Systems and methods for separating hydrocarbons using one or more dividing wall columns

Patent metadata

Field	Value
Publication number	US-9683776-B2
Application number	US-201213397921-A
Country	US
Kind code	B2
Filing date	Feb 16, 2012
Priority date	Feb 16, 2012
Publication date	Jun 20, 2017
Grant date	Jun 20, 2017

Abstract

Methods and systems for separating hydrocarbons using one or more dividing wall columns are provided. The method can include introducing a hydrocarbon fluid to a first dividing wall column. A first overhead comprising methane, ethane, or a combination thereof, a first intermediate comprising ethane, a second intermediate comprising ethane, and a first bottoms comprising one or more hydrocarbons having three or more carbon atoms per molecule can be recovered from the first dividing wall column. The first overhead can be introduced to a process for producing a liquefied natural gas. The first bottoms can be introduced to a second dividing wall column. A second overhead comprising propane, a third intermediate comprising butane, and a second bottoms comprising one or more hydrocarbons having five or more carbon atoms per molecule can be recovered from the second dividing wall column. The second overhead can be introduced to the process for producing a liquefied natural gas.

First claim

What is claimed is:

1. A method for separating hydrocarbons, comprising:
introducing a hydrocarbon feed comprising one or more hydrocarbons containing C1 to C20 carbon atoms per molecule to a first fractionation column, wherein the hydrocarbon feed comprises 80 mol % or more methane;
recovering an overhead from the first fractionation column, wherein the primary component in the overhead from the first fractionation column is methane;
recovering a bottoms from the first fractionation column;
introducing the bottoms from the first fractionation column to a first dividing wall column;
recovering an overhead from the first dividing wall column comprising methane, ethane, or a combination thereof;
recovering a first intermediate from the first dividing wall column, wherein the first intermediate has an ethane concentration of greater than or equal to 90 mol %, and wherein at least a portion of the first intermediate is recycled to the first dividing wall column;
recovering a second intermediate from the first dividing wall column as a product stream;
recovering a bottoms comprising one or more hydrocarbons having three or more carbon atoms per molecule from the first dividing wall column;
introducing the bottoms from the first dividing wall column to a second dividing wall column;
recovering an overhead from the second dividing wall column, wherein the primary component in the overhead from the second dividing wall column is propane;
recovering a third intermediate from the second dividing wall column, wherein the primary component in the third intermediate is butane; and
recovering a bottoms comprising one or more hydrocarbons having five or more carbon atoms per molecule from the second dividing wall column.

2. The method of claim 1 , wherein the method is conducted offshore.

3. The method of claim 1 , wherein each dividing wall column comprises a stripping section, a rectification section, and at least two fractionation zones located between the stripping and rectification sections.

4. The method of claim 1 , wherein each dividing wall column comprises a first and second fractionation zone, both disposed between a stripping section and a rectification section.

5. The method of claim 4 , wherein the rectification section operates at a temperature, T1; the first fractionation zone operates at a temperature, T2; the second fractionation zone operates at a temperature, T3; and the stripping section operates at a temperature, T4; wherein T1, T2, T3, and T4 are not the same temperatures.

6. The method of claim 5 , wherein T1 is less than T2.

7. The method of claim 6 , wherein T3 is less than T4.

8. The method of claim 5 , wherein T1 is less than T2, and a temperature difference between T1 and T2 is less than 30° C.

9. The method of claim 5 , wherein T3 is greater than T2, and a temperature difference between T3 and T2 is more than 15° C.

10. The method of claim 1 , further comprising expanding the hydrocarbon feed prior to introducing the hydrocarbon feed to the first fractionation column to provide a two phase composition.

11. The method of claim 1 , further comprising vaporizing about 50 wt % or more of the hydrocarbon feed prior to introducing the hydrocarbon feed to the first fractionation column.

12. The method of claim 4 , wherein introducing the bottoms from the first fractionation column to the first dividing wall column comprises apportioning the bottoms into a first portion and a second portion, and introducing the first portion to the stripping section of the first dividing wall column and the second portion to the first fractionation zone of the first dividing wall column.

13. The method of claim 9 , further comprising vaporizing about 50 wt % or more of the hydrocarbon feed prior to introducing the hydrocarbon feed to the first fractionation column, and wherein introducing the bottoms from the first fractionation column to the first dividing wall column comprises apportioning the bottoms into a first portion and a second portion, and introducing the first portion to the stripping section of the first dividing wall column and the second portion to the first fractionation zone of the first dividing wall column.

Assignees

• Stylianou Elena
• Schenk Myrian Andrea
• Kellogg Brown & Root Llc

Inventors

• Stylianou Elena
• Schenk Myrian Andrea

Classifications

• F25J1/0278

  Unit being stationary, e.g. on floating barge or fixed platform · CPC title

• F25J1/0212

  as a single flow MCR cycle · CPC title

• B01D3/141

  where at least one distillation column contains at least one dividing wall · CPC title

• F25J2215/64

  Propane or propylene · CPC title

• F25J2200/02

  in a single pressure main column system · CPC title