Desulfurization method and device for sulfuric acid production device

Patent metadata

Field	Value
Publication number	US-9687781-B2
Application number	US-201314646858-A
Country	US
Kind code	B2
Filing date	Oct 25, 2013
Priority date	Nov 30, 2012
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

This desulfurization device is for desulfurizing a discharge gas which contains sulfur oxides and which was discharged from a device for sulfuric acid production that includes a concentrated-sulfuric-acid production step in which sulfur trioxide gas obtained by oxidizing sulfur dioxide gas is absorbed in an aqueous sulfuric acid solution while supplying water thereto to thereby produce sulfuric acid having a concentration as high as 90 wt % or more but less than 99 wt %, the desulfurization device comprising: a desulfurization tower in which the sulfur oxides are removed from the discharge gas and, simultaneously therewith, dilute sulfuric acid is formed from the sulfur oxides; and a dilute sulfuric acid mixer which, in the concentrated-sulfuric-acid production step, mixes the dilute sulfuric acid with the aqueous sulfuric acid solution.

First claim

The invention claimed is:

1. A method for desulfurizing a discharge gas which contains sulfur oxides and which was discharged from a device for sulfuric acid production that includes a concentrated-sulfuric-acid production step in which sulfur trioxide gas obtained by oxidizing sulfur dioxide gas is absorbed in an aqueous sulfuric acid solution while supplying water thereto to thereby produce sulfuric acid having a concentration as high as 90 wt % or more but less than 99 wt %, the method comprising:
a desulfurization step in which the sulfur oxides are removed from the discharge gas and, simultaneously therewith, dilute sulfuric acid is formed from the sulfur oxides; and
a mixing step which, in the concentrated-sulfuric-acid production step, mixes the dilute sulfuric acid with the aqueous sulfuric acid solution,
wherein the dilute sulfuric acid is produced by bringing the discharge gas into contact with an activated carbon-based catalyst together with water in the presence of oxygen.

2. The method according to claim 1 , further comprising a humidification step for humidifying the discharge gas by bringing the discharge gas into contact with a humidifying liquid before the discharge gas is brought into contact with the activated carbon-based catalyst.

3. The method according to claim 2 , wherein at least part of the humidifying liquid having come into contact with the discharge gas is mixed with the aqueous sulfuric acid solution together with the dilute sulfuric acid in the concentrated sulfuric acid production step.

4. The method according to claim 2 , further comprising a removal step for removing nitrosylsulfuric acid from at least part of the humidifying liquid having come into contact with the discharge gas, wherein a liquid obtained by the removal of nitrosylsulfuric acid is used as the water.

5. The method according to claim 4 , wherein the removal step for removing nitrosylsulfuric acid comprises a method of adding one or both of hydrogen peroxide and ozone or a method of bringing the at least part of the humidifying liquid into contact with activated carbon while introducing air.

6. The method according to claim 2 , further comprising a removal step for removing nitrosylsulfuric acid from at least part of the humidifying liquid having come into contact with the discharge gas, wherein a liquid obtained by the removal of nitrosylsulfuric acid is mixed with the aqueous sulfuric acid solution in the concentrated sulfuric acid production step together with the dilute sulfuric acid.

7. The method according to claim 6 , wherein the removal step for removing nitrosylsulfuric acid comprises a method of adding one or both of hydrogen peroxide and ozone or a method of bringing the at least part of the humidifying liquid into contact with activated carbon while introducing air.

8. The method according to claim 2 , further comprising a heating step for heating at least part of the humidifying liquid having come into contact with the discharge gas, wherein the heated liquid is used as the humidifying liquid.

9. A desulfurization device for desulfurizing a discharge gas which contains sulfur oxides and which was discharged from a device for sulfuric acid production that includes a concentrated-sulfuric-acid production step in which sulfur trioxide gas obtained by oxidizing sulfur dioxide gas is absorbed in an aqueous sulfuric acid solution while supplying water thereto to thereby produce sulfuric acid having a concentration as high as 90 wt % or more but less than 99 wt %, the desulfurization device comprising:
desulfurization means in which the sulfur oxides are removed from the discharge gas and, simultaneously therewith, dilute sulfuric acid is formed from the sulfur oxides; and
mixing means which mixes the dilute sulfuric acid with the aqueous sulfuric acid solution,
wherein the desulfurization means includes humidification means which humidifies the discharge gas by bringing the discharge gas into contact with a humidifying liquid, a desulfurization tower configured to receive the discharge gas humidified by the humidification means, an activated carbon-based catalyst contained in the desulfurization tower, and a water supply pipe connected to the desulfurization tower in order to supply water to the activated carbon-based catalyst.

10. The desulfurization device according to claim 9 , wherein the mixing means is configured to mix at least part of the humidifying liquid having come into contact with the discharge gas with the aqueous sulfuric acid solution in the concentrated sulfuric acid production step together with the dilute sulfuric acid.

11. The desulfurization device according to claim 9 , further comprising nitrosylsulfuric acid removal means which removes nitrosylsulfuric acid from at least part of the humidifying liquid having come into contact with the discharge gas, wherein a liquid obtained by the removal of nitrosylsulfuric acid is supplied to the activated carbon-based catalyst.

12. The desulfurization device according to claim 9 , further comprising heating means for heating at least part of the humidifying liquid having come into contact with the discharge gas, wherein the humidifying means is configured to use the heated liquid as the humidifying liquid.

13. A sulfuric acid production plant comprising:
concentrated-sulfuric-acid production means in which sulfur trioxide gas obtained by oxidizing sulfur dioxide gas is absorbed in an aqueous sulfuric acid solution while supplying water thereto to thereby produce sulfuric acid having a concentration as high as 90 wt % or more but less than 99 wt %;
mixing means for mixing dilute sulfuric acid produced by removing sulfur oxides from a discharge gas containing the sulfur oxides with the aqueous sulfuric acid solution in the concentrated-sulfuric-acid production means; and
desulfurization means includes humidification means which humidifies the discharge gas by bringing the discharge gas into contact with a humidifying liquid, and a desulfurization tower configured to receive the discharge gas humidified by the humidification means, an activated carbon-based catalyst contained in the desulfurization tower, and a water supply pipe connected to the desulfurization tower in order to supply water to the activated carbon-based catalyst.

14. The sulfuric acid production plant according to claim 13 , wherein the mixing means is configured to mix at least part of a humidifying liquid having come into contact with the discharge gas with the aqueous sulfuric acid solution in the concentrated sulfuric acid production means together with the dilute sulfuric acid.

Assignees

• Chiyoda Corp

Inventors

• Kawamura Kazushige
• Takeda Dai
• Awai Eiji
• Takei Noboru
• Uemura Masataka

Classifications

• C02F2101/101

  Sulfur compounds · CPC title

• C01B17/74

  Preparation · CPC title

• B01D2255/702

  Carbon · CPC title

• C02F1/283

  using coal, charred products, or inorganic mixtures containing them · CPC title

• C02F2103/18

  from the purification of gaseous effluents · CPC title