cobalt, and mixtures thereof, and said support is selected from the group consisting of Al 2 O 3 and silica, and said optional promoter is selected from the group consisting of cerium, molybdenum and tungsten.

5. The catalyst blend of claim 4 , wherein said water-gas-shift catalyst comprises platinum (Pt) oxide and rhenium (Re) oxide on a Mo-promoted Al 2 O 3 support.

6. The catalyst blend of claim 1 comprising the at least one hydrogenation catalyst, wherein said at least one hydrogenation catalyst comprises a metal selected from the group consisting of nickel (Ni), copper (Cu), zinc (Zn), and combinations thereof.

7. The catalyst blend of claim 6 , wherein said hydrogenation catalyst comprises Ni.

8. The catalyst blend of claim 1 , wherein at least one of said cracking catalyst or said hydrogenation catalyst is supported on a solid support.

9. The catalyst blend of claim 8 , wherein at least one of said cracking catalyst or said hydrogenation catalyst is supported on porous microspheres.

10. The catalyst blend of claim 9 , wherein said porous microspheres are about 70-90 μm in diameter.

11. The catalyst blend of claim 9 , wherein said porous microspheres have pores that are about 90-110 nm in diameter.

12. The catalyst blend of claim 9 , wherein said cracking catalyst is formed in-situ within pores of said porous microspheres, and said water-gas shift and hydrogenation catalysts are incorporated in or on said microspheres as powders or particles.

13. The catalyst blend of claim 1 , wherein the catalyst blend comprises about 50-80 wt % of said cracking catalyst, about 7-20 wt % of said heterogeneous transition metal water-gas shift catalyst, and when present about 7-10 wt % of said hydrogenation catalyst.

14. The catalyst blend of claim 1 , wherein said at least one large pore zeolite is zeolite Y, and said at least one intermediate or small pore zeolite is ZSM-5.

15. A catalyst blend for single stage catalytic fast pyrolysis of a feedstock comprising:
a zeolite cracking catalyst comprising a mixture of at least one large pore zeolite and at least one intermediate or small pore zeolite in a ratio of 5:1 to 1:5;
a heterogeneous transition metal water-gas shift catalyst comprising at least one metal oxide and a support that is optionally promoted; and
optionally at least one hydrogenation catalyst; and
wherein:
at least one of said cracking catalyst or said hydrogenation catalyst is supported on a solid support; and
at least one of said cracking catalyst or said hydrogenation catalyst is supported on porous microspheres.

16. The catalyst blend of claim 15 , wherein said at least one large pore zeolite is selected from the group consisting of zeolite Y, and mixtures thereof, and said at least one intermediate or small pore zeolite is selected from the group consisting of CHA, ZSM-5, DDR, and SAPO.

17. The catalyst blend of claim 15 , wherein said metal oxide is selected from the group consisting of platinum, rhenium, cobalt, and mixtures thereof, and said support is selected from the group consisting of Al 2 O 3 and silica, and said optional promoter is selected from the group consisting of cerium, molybdenum and tungsten.

18. The catalyst blend of claim 15 , wherein said water-gas-shift catalyst comprises platinum (Pt) oxide and rhenium (Re) oxide on a Mo-promoted Al 2 O 3 support.

19. The catalyst blend of claim 15 comprising the at least one hydrogenation catalyst, wherein said at least one hydrogenation catalyst comprises a metal selected from the group consisting of nickel (Ni), copper (Cu), zinc (Zn), and combinations thereof.

20. The catalyst blend of claim 15 , wherein said porous microspheres are about 70-90 μm in diameter.

21. The catalyst blend of claim 15 , wherein the catalyst blend comprises about 50-80 wt % of said cracking catalyst, about 7-20 wt % of said heterogeneous transition metal water-gas shift catalyst, and when present about 7-10 wt % of said hydrogenation catalyst.

Assignees

• Basf Corp

Inventors

• Mcguire Robert

Classifications

• B01J23/24

  Chromium, molybdenum or tungsten · CPC title

• B01J37/0205

  in several steps · CPC title

• B01J29/48

  containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium · CPC title

• C07C2523/656

  Manganese, technetium or rhenium · CPC title

• B01J23/6567

  Rhenium · CPC title