Process and apparatus for minimizing attrition of catalyst particles

Patent metadata

Field	Value
Publication number	US-9687765-B2
Application number	US-201314434973-A
Country	US
Kind code	B2
Filing date	Oct 14, 2013
Priority date	Oct 31, 2012
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

An improved process and an improved apparatus for minimizing attrition of catalyst particles, especially propane dehydrogenation catalyst particles, entrained in a combined flow of such particles and an entraining gas in a catalyst recovery means during separation of such particles from the entraining gas, by use of a pre-treatment step in which the combined flow is at a rate between 7.6 and 15.2 meters per second are provided.

First claim

What is claimed is:

1. An improved process for minimizing attrition of catalyst particles entrained in a combined flow of such particles and an entraining: gas in a catalyst recovery means during separation of such particles from the entraining gas, which process comprises causing the combined flow to contact a high velocity separation means at a was flow velocity of 16.8 meters per second to 25.9 meters per second and thereby remove from said combined flow at least 99.8 percent of the catalyst particles, wherein the improvement comprises:
subjecting the combined flow, having an axis of flow direction, to a pre-treatment step that precedes contact of the combined flow with the separation means at the high gas flow velocity of from 16.8 meters per second to 25.9 meters per second, the pre-treatment step occurring at a lower gas flow velocity a range of from 7.6 meters per second to 15.2 meters per second in combination with a directional change away from the combined gas flow, which directional change is at least 90 degrees from the axis of flow direction and, which pre-treatment step combination of velocity and direction change causes removal from the combined flow greater than 80 percent of the catalyst particles such that less than 20 percent of the catalyst particles contact the high velocity separation means, the improved process providing a total catalyst attrition rate calculated in accord with the correlation r=Ku 2 /√{square root over (μ)}, where r is attrition rate (mass of catalyst attrited per hour per mass of catalyst impacted per hour), K is as catalyst specific attrition rate constant, u is the impact velocity (meters per second), and μ is solids-to-gas loading ratio (mass of catalyst to mass of gas), that is at least fifteen percent less than the total catalyst attrition rate without the pre-treatment step; and
wherein said high velocity separation means comprises a combined flow deflector, wherein said a combined flow deflector is a disk.

2. The improved process of claim 1 , wherein the total catalyst attrition rate provided by the improved process is at least fifty percent less than the total catalyst attrition rate in the absence of the pre-treatment step.

3. The improved process of claim 1 , wherein the separation means is a two-stage high velocity cyclone system that includes a primary cyclone operating at a gas flow velocity within a range from 16.8 meters per second to 22.9 meters per second, and a secondary cyclone operating at a gas flow velocity within a range of from 18.3 meters per second to 25.9 meters per second.

4. The improved process of Claim 1 , wherein the directional, change is within a range of from least 110 degrees up to 180 degrees away from the axis of flow direction.

5. The improved process of claim 1 , wherein the pre-treatment step causes removal from the combined flow of greater than 90 percent of the catalyst particles such that less than 10 percent of the catalyst particles contact the separation means.

6. The improved process of claim 1 , wherein the improved process provides a total catalyst attrition rate calculated in accord with the correlation r=Ku 2 /√{square root over (μ)} where r is attrition rate (mass of catalyst attrited per hour per mass of catalyst impacted per hour), K is a catalyst specific attrition rate constant, u is the impact velocity (meters per second), and μ is solids-to-gas loading ratio (mass of catalyst to mass of gas), that is at least twenty-one percent less than the total catalyst attrition rate without the pre-treatment step.

7. The improved process claim 1 , wherein the catalyst particles comprise propane dehydrogenation catalyst.

8. The improved process of claim 1 , wherein the catalyst specific attrition rate constant, K, is 100×10 −9 s 2 /m.

9. An improved apparatus for minimizing attrition of catalyst particles entrained in a combined flow of such particles and an entraining gas in a catalyst recovery means during separation of such particles from the entraining gas, which improved apparatus comprises one or more high velocity cyclone separators designed to receive the combined flow at a gas flow velocity of from 16.8 meters per second to 25.9 meters per second and thereby remove from said combined flow at least 99.8 percent of the catalyst particles, wherein the improvement comprises:
a combined flow deflector situated above dip legs of the one or more cyclone separators and wherein the combined flow deflector is capable of changing the velocity and direction thereby removing from the combined flow of greater than 80 percent of the catalyst particles from the combined stream of catalyst particles and entraining gas, such that less than 20 percent of the catalyst particles impact the high velocity separation means, wherein the combined gas flow velocity following contact with the combined flow deflector is from 7.6 meters per second to 15.2 meters per second and direction of combined gas flow following contact with the combined flow deflector is at least 90 degrees from the axis of combined flow prior to contact with the combined flow deflector, and wherein said a combined flow deflector is disk.

10. The improved apparatus of claim 9 , wherein the one or more cyclone separators comprise a two-stage high velocity cyclone system that includes a primary cyclone operating at a gas flow velocity within a range from 16.8 meters per second to 22.9 meters per second, and a secondary cyclone operating at a gas flow velocity within a range of from 18.3 meters per second to 25.9 meters per second.

Assignees

• Dow Global Technologies Llc

Inventors

• Pretz Matthew
• Stewart Mark W
• Shaw Don F
• Stears Brien A
• Kodam Madhusudhan M
• Freireich Ben

Classifications

• B01J8/34

  with stationary packing material in the fluidised bed, e.g. bricks, wire rings, baffles · CPC title

• B01J2208/00991

  Disengagement zone in fluidised-bed reactors · CPC title

• B01D45/12

  by centrifugal forces (centrifuges B04B; cyclones B04C) · CPC title

• B01J8/1827

  the fluidising gas being a reactant · CPC title

• B04C3/00

  Apparatus in which the axial direction of the vortex {flow following a screw-thread type line} remains unchanged {; Devices in which one of the two discharge ducts returns centrally through the vortex chamber, a reverse-flow vortex being prevented by bulkheads in the central discharge duct (combined with other devices B04C9/00)} · CPC title