Fracturing fluids and methods for treating hydrocarbon-bearing formations

Patent metadata

Field	Value
Publication number	US-9676995-B2
Application number	US-201213537800-A
Country	US
Kind code	B2
Filing date	Jun 29, 2012
Priority date	Jun 29, 2012
Publication date	Jun 13, 2017
Grant date	Jun 13, 2017

Abstract

Disclosed herein is a fracturing fluid comprising a carrier fluid; a polymer that is soluble in the carrier fluid; the polymer being a synthetic polymer; the synthetic polymer being operative to increase the viscosity of the carrier fluid to about 5 to about 50 centipoise; the fracturing fluid being operative to reduce friction during a downhole fracturing operation and to transport a proppant during the downhole fracturing operation.

First claim

What is claimed is:

1. A method for treating a hydrocarbon-bearing formation comprising:
blending a carrier fluid with a copolymer and a breaking agent to form a fracturing fluid, the copolymer being a synthetic polymer, the synthetic polymer comprising a labile group, the labile group comprising ester groups, carbonate groups, azo groups, disulfide groups, orthoester groups, acetal groups, etherester groups, ether groups, silyl groups, phosphazine groups, urethane groups, esteramide groups, etheramide groups, anhydride groups, a derivative thereof, or a combination thereof; the breaking agent comprising an oxidant, an acid, or an enzyme; and the breaking agent and the labile group being selected such that the breaking agent is effective to activate the labile group and the activated labile group facilitates the decomposition of the synthetic polymer;
injecting the fracturing fluid into the hydrocarbon-bearing formation, the fracturing fluid having a viscosity of about 5 to about 50 centipoise during injection;
discharging the fracturing fluid into a downhole fracture in the hydrocarbon-bearing formation, wherein the fracturing fluid is operative to reduce friction during a hydrocarbon-bearing treatment operation;
activating the labile group on the synthetic polymer with the breaking agent,
decomposing the synthetic polymer upon activation of the labile group to provide a decomposed polymer; and
removing the decomposed polymer from the hydrocarbon-bearing formation,
wherein the synthetic polymer is devoid of guar.

2. The method of claim 1 , wherein upon activation of the labile group, the viscosity of the fracturing fluid is reduced to 2 centipoise or less.

3. The method of claim 1 , wherein the fracturing fluid is free of a crosslinking agent.

4. The method of claim 1 , wherein the fracturing fluid is free of a naturally occurring polymer.

5. The method of claim 1 , wherein the fracturing fluid exhibits a maximum viscosity at ambient temperature of equal to or greater than about 8 centipoise after about 30 seconds following an introduction of the polymer into the carrier fluid.

6. The method of claim 1 , wherein the synthetic polymer is a water-soluble polymer.

7. The method of claim 6 , wherein the synthetic polymer comprises polyacrylamide, polyvinyl alcohol, poly(acrylamide/acrylic acid), potassium salt, poly acrylic acid, polydiallyl dimethyl ammonium chloride, poly(1-glycerol methacrylate), poly(2-dimethylaminoethyl methacrylate), poly(2-ethyl-2-oxazoline), poly(2-ethyl-2-oxazoline), poly(2-hydroxyethyl methacrylate/methacrylic acid), poly(2-hydroxypropyl methacrylate), poly(2-methacryloxyethyltrimethylammonium bromide), poly(2-vinyl-1-methylpyridinium bromide), poly(2-vinylpyridine N-oxide), poly(2-vinylpyridine), poly(3-chloro-2-hydroxypropyl-2-methacryloxyethyldimethylammonium chloride) or a combination comprising at least one of the foregoing.

8. The method of claim 1 , wherein the synthetic polymer has a number average molecular weight of about 2,000,000 to about 20,000,000 grams per mole.

9. The method of claim 1 , wherein the synthetic polymer is present in an amount of about 0.1 wt % to about 10 wt %, based on the total weight of the fracturing fluid.

10. The method of claim 1 , wherein the synthetic polymer is a polyacrylamide copolymer.

11. The method of claim 1 , wherein the viscosity of the carrier fluid is increased by about 100% to about 900% in about 50 to about 100 seconds upon introduction of the copolymer to the carrier fluid.

12. The method of claim 1 , wherein the fracturing fluid reaches about 85% or greater of a maximum viscosity attainable for a given concentration of the copolymer in the carrier fluid, where the maximum viscosity is measured at about 45° F., about 30 seconds after the copolymer first contacts the carrier fluid.

13. The method of claim 1 , wherein the fracturing fluid reaches its maximum viscosity within 10 to 40 seconds after introduction of the copolymer into the carrier fluid.

14. The method of claim 1 , wherein the fracturing fluid is a gel, a slurry or a combination of at least one of the foregoing.

15. The method of claim 1 , wherein the carrier fluid is slickwater having a viscosity of less than 3 centipoise.

16. The method of claim 1 , wherein the breaker is activated at a temperature of 50° C. or greater.

17. The method of claim 1 , wherein a solubility parameter of the copolymer is within about 25% of a solubility parameter of the carrier fluid.

18. A method for treating a hydrocarbon-bearing formation comprising:
blending slickwater having a viscosity of less than about 3 centipoise with a copolymer and a breaking agent to form a fracturing fluid, the copolymer being a synthetic polymer, the synthetic polymer comprising a labile group, the labile group comprising ester groups, amide groups, carbonate groups, azo groups, disulfide groups, orthoester groups, acetal groups, etherester groups, ether groups, silyl groups, phosphazine groups, urethane groups, esteramide groups, etheramide groups, anhydride groups, a derivative thereof, or a combination thereof; the breaking agent comprising an oxidant, an acid, or an enzyme; and the breaking agent and the labile group being selected such that the breaking agent is effective to activate the labile group and the activated labile group facilitates the decomposition of the synthetic polymer;
injecting the fracturing fluid into the hydrocarbon-bearing formation, the fracturing fluid having a viscosity of about 5 to about 50 centipoise during injection;
discharging the fracturing fluid into a downhole fracture in the hydrocarbon-bearing formation, wherein the fracturing fluid is operative to reduce friction during a hydrocarbon-bearing treatment operation;
activating the labile group on the synthetic polymer with the breaking agent, wherein upon activation of the labile group, the viscosity of the fracturing fluid is reduced to 2 centipoise or less;
decomposing the synthetic polymer upon activation of the labile group to provide a decomposed polymer; and
removing the decomposed polymer from the hydrocarbon-bearing formation,
wherein the synthetic polymer is present in an amount of about 0.1 wt % to about 10 wt %, based on the total weight of the fracturing fluid; and
the fracturing fluid reaches its maximum viscosity within 10 to 40 seconds after introduction of the copolymer into the carrier fluid.

19. The method of claim 18 , wherein the fracturing fluid reaches its maximum viscosity when the fracturing fluid penetrates the downhole fracture.

20. The method of claim 18 , wherein the breaking agent comprises sodium bromate, potassium bromate, or a combination comprising at least one of the foregoing.

Assignees

• Sun Hong
• Debenedictis Frances
• Zhou Jia
• Nelson Scott
• Royce Tom N
• Qu Qi
• Baker Hughes Inc

Inventors

• Sun Hong
• Debenedictis Frances
• Zhou Jia
• Nelson Scott
• Royce Tom N
• Qu Qi

Classifications

• C09K2208/24

  Bacteria or enzyme containing gel breakers · CPC title

• C09K2208/28

  Friction or drag reducing additives · CPC title

• C09K8/882 Primary

  obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C09K2208/26

  Gel breakers other than bacteria or enzymes · CPC title

• C09K8/725

  Compositions containing polymers · CPC title