Hydrocarbon processing apparatuses and processes for producing N-pentane and isobutane

Patent metadata

Field	Value
Publication number	US-9682901-B2
Application number	US-201414586409-A
Country	US
Kind code	B2
Filing date	Dec 30, 2014
Priority date	Dec 30, 2014
Publication date	Jun 20, 2017
Grant date	Jun 20, 2017

Abstract

Hydrocarbon processing apparatuses and processes for producing n-pentane and isobutane are provided herein. In an embodiment, a process for producing n-pentane and isobutane includes providing a hydrocarbon feed stream that includes C4 and C5 hydrocarbons. A recycle stream that includes C4+ hydrocarbons and the hydrocarbon feed stream is combined to produce a combined feed stream. The combined feed stream is separated to produce an iC4 product stream, an nC5+ product stream, and an iC5/nC4 feed stream. The iC5/nC4 feed stream is simultaneously disproportionated and isomerized in an isomerization zone to produce an intermediate stream that includes C3-C6 hydrocarbons. The C3-C6 hydrocarbons in the intermediate stream are separated to produce a C3− stream and the recycle stream that includes C4+ hydrocarbons.

First claim

What is claimed is:

1. A process for producing n-pentane and isobutane, wherein the process comprises:
providing a hydrocarbon feed stream comprising C4 and C5 hydrocarbons;
combining a recycle stream comprising C4+ hydrocarbons and the hydrocarbon feed stream to produce a combined feed stream;
separating the combined feed stream to produce an iC4 product stream, an nC5+ product stream, and an iC5/nC4 feed stream;
simultaneously disproportionating and isomerizing the iC5/nC4 feed stream in an isomerization zone substantially in the absence of water and in the presence of hydrogen to produce an intermediate stream comprising C3-C6 hydrocarbons; and
separating the C3-C6 hydrocarbons in the intermediate stream to produce a C3− stream and the recycle stream comprising C4+ hydrocarbons.

2. The process of claim 1 , further comprising maintaining a hydrogen to hydrocarbon ratio in the intermediate stream produced by simultaneously disproportionating and isomerizing the iC5/nC4 feed stream.

3. The process of claim 1 , wherein simultaneously disproportionating and isomerizing the iC5/nC4 feed stream comprises simultaneously disproportionating and isomerizing the iC5/nC4 feed stream at a first set of operating variables comprising temperature, liquid hourly space velocity, and disproportionation inhibitor content of the iC5/nC4 feed stream to produce a first yield of n-pentane and isobutane.

4. The process of claim 3 , further comprising adjusting one or more of the temperature, liquid hourly space velocity, or disproportionation inhibitor content of the iC5/nC4 feed stream from the first set of operating variables to produce a second yield of n-pentane and isobutane different from the first yield.

5. The process of claim 4 , wherein adjusting the one or more of the temperature, liquid hourly space velocity, or cyclics content comprises increasing the liquid hourly space velocity and/or including disproportionation inhibitor in the iC5/nC4 feed stream to reduce the isobutane content and increase n-pentane content in the second yield as compared to the first yield produced at the first set of operating variables.

6. The process of claim 1 , wherein simultaneously disproportionating and isomerizing the iC5/nC4 feed stream comprises simultaneously disproportionating and isomerizing the iC5/nC4 feed stream comprising a disproportionation inhibitor.

7. The process of claim 6 , wherein the disproportionation inhibitor consists of cyclic and/or paraffin hydrocarbons chosen from cyclopentane, methylcyclopentane, cyclohexane, benzene, C7+ paraffins, C7+ cyclic hydrocarbons, and combinations thereof, and wherein simultaneously disproportionating and isomerizing the iC5/nC4 feed stream comprises simultaneously disproportionating and isomerizing the iC5/nC4 feed stream comprising the disproportionation inhibitor.

8. The process of claim 6 , further comprising combining the disproportionation inhibitor and the iC5/nC4 feed stream after producing the iC5/nC4 feed stream.

9. The process of claim 1 , wherein providing the hydrocarbon feed stream comprises providing a hydrotreated naphtha stream comprising C4 and C5 hydrocarbons.

10. The process of claim 1 , wherein separating the combined feed stream comprises fractionating the combined feed stream to produce the iC4 product stream, the nC5+ product stream, and the iC5/nC4 feed stream.

11. The process of claim 1 , wherein separating the combined feed stream comprises separating the combined feed stream after combining the recycle stream and the hydrocarbon feed stream in the absence of intermediate reaction stages.

12. The process of claim 1 , further comprising providing the nC5+ product stream to a gasoline blending stage.

13. The process of claim 1 , further comprising providing the iC4 product stream to an alkylation stage and/or a dehydrogenation stage.

14. A process for isomerizing an iC5/nC4 feed stream, wherein the process comprises:
providing a hydrocarbon feed stream comprising C4 and C5 hydrocarbons;
combining a C4+ stream comprising isobutane and the hydrocarbon feed stream to produce a combined feed stream;
removing n-butane and isopentane from the combined feed stream to produce the iC5/nC4 feed stream, wherein the n-butane and isopentane are removed from the combined feed stream after combining the C4+ stream and the hydrocarbon feed stream in the absence of an intermediate reaction of components in the combined feed stream prior to removing the n-butane and isopentane therefrom; and
simultaneously disproportionating and isomerizing the iC5/nC4 feed stream to produce an intermediate stream comprising C3-C6 hydrocarbons.

Assignees

• Uop Llc

Inventors

• Lapinski Mark Paul
• Lowry David
• Lippmann Matthew
• Shecterle David James

Classifications

• C07C6/10

  in hydrocarbons containing no six-membered aromatic rings · CPC title

• C07C5/2791 Primary

  with metals · CPC title

• B01J2219/00006

  Large-scale industrial plants · CPC title

• C07C2521/04

  Alumina · CPC title

• C07C2523/42

  Platinum · CPC title