Gas barrier laminate having excellent water barrier property

Patent metadata

Field	Value
Publication number	US-9676171-B2
Application number	US-201414765151-A
Country	US
Kind code	B2
Filing date	Feb 6, 2014
Priority date	Feb 7, 2013
Publication date	Jun 13, 2017
Grant date	Jun 13, 2017

Abstract

A gas barrier laminate 10 having an inorganic barrier layer 3 and a water-trapping layer 5 that are formed on a plastic base material 1 , the water-trapping layer 5 including a matrix of a cationic polymer (a) in which is distributed a hygroscopic agent (b) having such a hygroscopic property as to attain a humidity lower than a humidity that can be attained by using the matrix. The gas barrier laminate exhibits super barrier property against water despite of a structure of a small number of layers.

First claim

The invention claimed is:

1. A gas barrier laminate comprising an inorganic barrier layer and a water-trapping layer that are formed on a plastic base material, the water-trapping layer including a matrix of an ionic polymer (a) in which is distributed a hygroscopic agent (b) comprising a crosslinked product of a monovalent metal salt of a poly(meth)acrylic acid having such a hygroscopic property as to attain a humidity lower than a humidity that can be attained by the matrix in the absence of the hygroscopic agent (b).

2. The gas barrier laminate according to claim 1 , wherein said inorganic barrier layer is an inorganic oxide film formed by the CVD method.

3. The gas barrier laminate according to claim 1 , wherein said water-trapping layer and the inorganic barrier layer are contiguous to each other.

4. The gas barrier laminate according to claim 1 , wherein said ionic polymer (a) is a cationic polymer (a1).

5. The gas barrier laminate according to claim 4 , wherein a crosslinked structure is introduced into said matrix.

6. The gas barrier laminate according to claim 5 , wherein said crosslinked structure includes a siloxane structure or an alicyclic structure.

7. The gas barrier laminate according to claim 1 , wherein said ionic polymer (a) is an anionic polymer (a2), and said matrix of said anionic polymer (a2) contains a crosslinked structure.

8. The gas barrier laminate according to claim 7 , wherein said matrix of an anionic polymer (a2) contains a siloxane structure and an alicyclic structure.

9. The gas barrier laminate according to claim 8 , wherein said water-trapping layer is blended with an adhering agent (c) having a functional group that is reactive with the matrix and a surface of the inorganic barrier layer.

10. The gas barrier laminate according to claim 9 , wherein said adhering agent (c) is a compound having an alicyclic epoxy group and an alkoxysilyl group.

11. A coating composition obtained by dissolving or dispersing, in a solvent, an ionic polymer (a), a hygroscopic agent (b) comprising a crosslinked product of a monovalent metal salt of a poly(meth)acrylic acid having such a hygroscopic property as to attain a humidity lower than a humidity that can be attained by said ionic polymer (a) in the absence of the hygroscopic agent (b), and a crosslinking agent.

12. The coating composition according to claim 11 , wherein said ionic polymer (a) is a cationic polymer (a1).

13. The coating composition according to claim 12 , wherein said hygroscopic agent (b) is contained in an amount of 50 to 1000 parts by weight and said crosslinking agent is contained in an amount of 5 to 60 parts by weight per 100 parts by weight of said cationic polymer (a1).

14. The coating composition according to claim 12 , wherein said crosslinking agent is a silane compound represented by the following formula (1):
X—SiR 1 n (OR 2 ) 3-n   (1)

wherein X is an organic group having an epoxy group at the terminal,
R 1 and R 2 are, respectively, methyl groups, ethyl groups or isopropyl groups, and
n is 0, 1 or 2.

15. The coating composition according to claim 11 , wherein said ionic polymer (a) is an anionic polymer (a2) and, further, contains a closely adhering agent (c).

16. The coating composition according to claim 15 , wherein said hygroscopic agent (b) is contained in an amount of 50 to 1300 parts by weight, said crosslinking agent is contained in an amount of 1 to 50 parts by weight, and said closely adhering agent (c) is contained in an amount of 0.1 to 10 parts by weight per 100 parts by weight of said anionic polymer (a2).

17. The coating composition according to claim 15 , wherein said crosslinking agent is a diglycidyl ester represented by the following formula (2),
G-O(C═O)-A-(C═O)O-G  (2)

wherein G is a glycidyl group, and
A is a divalent hydrocarbon group having an aliphatic ring.

18. The coating composition according to claim 15 , wherein said closely adhering agent (c) is a silane compound represented by the following formula (1):
X—SiR 1 n (OR 2 ) 3-n   (1)

wherein X is an organic group having an epoxy group at the terminal,
R 1 and R 2 are, respectively, methyl groups, ethyl groups or isopropyl groups, and
n is 0, 1 or 2.

Assignees

• Toyo Seikan Group Holdings Ltd

Inventors

• Okuyama Shimpei
• Obu Yusuke
• Nangou Shunya
• Mori Kota

Classifications

• C08J7/0423

  with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder · CPC title

• Y10T428/31663

  As siloxane, silicone or silane · CPC title

• B32B9/00

  Layered products comprising a {layer of a} particular substance not covered by groups B32B11/00 - B32B29/00 · CPC title

• C08J2479/02

  Polyamines · CPC title

• B32B2307/7244

  Oxygen barrier · CPC title