Solid polyaluminoxane composition, olefin polymerization catalyst, olefin polymer production method and solid polyaluminoxane composition production method

Patent metadata

Field	Value
Publication number	US-9676879-B2
Application number	US-201414766396-A
Country	US
Kind code	B2
Filing date	Feb 7, 2014
Priority date	Feb 8, 2013
Publication date	Jun 13, 2017
Grant date	Jun 13, 2017

Abstract

An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25° C. of less than 0.50 mol % as measured by a specific method (i), a solubility in toluene at 25° C. of less than 1.0 mol % as measured by a specific method (ii), and a 13 mol % or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d 8 soluble components by a specific method (iii).

First claim

The invention claimed is:

1. A solid polyaluminoxane composition production method comprising:
a step of contacting a polyaluminoxane composition solution (A) including a polyalkylaluminoxane, a trialkylaluminum and a hydrocarbon solvent, with at least one organic compound (B) containing a Group 15-17 element in the periodic table;
a step of precipitating a solid polyaluminoxane composition by reacting the compounds with an aluminum-carbon bond present in the polyaluminoxane composition solution (A) with the organic compound (B) under heating conditions at 40° C. or above; and
a step of thermally aging the precipitate at 90 to 200° C. after the precipitation step.

2. The solid polyaluminoxane composition production method according to claim 1 , wherein the organic compound (B) is an oxygen-containing organic compound (C).

3. The solid polyaluminoxane composition production method according to claim 2 , wherein the oxygen-containing organic compound (C) is one or more selected from the group consisting of aldehyde-containing organic compounds (D), ketone-containing organic compounds (E), alcohol-containing organic compounds (F) and carboxylic acid-containing organic compounds (G).

4. The solid polyaluminoxane composition production method according to claim 1 , wherein the polyalkylaluminoxane in the polyaluminoxane composition solution (A) includes a polyaluminoxane containing a structural unit represented by General Formula (1) below:

5. The solid polyaluminoxane composition production method according to claim 1 , wherein the trialkylaluminums in the polyaluminoxane composition solution (A) include trimethylaluminum.

6. The solid polyaluminoxane composition production method according to claim 1 , wherein the polyalkylaluminoxane in the polyaluminoxane composition solution (A) is polymethylaluminoxane and the trialkylaluminum in the polyaluminoxane composition solution (A) is trimethylaluminum.

Assignees

• Mitsui Chemicals Inc

Inventors

• Tsurugi Kou
• Hanada Shiori
• Shibahara Atsushi
• Kawamura Kazumori
• Nishino Fumiaki
• Harada Yasuyuki
• Yamada Wataru
• Matsumoto Akiko
• Hara Isao
• Nakamura Tatsuya
• Muroto Toshihiro

Classifications

• C08F4/027

  Polymers · CPC title

• C08F4/02

  Carriers therefor · CPC title

• C07F5/068

  preparation of alum(in)oxanes · CPC title

• C08F4/65922 Primary

  containing at least two cyclopentadienyl rings, fused or not · CPC title

• C08F4/6428

  with an aluminoxane, i.e. a compound containing an Al-O-Al- group · CPC title