Bonding layer including particles having bimodal size distribution for solid oxide fuel-cells

Patent metadata

Field	Value
Publication number	US-9680157-B2
Application number	US-201414502441-A
Country	US
Kind code	B2
Filing date	Sep 30, 2014
Priority date	Sep 30, 2013
Publication date	Jun 13, 2017
Grant date	Jun 13, 2017

Abstract

A bonding layer used to join individually formed fuel cell units together to create a solid oxide fuel cell stack can include particles contained within a carrier material. The particles can have at least one material component in common with a porous electrode of a first type and a bimodal particle size distribution. In some embodiments, the particles of a first mode of the bimodal particle size distribution are small enough to fit at least partially into the porosity of the electrodes bonded together, while the particles of the second mode of the bimodal particle size distribution are larger than the porosity of the electrodes.

First claim

What is claimed is:

1. A solid oxide fuel cell stack comprising:
a first solid oxide fuel cell unit;
a second solid oxide fuel cell unit; and
a bonding layer coupled between an outer porous electrode layer of the first solid oxide fuel cell unit and an outer porous electrode layer of the second solid oxide fuel cell unit, the outer porous electrode layers of the first and second solid oxide fuel cell units having the same composition;
wherein the bonding layer includes a bonding material comprising particles having at least one material component in common with the composition of the outer porous electrode layers of the first and second solid oxide fuel cell units and wherein the particles have a bimodal particle size distribution.

2. The solid oxide fuel cell stack of claim 1 , wherein a thickness of the bonding layer is at least about 40 micrometers and no greater than about 305 micrometers.

3. The solid oxide fuel cell stack of claim 1 , wherein the bonding material includes a porosity of at least about 33 vol % and no greater than about 51 vol % of a total volume of the bonding material.

4. The solid oxide fuel cell stack of claim 1 , wherein particles of a first mode of the bimodal particle size distribution have a d50 of at least about 6.3 micrometers and no greater than about 10.3 micrometers.

5. The solid oxide fuel cell stack of claim 1 , wherein particles of a second mode of the bimodal particle size distribution have a d50 of at least about 15.9 micrometers and no greater than about 50.8 micrometers.

6. The solid oxide fuel cell stack of claim 1 , wherein the bonding material comprises at least about 38 wt % and no greater than about 61 wt % of the particles of a first mode of the bimodal particle size distribution for a total weight of the particles.

7. The solid oxide fuel cell stack of claim 1 , wherein the bonding material comprises at least about 37 wt % and no greater than about 59 wt % of the particles of a second mode of the bimodal particle size distribution for a total weight of the particles.

8. The solid oxide fuel cell stack of claim 1 , wherein the bonding material includes a content of particles of a first mode of the bimodal particle size distribution that is substantially equal to a content of particles of a second mode of the bimodal particle size distribution.

9. The solid oxide fuel cell stack of claim 1 , wherein the bonding layer comprises an ink including the bonding material.

10. The solid oxide fuel cell stack of claim 9 , wherein the ink includes at least about 64 wt % LSM particles and no greater than about 88 wt % LSM particles of a total weight of the ink.

11. The solid oxide fuel cell stack of claim 9 , wherein a viscosity of the ink is at least about 56 kilocentipoise (kcps) and no greater than about 196 kcps.

12. The solid oxide fuel cell of claim 1 , wherein the porous electrode layer of a first type is a cathode layer comprising lanthanum strontium manganite (LSM).

13. The solid oxide fuel cell of claim 12 , wherein the bonding layer includes at least about 80 wt % LSM particles, the LSM particles having the bimodal particle size distribution.

14. The solid oxide fuel cell of claim 1 , wherein the porous electrode layer of a first type is an anode layer comprising nickel and yttria-stabilized zirconia (Ni-YSZ).

15. The solid oxide fuel cell of claim 14 , wherein the bonding layer includes at least about 80 wt % Ni-YSZ particles, the Ni-YSZ particles having the bimodal particle size distribution.

16. A solid oxide fuel cell stack, comprising:
at least two fuel cell units, each fuel cell unit comprising at least one porous electrode layer of a first type and at least one porous electrode layer of a second type separated by an electrolyte layer; and
a bonding layer coupled between the at least two fuel cell units and bonding an outer surface of the at least one porous electrode layer of the first type in one of the at least two fuel cell units to an outer surface of the at least one porous electrode layer of the first type in another one of the at least two fuel cell units;
wherein the bonding layer comprises particles contained within a carrier material, the particles having at least one material component in common with the at least one porous electrode layer of the first type and wherein the particles have a bimodal particle size distribution in which particles of a first mode of the bimodal particle size distribution are small enough to fit at least partially into a porosity of the at least one porous electrode layer of the first type and in which particles of a second mode of the bimodal particle size distribution are larger than the porosity of the at least one porous electrode layer of the first type.

17. A method of bonding together a plurality of solid oxide fuel cell units to form a solid oxide fuel cell stack, the method comprising:
loading a first solid oxide fuel cell unit and a second solid oxide fuel cell unit into a stencil printing apparatus, each fuel cell unit having at least one porous electrode layer of a first type on an outer surface of the fuel cell unit;
providing an ink to the stencil printing apparatus, the ink including particles having at least one material component in common with a composition of the at least one porous electrode layer of the first type and the particles making up at least about 60 wt % of a total weight of the ink and having a bimodal particle size distribution;
applying, by the stencil printing apparatus, the ink to the at least one electrode layer of the first type on the outer surfaces of the first and second solid oxide fuel cell units; and
bonding the at least one porous electrode layer of the first type of the first solid oxide fuel cell unit to the at least one porous electrode layer of the first type of the second solid oxide fuel cell unit to form the solid oxide fuel cell stack;
wherein a drying rate of the ink is controlled so that the ink has not dried when the at least one porous electrode layer of the first solid oxide fuel cell unit is bonded to the at least one porous electrode layer of the second solid oxide fuel cell unit.

18. The method of claim 17 , wherein bonding the at least one porous electrode layer of the first type of the first solid oxide fuel cell unit to the at least one porous electrode layer of the first type of the second solid oxide fuel cell unit comprises:
bringing printed sides of the fuel cell units together while the ink on each surface is still wet;
pressing the fuel cell units together at a pressure of about 1-2 psi for about 1-2 hours at room temperature to partially bond the fuel cell units;
heating the partially bonded fuel cell units within a range of approximately 1050° C. to approximately 1350° C. for two hours without any applied pressure; and
heating the fuel cell units within a range of approximately 1250° C. to approximately 1350° C. for about 1 to 3 hours at a pressure of at least about 0.1 MPa.

19. The method of claim 17 , further comprising mixing and de-airing the ink before applying the ink to the at least one porous electrode layers of the first and second solid oxide fuel cell units.

20. The method of claim 17 , further comprising:
placing a first stencil on the at least one porous electrode layer of the first type on the outer surface of the first solid oxide fuel cell unit before applying the ink to the at least one porous electrode layer of the first solid oxide fuel cell unit; and
placing a second stencil on the at least one porous electrode layer of the fi

Assignees

• Saint-Gobain Ceram & Plastics Inc

Inventors

• Zandi Morteza

Classifications

• H01M4/9033 Primary

  Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites · CPC title

• H01M8/2425 Primary

  High-temperature cells with solid electrolytes · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M4/9066

  of metal-ceramic composites or mixtures, e.g. cermets · CPC title

• H01M8/0297

  Arrangements for joining electrodes, reservoir layers, heat exchange units or bipolar separators to each other (H01M8/0271 takes precedence) · CPC title