Antimony-free flame retardant polyester composition

Patent metadata

Field	Value
Publication number	US-9670357-B2
Application number	US-201313909495-A
Country	US
Kind code	B2
Filing date	Jun 4, 2013
Priority date	Jun 4, 2013
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

Disclosed herein is a polyalkylene terephthalate flame retardant composition, comprising (a) 30 to 60 parts by weight of a polyalkylene terephthalate or a mixture of polyalkylene terephthalates, (b) 0.25 to 2.5 parts by weight of an antidrip agent, (c) 4 to 18 parts by weight of melamine polyphosphate (hereinafter “MPP”), and (d) 12 to 26 parts by weight of poly(pentabromobenzylacrylate) (hereinafter “PBBPA”), provided that the combined amount of MPP and PBBPA is at least 18 parts by weight and less than or equal to 30 parts by weight and provided that the composition is substantially antimony free. The invention also provides processes for making such compositions as well as articles derived therefrom.

First claim

The invention claimed is:

1. A polybutylene terephthalate flame retardant composition that comprises:
(a) 5 to 9 parts by weight of a polybutylene terephthalate wherein the first polybutylene terephthalate has an intrinsic viscosity of 1.15 to 1.25 cm 3 /g; and 28 to 50 parts by weight of a second polybutylene terephthalate, wherein the second polybutylene terephthalate has an intrinsic viscosity of 0.6 to 0.7 cm 3 /g;
(b) 0.25 to 2.5 parts by weight of polytetrafluorethylene;
(c) 4 to 18 parts by weight of melamine polyphosphate; and
(d) 12 to 26 parts by weight of poly(pentabromobenzylacrylate), provided that the combined amount of (c) and (d) is at least 18 parts by weight and less than or equal to 30 parts by weight;

wherein:
the composition is substantially antimony-free,
the composition has a tensile strength at break according to ASTM D638-2010 of greater than 110 Mpa; and wherein:
(i) the composition has a UL 94 (23° C./50% RH) test rating of V-0; or
(ii) the composition has a UL 94 (70° C.) test rating of V-0; or
(iii) the composition has a UL 94 (23° C./50% RH) test rating of V-0 and a UL 94 (70° C.) test rating of V-0, wherein the composition further comprising 25 to 35 parts by weight of a glass fiber.

2. The composition of claim 1 , wherein the polytetrafluoroethylene comprises 0.25 to 2 parts by weight of polytetrafluoroethylene encapsulated in styrene acrylonitrile resin.

3. The composition of claim 2 , comprising:
(c) 4.25 to 15.75 parts by weight of melamine polyphosphate; and
(d) 14.25 to 25.75 parts by weight of poly(pentabromobenzylacrylate).

4. The composition of claim 3 , comprising:
(c) 4.5 to 15.5 parts by weight of melamine polyphosphate; and
(d) 14.5 to 25.5 parts by weight of poly(pentabromobenzylacrylate) provided that the combined amount of (c) and (d) is at least 18 parts by weight and less than 30 parts by weight,
and wherein the composition has a UL 94 (23° C./50% RH) test rating of V-0 and a UL 94 (70° C.) test rating of V-0.

5. The composition of claim 1 , further comprising 0.3 to 0.7 parts by weight of talc.

6. A polybutylene terephthalate flame retardant composition, comprising:
(a1) 5 to 9 parts by weight of a first polybutylene terephthalate, wherein the first polybutylene terephthalate has an intrinsic viscosity of 1.15 to 1.25 cm 3 /g;
(a2) 28 to 50 parts by weight of a second polybutylene terephthalate, wherein the second polybutylene terephthalate has an intrinsic viscosity of 0.6 to 0.7 cm 3 /g;
(b) 0.5 to 2 parts by weight of polytetrafluoroethylene;
(c) 4.25 to 15.75 parts by weight of melamine polyphosphate;
(d) 14.25 to 25.75 parts by weight of poly(pentabromobenzylacrylate) provided that the combined amount of (c) and (d) is at least 18 parts by weight and less than or equal to 30 parts by weight; and
(e) 25 to 35 parts by weight of glass fiber; wherein:
the composition is substantially antimony-free;
the composition has a tensile strength at break according to ASTM D638-2010 of greater than 110 MPa; and wherein:
(i) the composition has a UL 94 (23° C./50% RH) test rating of V-0; or
(ii) the composition has a UL 94 (70° C.) test rating of V-0; or
(iii) the composition has a UL 94 (23° C./50% RH) test rating of V-0 and a UL 94 (70° C.) test rating of V-0.

7. The composition of claim 6 , wherein the glass fiber is E-glass fiber.

8. The composition of claim 7 , comprising:
(a1) 6 to 8 parts by weight of first polybutylene terephthalate;
(a2) 30 to 40 parts by weight of second polybutylene terephthalate;
(b) 0.5 to 2 parts by weight of polytetrafluoroethylene encapsulated in styrene acrylonitrile resin;
(c) 4.5 to 15.5 parts by weight of melamine polyphosphate;
(d) 14.5 to 25.5 parts by weight of poly(pentabromobenzylacrylate) provided that the combined amount of (c) and (d) is at least 18 parts by weight and less than or equal to 30 parts by weight;
(e) 25 to 35 parts by weight of E-glass fiber; and
(f) 0.4 to 0.6 parts by weight of talc,
wherein the composition has a UL 94 (23° C./50% RH) test rating of V 0 and a UL 94 (70° C.) test rating of V-0.

9. An article prepared from the composition of claim 1 .

Assignees

• Sabic Innovative Plastics Ip Bv
• Sabic Global Technologies Bv

Inventors

• Yang Yuzhen
• Ding Tianhua

Classifications

• C08L2201/02

  Flame or fire retardant/resistant · CPC title

• C08L33/16

  Homopolymers or copolymers of esters containing halogen atoms · CPC title

• C08K7/14

  Glass · CPC title

• C08L67/02 Primary

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• C08L27/18

  Homopolymers or copolymers or tetrafluoroethene · CPC title