Elastomeric composition exhibiting very good dispersion of the filler in the elastomeric matrix

Patent metadata

Field	Value
Publication number	US-9670332-B2
Application number	US-201113994192-A
Country	US
Kind code	B2
Filing date	Dec 9, 2011
Priority date	Dec 17, 2010
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

The invention relates to a rubber composition based on at least one diene elastomer, a filler comprising at least carbon black and an inorganic filler with an inorganic filler content of less than or equal to 50 parts by weight per hundred parts of elastomer, phr, and also a crosslinking system, characterized in that the dispersion of the filler in the elastomeric matrix has a Z value of greater than or equal to 80; and also to the process for preparing such a composition.

First claim

The invention claimed is:

1. A process for preparing a rubber composition based on at least one diene elastomer, a filler comprising at least carbon black and an inorganic filler with an inorganic filler content of less than or equal to 50 parts by weight per hundred parts of elastomer, and also a crosslinking system, comprising:
preparing a first masterbatch of diene elastomer and of carbon black, comprising: feeding a continuous flow of a diene elastomer latex to a mixing zone of a coagulation reactor defining an elongate coagulation zone extending between the mixing zone and an outlet,
feeding a continuous flow of a fluid comprising a filler comprising carbon black under pressure to the mixing zone of a coagulation reactor to form a coagulated mixture,
drying the coagulum obtained above in order to recover the first masterbatch,

incorporating the inorganic filler, and the other constituents of the composition, with the exception of a crosslinking system, into the first masterbatch obtained above, in a mixer by thermomechanically kneading everything until a maximum temperature of between 130° C. and 200° C. is reached,
cooling the combined mixture to a temperature below 100° C.,
subsequently incorporating: a crosslinking system,
kneading everything up to a maximum temperature below 120° C.

2. The process according to claim 1 , wherein the diene elastomer is selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers, and blends of these elastomers.

3. The process according to claim 2 , wherein the diene elastomer is a natural rubber.

4. The process according to claim 1 , wherein the inorganic filler is a silica or a silica covered carbon black.

5. The process according to claim 1 , wherein the content of carbon black is between 30 and 80 phr, and the content of inorganic filler is between 5 and 50 phr.

6. A process for preparing a masterbatch which comprises at least one diene elastomer, a filler comprising at least carbon black and an inorganic filler and having an inorganic filler content of less than or equal to 50 parts by weight per hundred parts of elastomer, comprising adding the inorganic filler to a first diene elastomer and carbon black masterbatch wherein the first diene elastomer and carbon black masterbatch is produced according to the following steps:
feeding a continuous flow of a diene elastomer latex to a mixing zone of a coagulation reactor defining an elongate coagulation zone extending between the mixing zone and an outlet,
feeding a continuous flow of a fluid comprising a filler comprising carbon black under pressure to the mixing zone of a coagulation reactor to form a coagulated mixture,
drying the coagulum obtained above in order to recover the first masterbatch.

7. The process according to claim 4 , wherein the silica is a precipitated silica or a silica-covered carbon black.

8. The process according to claim 5 , wherein the content of carbon black is between 40 and 70 phr and the content of inorganic filler is between 10 and 30 phr.

Assignees

• Thomasson Damien
• Michelin & Cie
• Michelin Rech Tech

Inventors

• Thomasson Damien

Classifications

• C08K3/36

  Silica · CPC title

• C08L21/00

  Compositions of unspecified rubbers · CPC title

• C08J2421/00

  Characterised by the use of unspecified rubbers · CPC title

• C08L7/00 Primary

  Compositions of natural rubber · CPC title

• C08K3/04 Primary

  Carbon · CPC title