Optical elements comprising cholesteric liquid crystal polymers

Patent metadata

Field	Value
Publication number	US-9671538-B2
Application number	US-201314440493-A
Country	US
Kind code	B2
Filing date	Nov 18, 2013
Priority date	Nov 19, 2012
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

A linear photopolymerizable polymer (LPP) layer is situated to align liquid crystal molecules in a cholesteric liquid crystal polymer (Ch-LCP) layer situated at or on the LPP layers. The Ch-LCP layer includes a patterned area and an unpatterned area. The patterned area and the un-patterned area have different optical properties. The Ch-LCP layer can be tuned to transmit light of a desired frequency and handedness. Single and multiple-layered LPP/Ch-LCP and/or LPP/LCP structures can be provided as patterned polarizers, patterned retarders and other devices.

First claim

We claim:

1. A method, comprising:
forming a photopolymerizable polymer network (PPN) layer for liquid crystal alignment,
aligning molecules of the PPN layer with each other in at least one alignment direction;
forming a cholesteric liquid crystal polymer (Ch-LCP) layer proximate the PPN layer so that liquid crystal molecules in the Ch-LCP layer are aligned with the at least one alignment direction; and
curing an unpatterned region of the Ch-LCP layer in an isotropic state.

2. The method of claim 1 , further comprising:
forming a patterned region of the Ch-LCP layer; and
curing the patterned region of the Ch-LCP layer in a cholesteric state.

3. The method of claim 2 , wherein curing the patterned region comprises polymerizing liquid crystal molecules of the patterned region by exposing the molecules to ultraviolet light.

4. The method of claim 1 , wherein curing the unpatterned region comprises thermal annealing.

5. The method of claim 4 , wherein thermal annealing comprises heating the Ch-LCP layer to a temperature greater than a clear-point temperature of the Ch-LCP layer.

6. The method of claim 4 , wherein curing the unpatterned region comprises polymerizing liquid crystal molecules of the unpatterned region by exposing the molecules to ultraviolet light.

7. The method of claim 1 , further comprising:
curing a patterned region of the Ch-LCP layer in a cholesteric state; and
removing an unpatterned region of the Ch-LCP layer.

8. The method of claim 7 , wherein removing the unpatterned region of the Ch-LCP layer comprises rinsing with a solvent.

9. The method of claim 1 , wherein the Ch-LCP layer comprises a chiral dopant, the method further comprising adjusting a concentration of the chiral dopant to tune the transmittance of a selected wavelength of light through the Ch-LCP layer.

10. A method, comprising:
on a substrate, forming an alignment layer;
aligning molecules of the alignment layer with each other in at least one alignment direction;
forming a cholesteric liquid crystal polymer (Ch-LCP) layer proximate the alignment layer in a patterned manner so that liquid crystal molecules in at least a patterned region of the Ch-LCP layer are aligned to the at least one alignment direction; and
processing the Ch-LCP layer to produce an optical property of the patterned region of the Ch-LCP layer that is different than a corresponding optical property of an unpatterned region of the Ch-LCP layer.

11. The method of claim 10 , wherein:
the alignment layer comprises a photopolymerizable polymer network (PPN) layer; and
aligning the molecules of the alignment layer with each other the at least one alignment direction comprises exposing the PPN to linearly polarized ultraviolet radiation.

12. The method of claim 10 , wherein processing the Ch-LCP layer comprises exposing at least a selected region of Ch-LCP layer to patterned linearly polarized ultraviolet radiation.

13. The method of claim 10 , wherein processing the Ch-LCP layer comprises removing the unpatterned region(s).

14. The method of claim 10 , wherein processing the Ch-LCP layer comprises thermal annealing.

15. The method of claim 10 , further comprising adjusting a concentration of a chiral dopant added to the cholesteric liquid crystal polymer of the Ch-LCP layer to produce a correspondingly tuned transmittance of a central wavelength of light transmitted through the Ch-LCP layer.

16. The method of claim 10 , wherein processing the Ch-LCP layer comprises:
curing the patterned region in a cholesteric phase; and
curing the unpatterned region in an isotropic phase.

17. A device, comprising:
a linear photopolymerizable polymer (LPP) layer having molecules defining at least one alignment direction; and
a cholesteric liquid crystal polymer (Ch-LCP) layer proximate the LPP layer such that liquid crystal molecules in a patterned area of the Ch-LCP layer are aligned with the at least one alignment direction, and the patterned area of the Ch-LCP layer has different optical properties than an unpatterned area of the Ch-LCP layer.

18. An optical element, comprising a device as recited in claim 17 .

19. A device, comprising:
a substrate;
an alignment layer situated on the substrate, the alignment layer comprising at least one selected region in which molecules are aligned with each other in at least one alignment direction; and
a first cholesteric liquid crystal polymer (Ch-LCP) layer situated on the alignment layer, the first Ch-LCP layer including liquid crystal molecules that, in the at least one selected region, are aligned with the at least one alignment direction, wherein the first Ch-LCP layer includes a patterned area and an unpatterned area, the patterned area and the unpatterned area having at least one different optical property.

20. The device of claim 19 , wherein the alignment layer is a linear photo-polymerizable polymer (LPP) layer.

21. The device of claim 19 , wherein:
the patterned area of the first Ch-LCP layer is polymerized in a cholesteric phase; and
the unpatterned area of the first Ch-LCP layer is polymerized in an isotropic phase.

22. The device of claim 21 , further comprising a second Ch-LCP layer overlaying at least part of the first Ch-LCP layer.

23. The device of claim 22 , wherein:
the second Ch-LCP layer comprises a patterned region polymerized in a cholesteric phase; and
the second Ch-LCP layer overlays at least part of the first Ch-LCP layer so that at least part of the patterned region of the second Ch-LCP layer overlays at least part of the unpatterned area of the first Ch-LCP layer.

24. The device of claim 22 , wherein:
the first Ch-LCP layer comprises a chiral dopant having a first handedness; and
the second Ch-LCP layer comprises a chiral dopant having a second handedness that is opposite the first handedness.

25. The device of claim 22 , wherein: the first Ch-LCP layer comprises
a chiral dopant concentration tuned to a first wavelength; and
the second Ch-LCP layer comprises a chiral dopant concentration tuned to a second wavelength different from the first wavelength.

26. An optical element, comprising a device as recited in claim 19 .

27. An optical filter, comprising:
a substrate;
a linear photopolymerizable polymer (LPP) layer supported by the substrate, the LPP layer defining at least one alignment direction;
a cholesteric liquid crystal polymer (Ch-LCP) layer proximate the LPP layer such that liquid crystal molecules of the Ch-LCP layer are aligned with the at least one alignment direction, the Ch-LCP layer including a patterned area cured in the cholesteric phase; and
a layer pair at least partially overlapping the Ch-LCP layer, the layer pair including an PP alignment layer and a liquid crystal polymer (LCP) layer situated so as to align respective molecules thereof with respect to the LPP alignment layer, the LCP layer including a dichroic dye.

Assignees

• The Arizona Board of Regents on behalf of the Univeristy of Arizona
• Univ Arizona

Inventors

• Pau Stanley
• Hsu Wei-Liang

Classifications

• G02B5/3016 Primary

  involving passive liquid crystal elements (optical properties of liquid crystals G02F1/0063; polarising elements associated with active liquid crystal devices G02F1/133528) · CPC title

• C09K19/56

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• C09K19/36

  Steroidal liquid crystal compounds · CPC title