Resistive type humidity sensor based on porous magnesium ferrite pellet

Patent metadata

Field	Value
Publication number	US-9671359-B2
Application number	US-201414466723-A
Country	US
Kind code	B2
Filing date	Aug 22, 2014
Priority date	Aug 27, 2013
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

The present invention relates to a process for preparing a humidity sensor based on resistive type porous Magnesium Ferrite (MgFe 2 O 4 ) pellets and a humidity sensor thereof. More particularly, the present invention includes a synthesis process of preparing 30 to 40% porous MgFe 2 O 4 pellets. The process further includes making Ohmic contacts on the porous MgFe 2 O 4 pellets. The process is very cost effective and optimized to keep the resistance of the porous MgFe 2 O 4 pellets in the range 200-300 MΩ. Further, the response and recovery time of the porous MgFe 2 O 4 pellets to humidity is in the range of few seconds only. Further, the porous MgFe 2 O 4 pellets can be used for humidity sensing for more than 12 months. Due to resistance stability even after long-term exposure in humidity, the porous MgFe 2 O 4 pellets do not require flash heating. Further, the humidity sensor prepared according to the process is highly sensitive towards relative humidity changes as the same is based on the measurement of resistance changes as compared to known humidity sensors which are based on the measurement of capacitance changes.

First claim

What is claimed is:

1. A process for preparing porous magnesium ferrite pellets having porosity in the range of 30 to 40%, the process comprising:
obtaining a homogenous mixture of magnesium oxide or magnesium carbonate and ferrous oxide in a molar ratio of 1:2;
pre-sintering the homogenous mixture in a furnace;
grinding the pre-sintered mixture;
pelletizing the grounded mixture to prepare intermediate pellets; and
sintering the intermediate pellets to prepare the porous magnesium ferrite pellets having porosity in the range of 30 to 40%.

2. The process as claimed in claim 1 , wherein the grain size of the porous magnesium ferrite pellets is in the range of 50 nm to 1 μm.

3. The process as claimed in claim 1 , wherein the pore size of the porous magnesium ferrite pellets is in the range of 15 nm to 450 nm.

4. The process as claimed in claim 1 , wherein the pelletizing comprises applying pressure on a predefined amount of the ground mixture through a hydraulic press.

5. The process as claimed in claim 3 , wherein the porous magnesium ferrite pellets have powder weight 0.1-0.2 g and dimension 5 mm×8 mm×1 mm at applied pressure of 10 tons.

6. The process as claimed in claim 1 , wherein the porous magnesium ferrite pellets exhibit resistance in the range of 200 to 300 MΩ at 10% relative humidity.

7. The process as claimed in claim 1 , wherein the porous magnesium ferrite pellets exhibit a change in resistance up to 4 to 8 MΩ for 1% change in relative humidity.

8. The process as claimed in claim 1 , wherein resistance value of the porous magnesium ferrite pellets is stable at 10%, 50%, and 90% relative humidity.

9. The process as claimed in claim 1 , wherein response time and recovery time of the porous magnesium ferrite pellets is 120 to 150 seconds and 140 to 200 seconds respectively.

10. A process for preparing a resistive humidity sensor, the process comprising:
obtaining a homogenous mixture of magnesium oxide or magnesium carbonate and ferrous oxide in a molar ratio of 1:2;
pre-sintering the homogenous mixture in a furnace;
grinding the pre-sintered mixture;
pelletizing the grounded mixture to prepare intermediate pellets;
sintering the intermediate pellets to prepare the porous magnesium ferrite pellets having porosity in the range of 30 to 40%; and
preparing the resistive type humidity sensor using a pellet from amongst the porous magnesium ferrite pellets as base resistive material for the resistive humidity sensor.

11. The process as claimed in claim 10 , further comprising:
diffusing a group II element added silver paste on longitudinal edges of the pellet to provide an ohmic contact at each of the longitudinal edges, wherein the diffusing comprises applying the group II element added silver paste on longitudinal edges of the pellet and heating the pellet thereafter, and wherein the group II element is zinc metal; and
soldering a polytetrafluoroethylene coated conducting wire on the Ohmic contact at each of the longitudinal edges.

12. The process as claimed in claim 10 , wherein the pellet exhibits resistance in the range of 200 to 300 MΩ at 10% relative humidity, and wherein the pellet exhibits a change in resistance up to 4 to 8 MΩ for 1% change in relative humidity.

13. A resistive humidity sensor comprising:
a resistive material sensitive to humidity; and
at least two electrodes connected to the resistive material to measure change in resistance of the resistive material, wherein the resistive material is a porous magnesium ferrite pellet having porosity in the range of 30 to 40%, the electrodes are soldered on an ohmic electro-conducting silver electrode area of said porous magnesium ferrite pellet, and wherein said pellet exhibits a resistance in the range of 200 to 300 MΩ at 10% relative humidity.

14. The resistive type humidity sensor as claimed in claim 13 , wherein the porous magnesium ferrite pellet exhibits a change in resistance up to 4 to 8 MΩ for 1% change in relative humidity.

Assignees

• Council Scient Ind Res

Inventors

• Kotnala Ravinder Kumar
• Shah Jyoti
• Kishan Hari
• Singh Bhikham

Classifications

• C04B2111/90

  Electrical properties · CPC title

• B23K20/004

  Wire welding · CPC title

• C04B38/0051

  characterised by the pore size, pore shape or kind of porosity · CPC title

• C04B35/26

  based on ferrites · CPC title

• C04B2235/3206

  Magnesium oxides or oxide-forming salts thereof · CPC title