Sour syngas treatment apparatuses and processes for treating sour syngas comprising sulfur components and carbon dioxide

Patent metadata

Field	Value
Publication number	US-9682343-B2
Application number	US-201514682636-A
Country	US
Kind code	B2
Filing date	Apr 9, 2015
Priority date	Apr 9, 2015
Publication date	Jun 20, 2017
Grant date	Jun 20, 2017

Abstract

Sour syngas treatment apparatuses and processes for treating a sour syngas stream are provided herein. In an embodiment, a process for treating a sour syngas stream that includes sulfur components and carbon dioxide includes absorbing the sulfur components and carbon dioxide from the sour syngas stream in a primary liquid/vapor phase absorption stage with a solvent to produce a liquid absorbent stream. The liquid absorbent stream includes the solvent, the sulfur components, and carbon dioxide. A portion of the sulfur components from the liquid absorbent stream is directly oxidized in the presence of a direct oxidation catalyst to produce elemental sulfur and a recycle stream. The recycle stream includes an unconverted portion of the sulfur components and carbon dioxide. The recycle stream is recycled for further absorption of the unconverted portion of the sulfur components and carbon dioxide through liquid/vapor phase absorption.

First claim

What is claimed is:

1. A process for treating a sour syngas stream comprising sulfur components and carbon dioxide, wherein the process comprises the steps of:
absorbing the sulfur components and carbon dioxide from the sour syngas stream in a primary liquid/vapor phase absorption stage with a solvent to produce a liquid absorbent stream comprising the solvent, the sulfur components, and carbon dioxide;
directly oxidizing a portion of the sulfur components from the liquid absorbent stream in the presence of a direct oxidation catalyst to produce elemental sulfur and a recycle stream comprising an unconverted portion of the sulfur components and carbon dioxide; and
recycling the recycle stream for further absorption of the unconverted portion of the sulfur components and carbon dioxide through liquid/vapor phase absorption.

2. The process of claim 1 , wherein directly oxidizing the portion of the sulfur components from the liquid absorbent stream comprises directly oxidizing the portion of the sulfur components from the liquid absorbent stream in the absence of a combustion stage prior to directly oxidizing the portion of the sulfur components from the liquid absorbent stream.

3. The process of claim 1 , further comprising separating the sulfur components and carbon dioxide from the liquid absorbent stream in a thermal regeneration stage to produce an acid gas stream comprising the sulfur components, carbon dioxide, and water, and wherein directly oxidizing the portion of the sulfur components from the liquid absorbent stream comprises directly oxidizing the portion of the sulfur components from the acid gas stream.

4. The process of claim 3 , wherein separating the sulfur components and carbon dioxide from the liquid absorbent stream in the thermal regeneration stage provides the acid gas stream with the sulfur components present in an amount of from about 0.5 to about 15 weight % based upon the total weight of the acid gas stream.

5. The process of claim 3 , wherein separating the sulfur components and carbon dioxide from the liquid absorbent stream in the thermal regeneration stage comprises separating the liquid absorbent stream in the absence of a nitrogen stripping stage between the primary liquid/vapor phase absorption stage and the thermal regeneration stage.

6. The process of claim 3 , wherein separating the sulfur components and carbon dioxide from the liquid absorbent stream in the thermal regeneration stage comprises separating the liquid absorbent stream in the absence of a secondary liquid/vapor phase absorption stage between the primary liquid/vapor phase absorption stage and the thermal regeneration stage.

7. The process of claim 3 , wherein separating the sulfur components and carbon dioxide from the liquid absorbent stream in the thermal regeneration stage comprises separating the liquid absorbent stream in the absence of an intervening separation stage between the primary liquid/vapor phase absorption stage and the thermal regeneration stage.

8. The process of claim 3 , further comprising releasing carbon dioxide from the liquid absorbent stream in a secondary liquid/vapor phase absorption stage between the primary liquid/vapor phase absorption stage and the thermal regeneration stage.

9. The process of claim 8 , wherein recycling the recycle stream comprises recycling the recycle stream to the secondary liquid/vapor phase absorption stage.

10. The process of claim 9 , wherein directly oxidizing the portion of the sulfur components from the liquid absorbent stream in the presence of the direct oxidation catalyst further comprises directly oxidizing the portion of the sulfur components exclusively with oxygen.

11. The process of claim 8 , further comprising stripping carbon dioxide from the liquid absorbent stream in a nitrogen stripping stage between the primary liquid/vapor phase absorption stage and the secondary liquid/vapor phase absorption stage to produce a carbon dioxide-rich stream and a sulfur-rich stream, wherein the carbon dioxide-rich stream is provided to the secondary liquid/vapor phase absorption stage.

12. The process of claim 1 , wherein recycling the recycle stream comprises recycling the recycle stream to the primary liquid/vapor phase absorption stage for separation along with the sour syngas stream.

13. The process of claim 1 , wherein absorbing the sulfur components and carbon dioxide from the sour syngas stream in the primary liquid/vapor phase absorption stage further produces a separated syngas stream depleted of sulfur-containing species and a portion of carbon dioxide present in the sour syngas stream.

14. The process of claim 1 , wherein directly oxidizing the portion of the sulfur components from the liquid absorbent stream comprises directly oxidizing hydrogen sulfide in the presence of the direct oxidation catalyst and oxygen to produce the elemental sulfur.

15. The process of claim 1 , wherein the unconverted portion of the sulfur components comprises one or more of carbonyl sulfide or sulfur dioxide, and wherein the process further comprises hydrogenating the recycle stream prior to further absorption of the unconverted portion of the sulfur components.

16. A process for treating a sour syngas stream comprising sulfur components and carbon dioxide, wherein the process comprises the steps of:
absorbing the sulfur components and carbon dioxide from the sour syngas stream in a primary liquid/vapor phase absorption stage with a solvent to produce a liquid absorbent stream comprising the solvent, the sulfur components, and carbon dioxide;
separating carbon dioxide from the liquid absorbent stream to produce a carbon dioxide stream and a sulfur-rich solvent stream comprising the solvent, the sulfur components, and carbon dioxide;
separating the sulfur components and carbon dioxide from the sulfur-rich solvent stream in a thermal regeneration stage to produce an acid gas stream comprising the sulfur components, carbon dioxide, and water, wherein the sulfur components are present in an amount of from about 0.5 to about 15 weight % based upon the total weight of the acid gas stream;
directly oxidizing a portion of the sulfur components from the acid gas stream in the presence of a direct oxidation catalyst to produce elemental sulfur and a recycle stream comprising an unconverted portion of the sulfur components and carbon dioxide;
recycling the recycle stream for further liquid/vapor phase absorption.

Assignees

• Uop Llc

Inventors

• Zhou Lubo
• Beuckels Bart
• Boehm Ernest James

Classifications

• B01D2257/302

  Sulfur oxides · CPC title

• B01D2252/2021

  Methanol · CPC title

• B01D2256/20

  Carbon monoxide · CPC title

• B01D2257/304

  Hydrogen sulfide · CPC title

• B01D53/1462 Primary

  Removing mixtures of hydrogen sulfide and carbon dioxide · CPC title