Elastomeric compositions and their use in articles

Patent metadata

Field	Value
Publication number	US-9670348-B2
Application number	US-201514880646-A
Country	US
Kind code	B2
Filing date	Oct 12, 2015
Priority date	Dec 19, 2011
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

A dynamically vulcanized alloy contains at least one isobutylene-containing elastomer, at least one thermoplastic resin, and an anhydride functionalized oligomer grafted to the thermoplastic resin. In the alloy, the elastomer is present as a dispersed phase of small vulcanized or partially vulcanized particles in a continuous phase of the thermoplastic resin and the alloy is substantially absent of any sulfonamides.

First claim

What is claimed is:

1. A dynamically vulcanized alloy comprising:
a) at least one elastomer derived from 1) at least one C 4 to C 7 isoolefin monomer and 2) at least one multiolefin or other polymerizable monomer;
b) at least one polyamide having a relative viscosity in the range of 2.9 to 3.9 per ASTM D2857;
c) at least one polyamide having a relative viscosity below 2.9 per ASTM D2857; and
d) a viscosity modifier of 10 to 30 phr of an anhydride functionalized oligomer grafted to at least one of the polyamides, wherein the oligomer, prior to anhydride functionalization, is a viscous liquid having a molecular weight in the range of 500 to 2500,
wherein the polyamides form a polyamide mixture, the dynamically vulcanized alloy has less than 100 ppm by weight of sulfonamides and the elastomer is present as a dispersed phase of small vulcanized or partially vulcanized particles in a continuous phase of the polyamide mixture.

2. The alloy of claim 1 , wherein the oligomer is selected from the group consisting of an alkyl derived oligomer, an aryl derived oligomer, and an alkenyl derived oligomer.

3. The alloy of claim 1 , wherein the anhydride functionality is either a succinic anhydride or a maleic anhydride.

4. The alloy of claim 1 , wherein the functionalized oligomer is selected from the group consisting of poly-isobutylene succinic anhydride, polyisobutene succinic anhydride, polybutene succinic anhydride, polyisopentene succinic anhydride, polypentene succinic anhydride, polyoctenyl succinic anhydride, polyisooctenyl succinic anhydride, poly-hexenyl succinic anhydride, and poly-dodecenyl succinic anhydride.

5. The alloy of claim 1 , wherein the 1) at least one isoolefin monomer is isobutylene, isobutene, 2-methyl-1-butene, 3-methyl-1-butene, 2-methyl-2-butene, 1-butene, 2-butene, hexene, or 4-methyl-1-pentene and 2) at least one multiolefin or other polymerizable monomer is isoprene, butadiene, 2,3-dimethyl-1,3-butadiene, myrcene, 6,6-dimethyl-fulvene, hexadiene, cyclopentadiene, piperylene, styrene, or dichlorostyrene.

6. The alloy of claim 1 , wherein the elastomer is functionalized with a halogen, acid, or ester.

7. The alloy of claim 1 , wherein the elastomer is present in the alloy in an amount in the range of 55 to 90 weight percent based on the amount of elastomer and polyamides in the alloy.

8. The alloy of claim 1 , wherein the elastomer comprises 1.0 to 1.5 mol % of a halogen.

9. The alloy of claim 1 , wherein the polyamide having a relative viscosity of below 2.9 is 5 to 25% of the total polyamide in the system.

10. The alloy of claim 1 , wherein the alloy comprises a cure system of at least one curative and optional cure accelerators.

11. A process of preparing a dynamically vulcanized alloy, the process comprising the following steps:
a) selecting at least one elastomer derived from 1) at least one C 4 to C 7 isoolefin monomer and 2) at least one multiolefin or other polymerizable monomer;
b) selecting at least one polyamide having a relative viscosity in the range of 2.9 to 3.9 per ASTM D2857 and at least one polyamide having a relative viscosity below 2.9 per ASTM D2857; and
c) selecting a viscosity modifier of an anhydride functionalized oligomer, wherein the oligomer, prior to anhydride functionalization, is a viscous liquid having a molecular weight in the range of 500 to 2500,
d) mixing in a mixer the at least one elastomer, the polyamides, and the viscosity modifier together until the polyamides have melted and the anhydride functionalized oligomer is grafted to at least one of the polyamides to form a mixed melted blend,
e) adding a cure package of at least one curative into the mixer,
f) continuing to mix the blend under conditions of high shear and elevated temperature to vulcanize the elastomer and disperse the vulcanized elastomer as discrete particles in a polyamide matrix of the polyamides; and
g) obtaining a dynamically vulcanized alloy
wherein during step d), the viscosity modifier is added to the mixer simultaneously with at least one of the polyamides or after the polyamides begin to melt in the extruder and the viscosity of the combined polyamide and viscosity modifier is lower than the viscosity of the at least one elastomer.

12. The process of claim 11 wherein the cure package is added to the mixer after the polyamides have melted and mixed with the elastomer.

13. The process of claim 12 wherein the cure package comprises a metal oxide.

14. The process of claim 11 wherein the cure package comprises a metal oxide.

15. The process of claim 11 wherein the at least one polyamide having a relative viscosity below 2.9 is a homopolymer.

16. A method of increasing the melt temperature of a dynamically vulcanized alloy,
wherein the dynamically vulcanized alloy comprises
a) at least one elastomer derived from 1) at least one C 4 to C 7 isoolefin monomer and 2) at least one multiolefin or other polymerizable monomer;
b) at least one polyamide having a relative viscosity in the range of 2.9 to 3.9 per ASTM D2857 and a defined melt temperature; and
c) 2 to 30 phr of an anhydride functionalized oligomer, wherein the oligomer, prior to anhydride functionalization, has a molecular weight in the range of 500 to 2500,
the method also comprising replacing a portion of the at least one polyamide with a polyamide homopolymer having a relative higher melt temperature.

17. The method of claim 16 wherein the polyamide having a relative higher melt temperature is 5 to 25% of the total polyamide in the dynamically vulcanized alloy.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Ellul Maria D
• Deyoung Ronald
• Kumor Dennis

Classifications

• C08L23/22 Primary

  Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins · CPC title

• C08K3/34

  Silicon-containing compounds · CPC title

• C08L23/283 Primary

  Iso-olefin halogenated homopolymers or copolymers · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L23/0869

  with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters · CPC title