Negative electrode for power storage device, method for forming the same, and power storage device

Patent metadata

Field	Value
Publication number	US-9685653-B2
Application number	US-201615200015-A
Country	US
Kind code	B2
Filing date	Jul 1, 2016
Priority date	Apr 6, 2012
Publication date	Jun 20, 2017
Grant date	Jun 20, 2017

Abstract

An object is to suppress electrochemical decomposition of an electrolyte solution and the like at a negative electrode in a lithium ion battery or a lithium ion capacitor; thus, irreversible capacity is reduced, cycle performance is improved, or operating temperature range is extended. A negative electrode for a power storage device including a negative electrode current collector, a negative electrode active material layer which is over the negative electrode current collector and includes a plurality of particles of a negative electrode active material, and a film covering part of the negative electrode active material. The film has an insulating property and lithium ion conductivity.

First claim

What is claimed is:

1. A method for forming a negative electrode, comprising:
forming a dispersion solution by dispersing an active material comprising a graphite particle having concavo-convex shape in a solution including one of metal alkoxide and silicon alkoxide, a stabilizing agent, and a solvent;
attaching a gel, formed by hydrolyzing and condensing the one of metal alkoxide and silicon alkoxide in the dispersion solution, on a surface of the active material;
forming an oxide film on the surface by performing heating treatment on the gel, so that a concave portion of the graphite particle is covered by the oxide film;
applying a slurry including the active material with the oxide film and a binder over a current collector; and
baking the slurry.

2. The method according to claim 1 , wherein the oxide film comprises Nb 2 O 5 .

3. The method according to claim 1 , wherein the oxide film comprises silicon oxide.

4. The method according to claim 1 , wherein the heating treatment is performed at more than or equal to 300° C. and less than or equal to 900° C.

5. A power storage device comprising a battery having the negative electrode formed by the method according to claim 1 .

6. A method for forming an active material, comprising:
forming a dispersion solution by dispersing a graphite particle having concavo-convex shape in a solution including one of metal alkoxide and silicon alkoxide, a stabilizing agent, and a solvent;
attaching a gel, formed by hydrolyzing and condensing the one of metal alkoxide and silicon alkoxide in the dispersion solution, on a surface of the graphite particle; and
forming an oxide film on the surface by performing heating treatment on the gel, so that a concave portion of the graphite particle is covered by the oxide film.

7. The method according to claim 6 , wherein the oxide film comprises Nb 2 O 5 .

8. The method according to claim 6 , wherein the oxide film comprises silicon oxide.

9. The method according to claim 6 , wherein the heating treatment is performed at more than or equal to 300° C. and less than or equal to 900° C.

10. A power storage device comprising a battery having the active material formed by the method according to claim 6 .

Assignees

• Semiconductor Energy Lab

Inventors

• Inoue Nobuhiro
• Kataniwa Sachiko
• Kuriki Kazutaka
• Momo Junpei

Classifications

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/628

  Inhibitors, e.g. gassing inhibitors, corrosion inhibitors · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/583

  Carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/0404 Primary

  by coating on electrode collectors · CPC title