Process for preparing olefins by thermal steamcracking

Patent metadata

Field	Value
Publication number	US-9670418-B2
Application number	US-201314420636-A
Country	US
Kind code	B2
Filing date	Aug 6, 2013
Priority date	Aug 9, 2012
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

The invention relates to a process for converting hydrocarbon inputs by thermal steamcracking to give at least one olefin-containing product stream comprising at least ethylene and propylene, by at least partly converting a hydrocarbon input in at least one cracking furnace ( 2 ), wherein the hydrocarbon input is converted under mild cracking conditions in the cracking furnace ( 2 ), mild cracking conditions meaning that propylene to ethylene are present in a ratio of 0.81 to 1.6 kg/kg at the cracking furnace exit, and the hydrocarbon input comprising predominantly hydrocarbons having a maximum carbon number of 6, preferably a maximum of 5.

First claim

The invention claimed is:

1. A process for converting hydrocarbon inputs by thermal steamcracking to give at least one olefin-containing product stream comprising at least ethylene and propylene, by at least partly converting a hydrocarbon input in at least one cracking furnace ( 2 ), characterized in that the hydrocarbon input is converted under mild cracking conditions in the cracking furnace ( 2 ), mild cracking conditions meaning that propylene to ethylene are present in a ratio of 0.85 to 1.6 kg/kg at the cracking furnace exit, and the hydrocarbon input comprising predominantly hydrocarbons having a maximum carbon number of 5.

2. The process as claimed in claim 1 , characterized in that the cracking furnace ( 2 ) which converts under mild cracking conditions is supplied with one or more recycled fractions (P, T) which are obtained from the product stream and which comprise predominantly hydrocarbons having a maximum carbon number of 5 as the hydrocarbon input.

3. The process as claimed in claim 1 or 2 , characterized in that the recycled fractions (P, T) are substantially free of diolefins when they are supplied to the cracking furnace ( 2 ) which converts under mild cracking conditions as the hydrocarbon input.

4. The process as claimed in claim 1 , characterized in that the cracking furnace ( 2 ) which converts under mild cracking conditions is supplied with predominantly saturated hydrocarbons as the hydrocarbon input.

5. The process as claimed in claim 1 , characterized in that the hydrocarbon input is converted in the cracking furnace ( 2 ) under mild cracking conditions that lead to a ratio of propylene to ethylene of up to 1.2 kg/kg, at the cracking furnace exit.

6. The process as claimed claim 1 , characterized in that a hydrocarbon input is converted under normal cracking conditions in a further cracking furnace ( 1 ), normal cracking conditions meaning that propylene to ethylene are present in a ratio of 0.25 to 0.85 kg/kg, preferably of 0.3 to 0.75 kg/kg and more preferably of 0.4 to 0.65 kg/kg at the cracking furnace exit, the ratio of propylene to ethylene for the cracking furnace ( 2 ) which converts under mild cracking conditions always having a greater value than the value for the ratio of propylene to ethylene for the cracking furnace ( 1 ) which converts under normal cracking conditions.

7. The process as claimed in claim 6 , in which the values for the ratio of propylene to ethylene differ by at least 0.1 kg/kg, preferably by at least 0.15 kg/kg, more preferably by at least 0.2 kg/kg.

8. The process as claimed in claim 1 , characterized in that the composition of a hydrocarbon input which is used for the cracking furnace ( 1 ) which converts under normal cracking conditions differs from that of the hydrocarbon input which is used for the cracking furnace ( 2 ) which converts under mild cracking conditions.

9. The process as claimed in claim 1 , characterized in that the cracking furnace ( 1 ) which converts under normal cracking conditions is supplied with at least one fraction (U) which has been separated from the product stream and recycled, comprising predominantly hydrocarbons having a carbon number of at least 6.

10. The process as claimed in claim 1 , characterized in that a fresh input is used, which is fractionated into at least one first and one second fresh input fraction (B 1 , B 2 ), and the first fresh input fraction (B 1 ) is conducted at least partly into the cracking furnace ( 1 ) which converts under normal cracking conditions and the second fresh input fraction (B 2 ) at least partly into the cracking furnace ( 2 ) which converts under mild cracking conditions.

11. The process as claimed in claim 1 , in which the cracking furnace exit temperature for the conversion in the cracking furnace ( 2 ) which converts under mild cracking conditions is between 680° C. and 820° C., preferably between 700° C. and 800° C. and further preferably between 710° C. and 780° C. and more preferably between 720° C. and 760° C., and the cracking furnace exit temperature for the conversion in the cracking furnace ( 1 ) which converts under normal cracking conditions is between 800° C. and 1000° C., preferably between 820° C. and 950° C. and more preferably between 840° C. and 900° C., the cracking furnace exit temperature of the cracking furnace ( 1 ) which converts under normal cracking conditions being at least 10° C. above, preferably at least 20° C. above, that of the cracking furnace ( 2 ) which converts under mild cracking conditions.

12. The process as claimed in claim 1 , in which 0.3 to 1.5 kg of steam per kg of hydrocarbon input is used in the cracking furnace ( 1 ) which converts under normal cracking conditions, and 0.15 to 0.8 kg of steam per kg of hydrocarbon input in the cracking furnace ( 2 ) which converts under mild cracking conditions.

13. The process as claimed in claim 1 , in which at least one fraction (V) comprising predominantly hydrocarbons having a carbon number of 2 or 3 is obtained from the product stream and at least partly converted in a cracking furnace ( 3 ) for gaseous input.

14. The process as claimed in any of claim 1 , characterized in that the fresh input (BL) conducted into the cracking furnace ( 2 ) which converts under mild cracking conditions comprises natural gas condensates or/and one or more cuts from a mineral oil refinery and/or synthetic and/or biogenic hydrocarbons and/or mixtures derived therefrom.

15. The process as claimed in claim 1 , characterized in that the fresh input (B) used for the cracking furnace ( 1 ) which converts under normal cracking conditions or/and for the fresh input for the fresh input fractionation ( 7 ) comprises natural gas condensates and/or crude oil fractions, especially naphtha, and/or synthetic and/or biogenic hydrocarbons and/or mixtures derived therefrom.

Assignees

• Linde Ag

Inventors

• Schmidt Gunther
• Fritz Helmut
• Walter Stefanie

Classifications

• C10G2400/20

  C2-C4 olefins · CPC title

• C10G9/36 Primary

  with heated gases or vapours · CPC title