Control of carbonyl sulfide with sodium borohydride in caustic towers for petroleum/petrochemical processes

Patent metadata

Field	Value
Publication number	US-9687779-B2
Application number	US-201514813333-A
Country	US
Kind code	B2
Filing date	Jul 30, 2015
Priority date	Jul 30, 2015
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

Sodium borohydride (NaBH 4 ) may be used to removing carbonyl sulfide (COS) from a process stream containing it. The method involves contacting the process stream with an amount of effective of NaBH 4 to react with the COS to form reaction products that may be removed by a process of washing away the reaction product by an aqueous basic compound and/or the reaction product having a higher boiling point than carbonyl sulfide which permits trapping the reaction product, such as in a caustic tower.

First claim

What is claimed is:

1. A method for removing carbonyl sulfide from a process stream containing it, the method comprising contacting the process stream with an amount of sodium borohydride ranging from a molar ratio of sodium borohydride to carbonyl sulfide of from about 0.02:1 to about 50:1 based on the amount of carbonyl sulfide, where the sodium borohydride reacts with the carbonyl sulfide to form at least one reaction product, where the at least one reaction product may be removed from the process stream by a process selected from the group consisting of:
washing away the at least one reaction product with a basic compound;
trapping the at least one reaction product, where the at least one reaction product has a higher boiling point than carbonyl sulfide; and
combinations thereof.

2. The method of claim 1 where:
the process stream is present in a caustic tower of a petroleum or petrochemical process;
the basic compound is selected from the group consisting of sodium hydroxide, potassium hydroxide, lithium hydroxide, an amine, and combinations thereof; and
the at least one reaction product having a higher boiling point than carbonyl sulfide is trapped in the caustic tower.

3. The method of claim 1 where the process stream is present in a process selected from the group consisting of a hydrogen sulfide scrubbing process and an olefins steam cracking process.

4. The method of claim 1 where the amount of sodium borohydride added to the process stream ranges from a molar ratio of sodium borohydride to carbonyl sulfide of from about 0.1:1 to about 40:1 based on the amount of carbonyl sulfide.

5. The method of claim 1 where the amount of sodium borohydride added to the process stream is effective to lower the concentration of COS in the process stream to from about 0.1 independently to about 100 ppm.

6. A method for removing carbonyl sulfide from a process stream containing it, where the process stream is present in a caustic tower of a petroleum or petrochemical process, the method comprising contacting the process stream with an amount of sodium borohydride ranging from a molar ratio of sodium borohydride to carbonyl sulfide of from about 0.02:1 to about 50:1 based on the amount of carbonyl sulfide where the sodium borohydride reacts with the carbonyl sulfide to form at least one reaction product that may be removed by a process selected from the group consisting of:
washing away the at least one reaction product with a basic compound selected from the group consisting of sodium hydroxide, potassium hydroxide, an amine, and combinations thereof;
trapping the at least one reaction product in the caustic tower, where the at least one reaction product has a higher boiling point than carbonyl sulfide; and
combinations thereof.

7. The method of claim 6 where the process stream is present in process selected from the group consisting of a hydrogen sulfide scrubbing process and an olefins steam cracking process.

8. The method of claim 6 where the amount of sodium borohydride added to the process stream ranges from a molar ratio of sodium borohydride to carbonyl sulfide of from about 0.1:1 to about 40:1 based on the amount of carbonyl sulfide.

9. The method of claim 6 where the amount of sodium borohydride added to the process stream is effective to lower the concentration of COS in the process stream to from about 0.1 independently to about 100 ppm.

10. The method of claim 6 where the method comprises washing away the at least one reaction product with a basic compound in an aqueous liquid:
when the basic compound is an alkali metal hydroxide, the amount of alkali metal hydroxide may be about 20 wt % or less of the liquid; and
when the basic compound is an amine, the amount of amine may comprise about 50 wt % independently to about 60 wt % of the liquid.

11. A method for removing carbonyl sulfide from a process stream containing it, where the process stream is present in a caustic tower of a petroleum or petrochemical process, the method comprising contacting the process stream with an amount of sodium borohydride ranging from a molar ratio of sodium borohydride to carbonyl sulfide of from about 0.1:1 to about 40:1 based on the amount of carbonyl sulfide where the sodium borohydride reacts with the carbonyl sulfide to form at least one reaction product that may be removed by a process selected from the group consisting of:
washing away the at least one reaction product with a basic compound selected from the group consisting of sodium hydroxide, potassium hydroxide, an amine, and combinations thereof;
trapping the at least one reaction product in the caustic tower, where the at least one reaction product has a higher boiling point than carbonyl sulfide; and
combinations thereof;

where the process stream is present in process selected from the group consisting of a hydrogen sulfide scrubbing process and an olefins steam cracking process.

12. The method of claim 11 where the amount of sodium borohydride added to the process stream is effective to lower the concentration of COS in the process stream to from about 0.1 independently to about 100 ppm.

13. The method of claim 11 where the method comprises washing away the at least one reaction product with a basic compound in an aqueous liquid:
when the basic compound is an alkali metal hydroxide, the amount of alkali metal hydroxide may be about 20 wt % or less of the liquid; and
when the basic compound is an amine, the amount of amine may comprise about 50 wt % independently to about 60 wt % of the liquid.

Assignees

• Baker Hughes Inc

Inventors

• Mo Hua
• Metzler Roger D

Classifications

• B01D2258/0283

  Flue gases · CPC title

• B01D53/485 Primary

  containing only one sulfur compound other than sulfur oxides or hydrogen sulfide · CPC title

• B01D53/78 Primary

  with gas-liquid contact · CPC title

• B01D2251/306

  of potassium · CPC title

• B01D2251/302

  of lithium · CPC title