Process for producing polyether polyol, process for producing flexible polyurethane foam, and seat

Patent metadata

Field	Value
Publication number	US-9676897-B2
Application number	US-201314041553-A
Country	US
Kind code	B2
Filing date	Sep 30, 2013
Priority date	Mar 30, 2011
Publication date	Jun 13, 2017
Grant date	Jun 13, 2017

Abstract

To suppress deterioration of mechanical properties of a foam, by using a polyol system solution stored.
A polyol system solution is prepared by using a polyether polyol (A1) having a hydroxy value of from 5 to 45 mgKOH/g and an average number of hydroxy groups of from 2 to 8, obtainable by subjecting an alkylene oxide to ring-opening addition polymerization to an initiator, in the presence of a double metal cyanide complex catalyst, to obtain an intermediate polyol; and subjecting ethylene oxide to a ring-opening addition polymerization in an amount of from 1 to 23 mol per 1 mol of the initiator to the intermediate polyol, in the presence of an alkali metal hydroxide as a polymerization catalyst, and a flexible polyurethane foam is produced by using the polyol system solution.

First claim

What is claimed is:

1. A process for producing a polyether polyol, the process comprising:
subjecting a propylene oxide to ring-opening addition polymerization with respect to an initiator having an average number of hydroxyl groups of from 2 to 8, in the presence of a double metal cyanide complex catalyst in a form of slurry, to obtain an intermediate polyol; and
subjecting ethylene oxide to ring-opening addition polymerization with respect to the intermediate polyol in the presence of an alkali metal hydroxide as a polymerization catalyst, to obtain a polyether polyol (A1) having a hydroxyl value of from 5 to 24 mgKOH/g, wherein the polyether polyol (A1) comprises a terminal ethylene oxide addition in molar amount of from 19.1 to 23 mol per mol of the initiator provided in the ring-opening addition polymerization of the propylene oxide,
wherein no alkylene oxides other than propylene oxide are added in the presence of the double metal cyanide complex catalyst before subjecting ethylene oxide to ring-opening addition polymerization with respect to the intermediate polyol, and
wherein the intermediate polyol is obtained by:
supplying and reacting a part of the propylene oxide in a reaction fluid comprising the initiator and the double metal cyanide complex catalyst, wherein the maximum temperature of the reaction fluid reached during the reaction of the part of the propylene oxide is higher by from 15 to 50° C. than the initial temperature of the reaction fluid immediately before supplying the part of propylene oxide; and
supplying the remaining part of the propylene oxide after the reaction of the part of the propylene oxide, and carrying out ring-opening addition polymerization in the presence of the double metal cyanide complex catalyst.

2. The process according to claim 1 , wherein an amount of the part of the propylene oxide provided is from 5 to 20 parts by mass per 100 parts by mass of the initiator contained in the reaction fluid, and the initial temperature of the reaction fluid is from 120 to 165° C.

3. The process according to claim 1 , wherein the double metal cyanide complex catalyst has tert-butyl alcohol as an organic ligand.

4. The process according to claim 1 , wherein the amount of the ethylene oxide is from 19.1 to 21.8 mol per mol of the initiator provided in the ring-opening addition polymerization of the propylene oxide.

5. The process according to claim 1 , wherein the hydroxyl value of the initiator provided in the ring-opening addition polymerization of the propylene oxide is not more than 6, 300 mgKOH/g.

6. The process according to claim 1 , wherein the hydroxyl value of the initiator provided in the ring-opening addition polymerization of the propylene oxide is not more than 300 mgKOH/g.

7. The process according to claim 1 , wherein the hydroxyl value of the initiator provided in the ring-opening addition polymerization of the propylene oxide is not more than 187 mgKOH/g.

8. The process according to claim 1 , wherein a total amount of metals derived from the double metal cyanide complex catalyst in the polyether polyol (A1) at a time of completion of the ring opening addition polymerization of ethylene oxide to the intermediate polyol is 1 to 30 ppm.

9. The process according to claim 1 , wherein removal of the double metal cyanide complex catalyst and/or deactivation of the double metal cyanide complex catalyst from the intermediate polyol is carried out before subjecting ethylene oxide to ring-opening addition polymerization to the intermediate polyol.

10. The process according to claim 1 , wherein the initial temperature of the reaction fluid is from 120 to 165° C.

11. A process for producing a flexible polyurethane foam, the process comprising: reacting a polyol (A) with a polyisocyanate (B) in the presence of a catalyst (C) and a blowing agent (D), wherein the polyol (A) comprises the polyether polyol (A1) obtained by the process as defined in claim 1 in an amount of from 2 to 100 mass % based on the total amount of the polyol (A).

12. The process according to claim 11 , wherein the blowing agent (D) consists of water.

13. The process according to claim 11 , wherein the amount of the polyether polyol (A1) is from 50 to 100 mass % based on the total amount of the polyol (A).

14. The process according to claim 11 , wherein the polyol (A) further comprises polymer fine particles (H) in an amount of more than 0 mass % and at most 30 mass %.

15. The process according to claim 14 , wherein the polyol (A) further comprises polymer-dispersed polyol (A21) which comprises: a polyol (A2) which is a polyol other than the polyol (A1); and the polymer fine particles (H) dispersed in the polyol (A2).

16. A seat comprising the flexible polyurethane foam produced by the process as defined in claim 11 .

17. An automobile part comprising the seat according to 16 .

Assignees

• Asahi Glass Co Ltd

Inventors

• Sasaki Takayuki
• Ito Takashi
• Horie Akio
• Suzuki Chitoshi
• Arai Takeaki
• Furumi Masahito

Classifications

• C08G18/4866

  having a low unsaturation value · CPC title

• C08G18/4072 Primary

  Mixtures of compounds of group C08G18/63 with other macromolecular compounds · CPC title

• C08J9/00

  Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof (mechanical aspects of shaping of plastics or substances in a plastic state for the production of porous or cellular articles B29C) · CPC title

• C08G2101/0008

  Chemistry & Metallurgy · mapped topic

• C08G18/4845

  containing oxypropylene or higher oxyalkylene end groups · CPC title