Toner compositions with antiplasticizers

Patent metadata

Field	Value
Publication number	US-9684257-B1
Application number	US-201615187545-A
Country	US
Kind code	B1
Filing date	Jun 20, 2016
Priority date	Jun 20, 2016
Publication date	Jun 20, 2017
Grant date	Jun 20, 2017

Abstract

Disclosed herein include styrene-acrylic-based binder compositions containing an antiplasticizer with particles having a core-shell type structure and methods for their preparation.

First claim

What is claimed is:

1. A composition comprising:
particles having a core and a shell disposed over the core, wherein
the core comprises:
a first antiplasticizer;
a first styrene-acrylate resin; and
a polyester resin;

the shell comprises:
a second styrene-acrylate resin.

2. The composition of claim 1 , wherein the first antiplasticizer has a melting point of from about −30° C. to about 500° C.

3. The composition of claim 1 , wherein the first antiplasticizer is selected from the group consisting of an alkyl benzoate, a citrate, an alkyl toluate, a phthalate, and mixtures thereof.

4. The composition of claim 1 , wherein the first antiplasticizer comprises a citrate.

5. The composition of claim 1 , wherein the first antiplasticizer is present in the toner composition in an amount of from about 0.1 to about 10 percent by weight of the total weight of the toner particles.

6. The composition of claim 1 , wherein the shell includes a second antiplasticizer which is same or different from the first antiplasticizer in the core.

7. The composition of claim 1 , wherein the polyester resin comprises a crystalline polyester resin and an amorphous resin.

8. The composition of claim 1 , wherein the crystalline polyester resin is presented in the core in an amount of from about 5 to about 50 percent by weight of the toner components.

9. The composition of claim 1 , wherein the amorphous polyester resin is presented in the core in an amount of from about 10 to about 95 percent by weight of the toner.

10. The composition of claim 1 , wherein the amorphous polyester resin is selected from the group consisting poly(alkoxylated bisphenol-A co-fumarate-co-terephthalate-cododecenylsuccinate), poly(propoxylated bisphenol co-fumarate), poly(ethoxylated bisphenol co-fumarate), and mixtures thereof.

11. The composition of claim 1 , wherein the first styrene-acrylate resin is present in the core in an amount of from about 7 to about 50 percent by weight of the total weight of the composition and the second styrene-acrylate resin is present in the shell in an amount of from about 7 to about 50 percent by weight of the total weight of the composition.

12. The composition of claim 1 , wherein the styrene-acrylate resin in the core and the styrene-acrylate resin in the shell are independently selected from the group consisting of poly(styrene-alkyl acrylate), poly(styrene-alkyl methacrylate), poly(styrene-alkyl acrylate-acrylic acid), poly(styrene-alkyl methacrylate-acrylic acid), poly(alkyl methacrylate-alkyl acrylate), poly(alkyl methacrylate-aryl acrylate), poly(aryl methacrylate-alkyl acrylate), poly(alkyl methacrylate-acrylic acid), poly(styrene-alkyl acrylate-acrylonitrile-acrylic acid), poly(alkyl acrylate-acrylonitrile-acrylic acid), poly(methyl methacrylate-butadiene), poly(ethyl methacrylate-butadiene), poly(propyl methacrylate-butadiene), poly(butyl methacrylate-butadiene), poly(methyl acrylate-butadiene), poly(ethyl acrylate-butadiene), poly(propyl acrylate-butadiene), poly(butyl acrylate-butadiene), poly(styrene-isoprene), poly(methylstyrene-isoprene), poly(methyl methacrylate-isoprene), poly(ethyl methacrylate-isoprene), poly(propyl methacrylate-isoprene), poly(butyl methacrylate-isoprene), poly(methyl acrylate-isoprene), poly(ethyl acrylate-isoprene), poly(propyl acrylate-isoprene), poly(butyl acrylate-isoprene), poly(styrene-propyl acrylate), poly(styrene-butyl acrylate), poly(styrene-butyl acrylate-acrylic acid), poly(styrene-butyl acrylate-methacrylic acid), poly(styrene-butyl acrylate-acrylonitrile), poly(styrene-butyl acrylate-acrylonitrile-acrylic acid), poly(styrene-1,3-diene), poly(styrene-1,3-diene-acrylic acid), poly (styrene-1,3-diene-acrylonitrile-acrylic acid), poly(styrene-butadiene), poly(methylstyrene-butadiene), poly (styrene-butadiene-acrylic acid), poly(styrene-butadiene-methacrylic acid), poly(styrene-butadiene-acrylonitrile-acrylic acid), poly(styrene-butyl acrylate-acrylic acid), poly(styrene-butyl acrylate-methacrylic acid), poly(styrene-butyl acrylate-acrylononitrile), poly(styrene-butyl acrylate-acrylonitrile-acrylic acid), poly(styrene-butadiene), poly(styrene-isoprene), poly(styrene-butyl methacrylate), poly(styrene-butyl methacrylate-acrylic acid), poly(butyl methacrylate-butyl acrylate), poly(butyl methacrylate-acrylic acid), poly(acrylonitrile-butyl acrylate-acrylic acid), and mixtures thereof.

13. The composition according to claim 1 , wherein both the first styrene-acrylate resin and the second styrene-acrylate resin each comprises a styrene alkyl acrylate polymer.

14. The composition according to claim 1 , wherein the first styrene-acrylate resin and the second styrene-acrylate resin are the same.

15. The composition of claim 1 having a minimum fusing temperature of from about 90 to about 150° C.

16. The composition of claim 1 having a dielectric loss of from about 5 to about 65.

17. A toner composition comprising
toner particles having a core and a shell disposed over the core, wherein
the core comprises:
a first antiplasticizer;
a first styrene-acrylate resin;
a polyester resin; and

the shell comprises:
a second styrene-acrylate resin.

18. The toner composition of claim 17 , wherein the shell includes a second antiplasticizer which is same or different from the first antiplasticizer in the core.

19. A method of making a plurality of particles comprising
providing an emulsion comprising a resin, an optional colorant, and an optional wax, and an antiplasticizer, wherein the resin comprises a first styrene-acrylate resin and a polyester resin;
aggregating the emulsion to form particle cores;
forming a shell over the particle cores to form particles, wherein the shell comprises a second styrene-acrylate resin; and
coalescing the particles.

20. The method of claim 19 , wherein the antiplasticizer is added to the emulsion at a temperature that is below the glass transition temperature (T g ) of the first styrene-acrylate resin and below the glass transition temperature (T g ) of the crystalline polyester resin.

Assignees

• Xerox Corp

Inventors

• Farrugia Valerie M
• Veregin Richard P N
• Hawkins Michael S

Classifications

• G03G9/09392

  Preparation thereof · CPC title

• G03G9/09371 Primary

  obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• G03G9/097

  Plasticisers; Charge controlling agents · CPC title

• G03G9/0823

  Electric parameters · CPC title

• G03G9/0819

  characterised by the dimensions of the particles · CPC title