Fiber with gradient properties and method of making the same

Patent metadata

Field	Value
Publication number	US-9683312-B2
Application number	US-201113316504-A
Country	US
Kind code	B2
Filing date	Dec 10, 2011
Priority date	Dec 10, 2011
Publication date	Jun 20, 2017
Grant date	Jun 20, 2017

Abstract

There is provided a fiber and method of making a fiber. The fiber has an inner-volume portion having a first outer diameter, a plurality of nanostructures, and one or more first polymers. The nanostructures act as an orientation template for orientation of the one or more first polymers in a direction parallel to a longitudinal axis of the fiber. The fiber has an outer-volume portion having a second outer diameter and one or more second polymers. The outer-volume portion is in contact with and completely encompasses the inner-volume portion. The inner-volume portion has at least one of a tensile modulus and a strength that are higher than at least one of a tensile modulus and a strength of the outer-volume portion.

First claim

What is claimed is:

1. A continuous-filament finished fiber consisting of:
an inner-volume portion having a first outer diameter and having a plurality of nanostructures selected from the group consisting of nanotubes, carbon nanotubes, halloysite nanotubes, and boron nitride nanotubes, and having a first polymer selected from the group consisting of polyacrylonitrile (PAN), pitch, polyphenylene sulfide (PPS), viscose, cellulose, polyvinylidene chloride (PVDC), and polyvinyl alcohol (PVA), the nanostructures substantially aligned along a longitudinal axis of the continuous-filament finished fiber and polymer chains of the first polymer oriented in a direction parallel to the longitudinal axis of the continuous-filament finished fiber; and,
an outer-volume portion having a second outer diameter and having a second polymer selected from the group consisting of polyacrylonitrile (PAN), pitch, polyphenylene sulfide (PPS), viscose, cellulose, polyvinylidene chloride (PVDC), and polyvinyl alcohol (PVA), the outer-volume portion being in contact with and completely encompassing the inner-volume portion,
wherein the inner-volume portion has a greater tensile modulus and/or tensile strength than the outer-volume portion, and further wherein the first polymer and the second polymer are identical polymers.

2. The continuous-filament finished fiber of claim 1 wherein the polymer chains of the first polymer that are oriented in the direction parallel to the longitudinal axis of the continuous-filament finished fiber create a higher stiffness in the inner-volume portion and a lower stiffness at the outer surface of the outer-volume portion of the continuous-filament finished fiber.

3. The continuous-filament finished fiber of claim 1 wherein the first outer diameter has a length in a range of from about 2 micrometers to about 50 micrometers, and the second outer diameter has a length in a range of from about 2 micrometers to about 50 micrometers, wherein the length of the second outer diameter is greater than the length of the first outer diameter.

4. The continuous-filament finished fiber of claim 1 wherein the first polymer and the second polymer are polyacrylonitrile (PAN).

5. The continuous-filament finished fiber of claim 1 wherein each continuous-filament finished fiber is a carbon fiber or a carbon-based fiber.

6. The continuous-filament finished fiber of claim 1 wherein the first polymer and the second polymer are a melt-processable/spinnable polyacrylonitrile (PAN) or a solution spinnable polyacrylonitrile (PAN).

7. The continuous-filament finished fiber of claim 1 wherein each continuous-filament finished fiber has gradient properties that vary from the tensile modulus and the tensile strength that are higher in the inner-volume portion to the tensile modulus and the tensile strength that are lower at the outer-volume portion and that result in the continuous-filament finished fiber having an improved resistance to microfracture formation at a fiber-matrix interface between the continuous-filament finished fiber and a resin matrix, as compared to a continuous-filament finished fiber having an inner-volume portion with one or more first polymers and an outer-volume portion with one or more second polymers, each of the first polymers and the second polymers being an identical polymer or polymers, and the continuous-filament finished fiber not having nanostructures in the inner-volume portion that act as a nucleating agent for orientation of the first polymers in the inner-volume portion.

