Apparatus and method for continuously producing carbon nanotubes

Patent metadata

Field	Value
Publication number	US-9687802-B2
Application number	US-201113981597-A
Country	US
Kind code	B2
Filing date	Aug 19, 2011
Priority date	Apr 4, 2011
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

Disclosed are an apparatus and method for continuously producing carbon nanotubes. More specifically, disclosed are an apparatus for continuously producing carbon nanotubes including i) a reactor to synthesize carbon nanotubes, ii) a separator to separate a mixed gas from the carbon nanotubes transferred from the reactor, iii) a filter to remove all or part of one or more component gases from the separated mixed gas, and iv) a recirculation pipe to recirculate the filtered mixed gas to the reactor for carbon nanotubes.

First claim

The invention claimed is:

1. An apparatus for continuously producing carbon nanotubes comprising:
i) a reactor to synthesize carbon nanotubes, comprising a catalyst supply pipe equipped at a first top portion of the reactor to supply a catalyst into the reactor from the first top portion, a reaction gas supply pipe to supply a reaction gas including a carbon source, a reducing gas, and an inert gas into a bottom portion of the reactor, and a product discharge pipe at a second top portion of the reactor to discharge the produced carbon nanotubes and a mixed gas, and which is capable of extending a residence time in the reactor by increasing a contact time in the reactor by supplying the catalyst into the reactor from the first top portion together with the reaction gas into the reactor from the bottom portion of the reactor;
ii) a separator to separate a mixed gas from the carbon nanotubes transferred from the reactor;
iii) a hydrogen pressure swing adsorption (PSA) unit including two or more adsorption towers and two or more flow direction control valves that is configured to process removal of 19 to 34% of only hydrogen (H 2 ) gas produced as a byproduct gas in the reactor from the separated mixed gas from the separator;
iv) a filter, a scrubber or a combination thereof arranged between (ii) the separator and (iii) the PSA unit; and
v) a recirculation pipe to recirculate the processed gas including non-reacted carbon source, the inert gas and the reducing gas injected at the start of the reaction discharged from the PSA unit to the reactor for carbon nanotubes,
wherein the reactor is a fluidized bed reactor,
wherein the PSA unit includes a first flow direction control valve to direct the mixed gas discharged from the separator to a first adsorption tower to perform pressurization, a second flow direction control valve to direct the processed gas to the recirculation pipe and a third flow direction control valve to direct the hydrogen (H 2 ) gas discharged from a second adsorption tower, which is depressurized, toward a discharge gas disposal or hydrogen (H 2 ) storage unit, and
wherein, in the PSA unit, the first to third flow direction control valves are connected.

2. The apparatus according to claim 1 , wherein the separator is a cyclone.

3. The apparatus according to claim 1 , comprising further a control unit to control the amount of the reaction gas supplied to the reactor and the amount of the gas removed in the PSA unit.

4. The apparatus according to claim 1 , comprising further a control unit to control the amount of the reaction reducing gas supplied to the reactor and the amount of the reducing gas passed through the PSA unit.

5. The apparatus according to claim 4 , wherein the control unit is adjusted to match the amount of reducing gas supplied to the reactor and the amount of reducing gas to pass through the PSA unit.

6. The apparatus according to claim 1 wherein the apparatus does not include any waste gas incineration means.

7. An apparatus for continuously producing carbon nanotubes comprising:
i) a reactor to synthesize carbon nanotubes, comprising a catalyst supply pipe equipped at a first top portion of the reactor to supply a catalyst into the reactor from the first top portion, a reaction gas supply pipe to supply a reaction gas including a carbon source, a reducing gas, and an inert gas into a bottom portion of the reactor, and a product discharge pipe at a second top portion of the reactor to discharge the produced carbon nanotubes and mixed gas, and which is capable of extending a residence time in the reactor by increasing a contact time in the reactor by supplying the catalyst into the reactor from the first top portion together with the reaction gas into the reactor from the bottom portion of the reactor;
ii) a separator to separate a mixed gas from the carbon nanotubes transferred from the reactor;
iii) a metal membrane gas separation unit, wherein the metal membrane is made of at least one metal selected from the group consisting of Pd, Ir, Rh, Pd—Ni alloys, Pd—Ag alloys, and Pd—Cu alloys, and the metal membrane gas separation unit is configured to process removal of 19 to 34% of only hydrogen (H 2 ) gas produced as a byproduct gas in the reactor from the separated mixed gas from the separator at temperature below 500° C.;
iv) a filter, a scrubber or a combination thereof arranged between (ii) the separator and (iii) the metal membrane gas separation unit; and
v) a recirculation pipe to recirculate the processed gas including non-reacted carbon source, the inert gas and the reducing gas injected at the start of the reaction discharged from the metal membrane gas separation unit to the reactor for carbon nanotubes,
wherein the reactor is a fluidized bed reactor.

8. The apparatus according to claim 7 , comprising further a control unit to control the amount of the reaction gas supplied to the reactor and the amount of the gas removed in the separation unit.

9. The apparatus according to claim 7 , comprising further a control unit to control the amount of the reaction reducing gas supplied to the reactor and the amount of the reducing gas passed through the separation unit.

10. The apparatus according to claim 9 , wherein the control unit is adjusted to match the amount of reducing gas supplied to the reactor and the amount of reducing gas to pass through the separation unit.

11. The apparatus according to claim 7 , wherein the apparatus does not include any waste gas incineration means.

Assignees

• Chang Kwang-Hyun
• Kim Jin-Do
• Yoon Kwang-Woo
• Lg Chemical Ltd

Inventors

• Chang Kwang-Hyun
• Kim Jin-Do
• Yoon Kwang-Woo

Classifications

• B01J8/0055 Primary

  using cyclones · CPC title

• C01B31/024

  Chemistry & Metallurgy · mapped topic

• D01F9/133

  Apparatus therefor · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• B01J2208/00548

  Flow · CPC title