Polarizing plate protective film, polarizing plate and display device

Patent metadata

Field	Value
Publication number	US-9678249-B2
Application number	US-201615082730-A
Country	US
Kind code	B2
Filing date	Mar 28, 2016
Priority date	Mar 30, 2015
Publication date	Jun 13, 2017
Grant date	Jun 13, 2017

Abstract

A polarizing plate protective film contains a compound represented by general formula (II-1) or (II-2). In general formulas (II-1) and (II-2), X represents a 6-membered cyclic acetal group; n represents an integer of 2 or more; and a plurality of Xs may be identical or different. In general formula (II-1), Z 2 represents a linking group having a valence of n; R 1 represents a substituent, when there are a plurality of R 1 s, at least two of the plurality of R 1 s may be taken together to form a ring, R 1 s in different benzene rings may be taken together to form a single bond; m represents an integer of 0-4; and the plurality of R 1 s may be identical or different. In general formula (II-2), Z 3 represents an alkylene group having a valence of n, provided that Z 3 does not have a ring structure.

First claim

What is claimed is:

1. A polarizing plate protective film comprising:
a compound represented by general formula (II-1) or (II-2) shown below:

[(in general formulas (II-1) and (II-2), X represents a group represented by general formula (I-A-3) shown below; n represents an integer of 2 or more; and a plurality of Xs are identical or different;
in general formula (II-1), Z 2 represents a linking group having a valence of n; R 1 represents a substituent; m represents an integer of 0-4; and the plurality of R 1 s are identical or different;
in general formula (II-2), Z 3 represents an alkylene group having a valence of n, provided that Z 3 does not have a ring structure;

(in general formula (I-A-3), R C7 to R C12 each independently represent a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, an acyl group, an alkoxy group, or an alkoxycarbonyl group; * indicates a bonding arm which is bonded to a benzene ring in general formula (II-1) or Z 3 in general formula (II-2))].

2. The polarizing plate protective film according to claim 1 , wherein the compound represented by general formula (II-1) or (II-2) has 2 to 4 Xs and a total number of carbon atoms in a constituent moiety other than the Xs is 40 or less.

3. The polarizing plate protective film according to claim 1 , wherein a number of atoms in a shortest linking path linking two Xs together is 20 or less in every path between two Xs.

4. The polarizing plate protective film according to claim 2 , wherein a number of atoms in a shortest linking path linking two Xs together is 20 or less in every path between two Xs.

5. The polarizing plate protective film according to claim 1 , wherein Z 2 shown above is any one of or any combination of —O—, —S—, —SO—, —SO 2 —, —C(═O)—, —OC(═O)—, —C(R 11 )(R 12 )—, >C<, (—OCH 2 CH 2 ) 2 C(CH 2 CH 2 O—) 2 , >C(R 13 )—, >N—, and —N(Ra)—, where R 11 to R 13 each independently represent a hydrogen atom, an alkyl group or an aryl group, and Ra represents a hydrogen atom, an alkyl group, an aryl group, or an acyl group.

6. The polarizing plate protective film according to claim 2 , wherein Z 2 shown above is any one of or any combination of —O—, —S—, —SO—, —SO 2 —, —C(═O)—, —OC(═O)—, —C(R 11 )(R 12 )—, >C<, (—OCH 2 CH 2 ) 2 C(CH 2 CH 2 O—) 2 , >C(R 13 )—, >N—, and —N(Ra)—, where R 11 to R 13 each independently represent a hydrogen atom, an alkyl group or an aryl group, and Ra represents a hydrogen atom, an alkyl group, an aryl group, or an acyl group.

7. The polarizing plate protective film according to claim 3 , wherein Z 2 shown above is any one of or any combination of —O—, —S—, —SO—, —SO 2 —, —C(═O)—, —OC(═O)—, —C(R 11 )(R 12 )—, >C<, (—OCH 2 CH 2 ) 2 C(CH 2 CH 2 O—) 2 , >C(R 13 )—, >N—, and —N(Ra)—, where R 11 to R 13 each independently represent a hydrogen atom, an alkyl group or an aryl group, and Ra represents a hydrogen atom, an alkyl group, an aryl group, or an acyl group.

8. The polarizing plate protective film according to claim 4 , wherein Z 2 shown above is any one of or any combination of —O—, —S—, —SO—, —SO 2 —, —C(═O)—, —OC(═O)—, —C(R 11 )(R 12 )—, >C<, (—OCH 2 CH 2 ) 2 C(CH 2 CH 2 O—) 2 , >C(R 13 )—, >N—, and —N(Ra)—, where R 11 to R 13 each independently represent a hydrogen atom, an alkyl group or an aryl group, and Ra represents a hydrogen atom, an alkyl group, an aryl group, or an acyl group.

9. The polarizing plate protective film according to claim 1 , further comprising cellulose acylate.

10. The polarizing plate protective film according to claim 2 , further comprising cellulose acylate.

11. The polarizing plate protective film according to claim 3 , further comprising cellulose acylate.

12. The polarizing plate protective film according to claim 4 , further comprising cellulose acylate.

13. A polarizing plate comprising:
a polarizer; and
one or more polarizing plate protective films applied on one or both surfaces of the polarizer,
wherein at least one of the one or more polarizing plate protective films is the polarizing plate protective film according to claim 1 .

14. A polarizing plate comprising:
a polarizer; and
one or more polarizing plate protective films applied on one or both surfaces of the polarizer,
wherein at least one of the one or more polarizing plate protective films is the polarizing plate protective film according to claim 2 .

15. The polarizing plate according to claim 13 , wherein the at least one of the one or more polarizing plate protective films contains a compound represented by general formula (A) shown below:

(in general formula (A), R A1 and R A3 each independently represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group or an aromatic group, and the alkyl group, the cycloalkyl group, the alkenyl group and the aromatic group may each have a substituent; R A5 represents a hydrogen atom or a substituent).

16. The polarizing plate according to claim 14 , wherein the at least one of the one or more polarizing plate protective films contains a compound represented by general formula (A) shown below:

(in general formula (A), R A1 and R A3 each independently represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group or an aromatic group, and the alkyl group, the cycloalkyl group, the alkenyl group and the aromatic group may each have a substituent; R A5 represents a hydrogen atom or a substituent).

17. A display device comprising:
at least one polarizing plate according to claim 13 .

18. A display device comprising:
at least one polarizing plate according to claim 14 .

19. A display device comprising:
at least one polarizing plate according to claim 15 .

20. A display device comprising:
at least one polarizing plate according to claim 16 .

Assignees

• Fujifilm Corp

Inventors

• Yoshida Aiko
• Shimoju Naoya
• Sano Naoki
• Fukagawa Nobutaka

Classifications

• G02B1/14 Primary

  Protective coatings, e.g. hard coatings · CPC title

• G02B5/3033

  in the form of a thin sheet or foil, e.g. Polaroid · CPC title