8. A continuous-filament finished carbon fiber consisting of:
an inner core portion having a plurality of carbon nanotubes and a first polymer selected from the group consisting of polyacrylonitrile (PAN), pitch, polyphenylene sulfide (PPS), viscose, cellulose, polyvinylidene chloride (PVDC), and polyvinyl alcohol (PVA), the carbon nanotubes substantially aligned along a longitudinal axis of the continuous-filament finished carbon fiber and polymer chains of the first polymer oriented in a direction parallel to the longitudinal axis of the continuous-filament finished carbon fiber; and,
an outer sheath portion having a second polymer selected from the group consisting of polyacrylonitrile (PAN), pitch, polyphenylene sulfide (PPS), viscose, cellulose, polyvinylidene chloride (PVDC), and polyvinyl alcohol (PVA), the outer sheath portion being in contact with and cylindrically encompassing the inner core portion,
wherein the inner core portion has a greater tensile modulus and/or tensile strength than the outer sheath portion, and further wherein the first polymer and the second polymer are identical polymers.

9. The continuous-filament finished carbon fiber of claim 8 wherein the polymer chains of the first polymer that are oriented in the direction parallel to the longitudinal axis of the continuous-filament finished fiber create a higher stiffness in the inner core portion and a lower stiffness at the outer surface of the outer sheath portion of each continuous-filament finished carbon fiber.

10. The continuous-filament finished carbon fiber of claim 8 wherein the first polymer and the second polymer are polyacrylonitrile (PAN).

11. The continuous-filament finished carbon fiber of claim 8 wherein the first polymer and the second polymer are polyphenylene sulfide (PPS).

12. The continuous-filament finished carbon fiber of claim 8 wherein the continuous-filament finished carbon fiber has gradient properties that vary from the tensile modulus and the tensile strength that are higher in the inner core portion to the tensile modulus and the tensile strength that are lower at the outer sheath portion and that result in the continuous-filament finished carbon fiber having an improved resistance to microfracture formation at a fiber-matrix interface between the continuous-filament finished carbon fiber and a resin matrix, as compared to a continuous-filament finished carbon fiber having an inner core portion with a plurality of first polymers and an outer sheath portion with a plurality of second polymers, each of the first polymers and the second polymers being a same polymer, and the continuous-filament finished carbon fiber not having carbon nanotubes in the inner core portion that act as a nucleating agent for orientation of the first polymers in the inner core portion.

13. A composite part comprising:
a plurality of continuous-filament finished carbon-based fibers, at least one continuous-filament finished carbon-based fiber consisting of:
an inner-volume portion having a first outer diameter and having a plurality of nanostructures selected from the group consisting of nanotubes, carbon nanotubes, halloysite nanotubes, and boron nitride nanotubes, and having a first polymer selected from the group consisting of polyacrylonitrile (PAN), pitch, polyphenylene sulfide (PPS), viscose, cellulose, polyvinylidene chloride (PVDC), and polyvinyl alcohol (PVA), the nanostructures substantially aligned along a longitudinal axis of the continuous-filament finished carbon-based fiber and polymer chains of the first polymer oriented in a direction parallel to the longitudinal axis of the continuous-filament finished carbon-based fiber; and,
an outer-volume portion having a second outer diameter and having a second polymer selected from the group consisting of polyacrylonitrile (PAN), pitch, polyphenylene sulfide (PPS), viscose, cellulose, polyvinylidene chloride (PVDC), and polyvinyl alcohol (PVA), the outer-volume portion being in contact with and completely encompassing the inner-volume portion,
wherein the inner-volume portion has a greater tensile modulus and/or tensile strength than the outer-

Assignees

• Tsotsis Thomas Karl
• Boeing Co

Inventors

• Tsotsis Thomas Karl

Classifications

• D01F8/00

  Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof · CPC title

• Y10T428/2918

  including free carbon or carbide or therewith [not as steel] · CPC title

• D01F1/10 Primary

  Other agents for modifying properties · CPC title

• Y10T428/2916

  including boron or compound thereof [not as steel] · CPC title

• Y10T428/2929

  Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type] · CPC title