Fluid bed coking process with decoupled coking zone and stripping zone

Patent metadata

Field	Value
Publication number	US-9670417-B2
Application number	US-201414185243-A
Country	US
Kind code	B2
Filing date	Feb 20, 2014
Priority date	Mar 8, 2013
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

A fluid coking unit for converting a heavy oil feed to lower boiling products by thermal has a centrally-apertured annular baffle at the top of the stripping zone below the coking zone to inhibit recirculation of solid particles from the stripping zone to the coking zone. By inhibiting recirculation of the particles from the stripping zone to the coking zone, the temperatures of the two zones are effectively decoupled, enabling the coking zone to be run at a lower temperature than the stripping zone to increase the yield of liquid products.

First claim

The invention claimed is:

1. A fluid coking unit for converting a heavy oil feed to lower boiling products by thermal cracking in a fluid bed, comprises:
(i) a reactor having a coking zone to contain a fluidized bed of solid particles into which the heavy oil feed is introduced;
(ii) a scrubbing zone located above the coking zone into which vapor phase product from the coking zone is passed;
(iii) a stripping zone, located at the bottom of the coking zone, for stripping at least a portion of the hydrocarbons which adhere to the solid particles passing into the stripping zone from the coking zone;
(iv) a heater communicating with the stripping zone to receive solid particles from the bottom of the stripping zone;
(v) a conduit for passing hot solid particles from the heater to the coking zone;
(vi) a recirculation conduit for recycling hot solid particles from the heater to the stripping zone; with
(vii) a centrally-apertured annular baffle at the top of the stripping zone to inhibit recirculation of solid particles from the stripping zone to the coking zone, wherein the centrally-apertured annular baffle is imperforate apart from the central aperture;
wherein the recirculation conduit has an outlet at the top of the stripper zone below the centrally apertured annular baffle and above a plurality of stripper sheds.

2. A fluid coking unit according to claim 1 which comprises a gasifier connected by a transfer conduit to the heater to receive a portion of the fluidized solid particles from the heater.

3. A fluid coking unit according to claim 2 in which the gasifier is connected by a return conduit to the heater to return fluidized solid particles from the gasifier to the heater.

4. A fluid coking unit according to claim 1 in which the centrally apertured annular baffle and is located above the top of the stripper sheds by a vertical distance to define a mixing zone in which the recirculated hot particles from the heater becomes mixed with the solid particles passing into the stripping zone from the coking zone.

5. A fluid coking unit according to claim 4 in which the centrally apertured annular baffle is located above the top of the stripper sheds by a vertical distance from 0.5 to 1.5 times a bed diameter of the stripping zone.

6. A fluid coking unit according to claim 5 in which the centrally apertured annular baffle is located above the top of the stripper sheds by a vertical distance of about one bed diameter of the stripping zone.

7. A fluid coking unit according to claim 1 in which the centrally-apertured annular baffle comprises a downwardly directed frusto-conical baffle fixed at its outer circumference to the inner wall of the reactor.

8. A fluid coking unit according to claim 1 in which the aperture of the centrally-apertured annular baffle has an open area from 30 to 70% of its total area on a horizontal projection.

9. A fluid coking unit according to claim 1 in which the aperture of the centrally-apertured annular baffle has an open area from 40 to 60% of its total area on a horizontal projection.

10. A fluid coking unit according to claim 1 in which the angle of the centrally-apertured annular baffle is from 30 to 60° from the vertical.

11. A fluid coking unit according to claim 1 in which the centrally-apertured annular baffle has an upturned lip around the circumference of the aperture.

12. A fluid coking unit according to claim 1 in which the recirculation conduit for recycling hot solid particles from the heater to the stripping zone terminates in an outlet at the top of the stripping zone.

13. A fluid coking unit according to claim 12 in which the stripping zone has stripping sheds with the recirculation conduit for recycling hot solid particles from the heater to the stripping zone terminating in an outlet at the top of the stripping zone above the stripping sheds and below the centrally-apertured annular baffle.

14. A fluid coking unit according to claim 12 in which the stripping zone has stripping sheds with the recirculation conduit for recycling hot solid particles from the heater to the stripping zone entering a side of the stripping zone and terminating in a vertical outlet at the top of the stripping zone above the stripping sheds and below the centrally-apertured annular baffle.

15. A fluid coking unit according to claim 1 which includes a gasifier with a conduit connecting the bottom of the stripping zone to the heater to pass solid particles from the stripper to the heater, a conduit for passing hot solid particles from the heater to the coking zone, a conduit for passing hot solid particles from the heater to the gasifier, and a conduit for passing gas from the gasifier to the heater.

Assignees

• Du Bing
• Healy Timothy M
• Bernatz Fritz A
• Huang Yi En
• Martin Zachary R
• Raich Brenda A
• Exxonmobil Res & Eng Co

Inventors

• Du Bing
• Healy Timothy M
• Bernatz Fritz A
• Huang Yi En
• Martin Zachary R
• Raich Brenda A

Classifications

• B01J2208/0084

  inside the bed, e.g. baffles · CPC title

• C10G2300/4006

  Temperature · CPC title

• B01J8/34

  with stationary packing material in the fluidised bed, e.g. bricks, wire rings, baffles · CPC title

• C10G9/30 Primary

  according to the "moving bed" method · CPC title

• C10G9/005

  Coking (in order to produce liquid products mainly) · CPC title