On-line analysis of acrylonitrile product

Patent metadata

Field	Value
Publication number	US-9670146-B2
Application number	US-201514710710-A
Country	US
Kind code	B2
Filing date	May 13, 2015
Priority date	May 19, 2014
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

An apparatus comprises a first controller configured to control at least the flow rate of a polymerization inhibitor or acrylonitrile product to a first location where the two are mixed. The apparatus comprises a first on-line analyzer configured to measure polymerization inhibitor concentration in the acrylonitrile product at a second location, the second location downstream of the first location. The first on-line analyzer is configured to provide information relating to the measured inhibitor concentration at the second location to the first controller, the first controller configured to process the information from the first on-line analyzer and to adjust at least a first operating parameter of a first addition device if the measured inhibitor concentration at the second location is outside a first predetermined condition. A second controller and a second on-line analyzer are provided to provide similar control of water addition to acrylonitrile product.

First claim

We claim:

1. An apparatus comprising:
a first location wherein a polymerization inhibitor is added to an acrylonitrile product to form a mixture of acrylonitrile product and the polymerization inhibitor;
a first controller, the first controller configured to control at least the flow rate of a polymerization inhibitor to the first location, or at least the flow rate of the acrylonitrile product to the first location, wherein the first controller comprises a first processor, the first processor comprising a first memory, the first memory configured to receive and store the first predetermined condition;
a first on-line analyzer, the first on-line analyzer configured to measure polymerization inhibitor concentration in the acrylonitrile product at a second location, the second location downstream of the first location;
the first on-line analyzer configured to provide information relating to the measured inhibitor concentration at the second location to the first controller, the first controller configured to process the information from the first on-line analyzer and to adjust at least a first operating parameter of a first addition device if the measured inhibitor concentration at the second location is outside a first predetermined condition;
a third location wherein water is added to the acrylonitrile product to form a mixture of acrylonitrile product and water;
a second controller, the second controller configured to control at least the flow rate of water to the third location, or at least the flow rate of the acrylonitrile product to the third location, wherein the second controller comprises a second processor, the second processor comprising a second memory, the second memory configured to receive and store the second predetermined condition;
a second on-line analyzer, the second on-line analyzer configured to measure water concentration in the acrylonitrile product at a fourth location, the fourth location downstream of the third location;
the second on-line analyzer configured to provide information relating to the measured water concentration at the fourth location to the second controller, the second controller configured to process the information from the second on-line analyzer and to adjust at least a second operating parameter of a second addition device if the measured water concentration at the fourth location is outside a second predetermined conditions;
a third controller, the third controller configured to control at least one operating parameter of an acrylonitrile manufacturing plant, wherein the third controller comprises a third processor, the third processor comprising a third memory, the third memory configured to receive and store the third predetermined condition;
a third on-line analyzer, the third on-line analyzer configured to measure at least one impurity concentration in the acrylonitrile product at a fifth location, the fifth location upstream of the first location; wherein the third on-line analyzer comprises a gas chromatograph;
the third on-line analyzer configured to provide information relating to the measured at least one impurity at the fifth location to the third controller, the third controller configured to process the information from the third on-line analyzer and to adjust at least a third operating parameter upstream of the fifth location if the measured impurity concentration at the fifth location is greater than a third predetermined condition; and
a composite sample collector located at a sixth location, the sixth location downstream of the fourth location, the composite sample collector configured to collect a sample representative of three to twelve hours of acrylonitrile production.

2. The apparatus of claim 1 , wherein the polymerization inhibitor is methyl ether of hydroquinone.

3. The apparatus of claim 1 , wherein the first on-line analyzer comprises an ultraviolet light analyzer.

4. The apparatus of claim 1 , wherein the first predetermined condition comprises a desired inhibitor concentration at the second location.

5. The apparatus of claim 4 , wherein the first addition device is selected from the group consisting of a valve, pump, and combinations thereof.

6. The apparatus of claim 5 , wherein the first addition device is configured to be operated for controlled addition of inhibitor to the acrylonitrile product at the first location.

7. The apparatus of claim 5 , wherein the first addition device is configured to be operated for controlled addition of acrylonitrile product to inhibitor at the first location.

8. The apparatus of claim 1 , wherein the second on-line analyzer comprises an infrared light analyzer.

9. The apparatus of claim 1 , wherein the second predetermined condition comprises a desired water concentration at the fourth location.

10. The apparatus of claim 9 , wherein the second addition device is selected from the group consisting of a valve, pump, and combinations thereof.

11. The apparatus of claim 10 wherein the second addition device is configured to be operated for controlled addition of water to the acrylonitrile product at the third location.

12. The apparatus of claim 10 , wherein the second addition device is configured to be operated for controlled addition of acrylonitrile product to water at the third location.

13. The apparatus of claim 1 , wherein the third predetermined condition comprises a desired maximum concentration of the at least one impurity at the fifth location.

14. The apparatus of claim 13 , wherein the first addition device is selected from the group consisting of a valve, pump, and combinations thereof.

15. The apparatus of claim 1 , wherein the at least one impurity is selected from the group consisting of hydrogen cyanide, acetonitrile, and acetone, and combinations thereof.

Assignees

• Ineos Europe Ag

Inventors

• Mcdonel Timothy Robert
• Couch Jay Robert
• Wagner David Rudolph
• Wachtendorf Paul Trigg

Classifications

• C07C253/32 Primary

  Separation; Purification; Stabilisation; Use of additives · CPC title

• G05D11/13

  characterised by the use of electric means · CPC title

• G05D11/138

  by sensing the concentration of the mixture, e.g. measuring pH value · CPC title

• C07C255/08

  Acrylonitrile; Methacrylonitrile · CPC title