Pesticidal compositions and processes related thereto

Patent metadata

Field	Value
Publication number	US-9676704-B2
Application number	US-201514733057-A
Country	US
Kind code	B2
Filing date	Jun 8, 2015
Priority date	Jun 9, 2014
Publication date	Jun 13, 2017
Grant date	Jun 13, 2017

Abstract

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the following formula (“Formula One”).

First claim

We claim:

1. A molecule having the following formula

wherein:
(a) R1, R2, R3, R4, and R5, are, each independently, H, F, Cl, Br, I, CN, (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, or (C 1 -C 6 )haloalkoxy;
(b) R6 is (C 1 -C 6 )haloalkyl;
(c) R7 is H;
(d) R8 is H, (C 1 -C 6 )alkyl, or (C 1 -C 6 )haloalkyl;
(e) R9 is H, F, Cl, Br, I, (C 1 -C 6 )alkyl, or (C 1 -C 6 )haloalkyl;
(f) R10 is F, Cl, Br, I, (C 1 -C 6 )alkyl, or (C 1 -C 6 )haloalkyl;
(g) R11 and R12 are, each independently, H, F, Cl, Br, I, (C 1 -C 6 )alkyl, or (C 1 -C 6 )haloalkyl;
(h) L is
(1) a linker that is a bond connecting the two nitrogen atoms, or
(2) a (C 1 -C 6 )alkyl that is optionally substituted with one or more substituents, wherein each substituent is independently selected from F, Cl, Br, I, CN, OH, oxo, (C 1 -C 6 )alkoxy, S(C 1 -C 6 )alkyl, S(O)(C 1 -C 6 )alkyl, S(O) 2 (C 1 -C 6 )alkyl, and N((C 1 -C 6 )alkyl) 2 wherein each (C 1 -C 6 )alkyl is independently selected, and wherein each said alkyl or alkoxy has one or more substituents independently selected from H, F, Cl, Br, and I;

(i) R13 is
(1) an H, or
(2) a (C 1 -C 6 )alkyl that is optionally substituted with one or more substituents, wherein each substituent is independently selected from F, Cl, Br, I, CN, OH, oxo, (C 1 -C 6 )alkoxy, S(C 1 -C 6 )alkyl, S(O)(C 1 -C 6 )alkyl, S(O) 2 (C 1 -C 6 )alkyl, and N((C 1 -C 6 )alkyl) 2 wherein each (C 1 -C 6 )alkyl is independently selected, and wherein each said alkyl or alkoxy has one or more substituents independently selected from H, F, Cl, Br, and I; and

(j) R14 is independently selected from (C 1 -C 8 )alkyl, (C 1 -C 8 )haloalkyl, (C 3 -C 8 )cycloalkyl, (C 2 -C 8 )alkenyl, or (C 2 -C 8 )alkynyl, wherein each said alkyl, haloalkyl, cycloalkyl, alkenyl, and alkynyl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , OH, oxo, (C 1 -C 6 )alkoxy, S(C 1 -C 6 )alkyl, S(O)(C 1 -C 6 )alkyl, S(O) 2 (C 1 -C 6 )alkyl, and N((C 1 -C 6 )alkyl) 2 wherein each (C 1 -C 6 )alkyl is independently selected, and wherein each said alkyl or alkoxy has one or more substituents independently selected from H, F, Cl, Br, and I.

2. A molecule according to claim 1 wherein:
(a) R1 is H;
(b) R2 is H, F, Cl, or Br;
(c) R3 is H, F, Cl, or Br;
(d) R4 is H, F, Cl, or Br;
(e) R5 is H;
(f) R6 is (C 1 -C 8 )haloalkyl;
(g) R7 is H;
(h) R8 is H;
(i) R9 is H;
(j) R10 is selected from a group consisting of F, Cl, Br, I, (C 1 -C 6 )alkyl, and (C 1 -C 6 )haloalkyl;
(k) R11 is H;
(l) R12 is H;
(m) L is
(1) a linker that is bond connecting the two nitrogen atoms, or
(2) a (C 1 -C 6 )alkyl;

(n) R13 is
(1) an H, or
(2) a (C 1 -C 8 )alkyl;

(o) R14 is independently selected from (C 1 -C 8 )alkyl, (C 1 -C 8 )haloalkyl, (C 3 -C 8 )cycloalkyl, (C 2 -C 8 )alkenyl, or (C 2 -C 8 )alkynyl, wherein each said alkyl, haloalkyl, cycloalkyl, alkenyl, and alkynyl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , OH, oxo, (C 1 -C 6 )alkoxy, S(C 1 -C 6 )alkyl, S(O)(C 1 -C 6 )alkyl, S(O) 2 (C 1 -C 6 )alkyl, and N((C 1 -C 6 )alkyl) 2 wherein each (C 1 -C 6 )alkyl is independently selected, and wherein each said alkyl or alkoxy has one or more substituents independently selected from H, F, Cl, Br, and I.

3. A molecule according to claim 1 wherein:
(a) R1 is H;
(b) R2 is Cl or Br;
(c) R3 is H, F, Cl, or Br;
(d) R4 is Cl or Br;
(e) R5 is H;
(f) R6 is (C 1 -C 8 )haloalkyl;
(g) R7 is H;
(h) R8 is H;
(i) R9 is H;
(j) R10 is Br, (C 1 -C 8 )alkyl, (C 1 -C 8 )haloalkyl;
(k) R11 is H;
(l) R12 is H;
(m) L is
(1) a linker that is bond connecting the two nitrogen atoms, or
(2) a (C 1 -C 6 )alkyl;

(n) R13 is
(1) an H, or
(2) a (C 1 -C 8 )alkyl;

(o) R14 is (C 1 -C 8 )alkyl, (C 1 -C 8 )haloalkyl, (C 3 -C 8 )cycloalkyl, or (C 2 -C 8 )alkenyl, wherein each said alkyl or cycloalkyl is substituted with CN, SCH 3 , S(O)CH 3 , or S(O) 2 CH 3 .

4. A molecule according to claim 1 wherein said molecule is selected from one of the following molecules

No.
Structure

F1

F2

F3

F4

F5

F6

F7

F8

F9

F10

F11

F12

Assignees

• Dow Agrosciences Llc

Inventors

• Leplae Jr Paul Renee
• Hunter James E
• Watson Gerald B
• Lo William C
• Herbert John

Classifications

• A01N53/00

  Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof · CPC title

• A01N33/08

  containing oxygen or sulfur · CPC title

• C07C323/60

  with the carbon atom of at least one of the carboxyl groups bound to nitrogen atoms · CPC title

• A01N37/20 Primary

  containing the group [IMAGE cpc-sch-A01N-0935.gif], wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof · CPC title

• C07C255/46

  to carbon atoms of non-condensed rings · CPC title