Natural gas processing and systems

Patent metadata

Field	Value
Publication number	US-9670113-B2
Application number	US-201313936783-A
Country	US
Kind code	B2
Filing date	Jul 8, 2013
Priority date	Jul 9, 2012
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

Natural gas and petrochemical processing systems including oxidative coupling of methane reactor systems that integrate process inputs and outputs to cooperatively utilize different inputs and outputs of the various systems in the production of higher hydrocarbons from natural gas and other hydrocarbon feedstocks.

First claim

The invention claimed is:

1. A natural gas processing system, comprising:
(a) an oxidative coupling of methane (OCM) reactor system comprising at least one reactor vessel having at least one OCM catalyst disposed therein and configured to operate with an inlet temperature between about 400° C. and about 600° C. to yield a product stream comprising at least two different hydrocarbon compounds, wherein the OCM catalyst comprises a nanostructured component which comprises a nanowire component having an aspect ratio greater than ten;
(b) one or more of (i) an extraction system for separating at least one hydrocarbon compound from at least one non-hydrocarbon compound as part of the product stream or a feed stream to the at least one reactor vessel, and (ii) a fractionation system for separating the at least two different hydrocarbon compounds; and
(c) an interconnected pipeline, the interconnected pipeline fluidly connecting (i) an inlet of the OCM reactor system to an outlet of the extraction system and/or the fractionation system, or (ii) an outlet of the OCM reactor system to an inlet of the extraction system and/or the fractionation system.

2. The processing system of claim 1 , wherein the extraction system comprises a methane rich effluent outlet, and wherein the inlet of the OCM reactor system is fluidly coupled to the methane rich effluent outlet of the extraction system, to convey methane rich effluent from the extraction system to the reactor vessel.

3. The processing system of claim 1 , wherein the fractionation system comprises one or more of a de-ethanizing unit, a de-propanizing unit and a de-butanizing unit, and the outlet of the OCM reactor system is fluidly coupled to an inlet of the fractionation system for transferring an OCM product in the product stream to the fractionation system.

4. The processing system of claim 3 , wherein the outlet of the OCM reactor system is fluidly coupled to an inlet of the de-ethanizing unit in the fractionation system for transferring an OCM product to the de-ethanizing unit.

5. The processing system of claim 1 , wherein the outlet of the OCM reactor system is fluidly coupled to the inlet of the extraction system for transferring an OCM product to the extraction system.

6. The processing system of claim 2 or 5 , wherein the extraction system is selected from a cryogenic extraction system and a lean oil extraction system.

7. The processing system of claim 2 or 5 , wherein the extraction system comprises a cryogenic extraction system, wherein the cryogenic extraction system comprises a nitrogen rejection unit and a cryogenic de-methanizing unit for separating methane from the OCM product.

8. The processing system of claim 1 , wherein the at least one OCM catalyst catalyzes an OCM reaction of methane and oxygen at a reactor inlet temperature of between about 400° C. and 600° C., and a pressure of less than 150 psig, wherein the reaction has methane conversion of at least 10% in a single process pass and a C2+selectivity of at least 50%.

9. The processing system of claim 1 , wherein the nanowire component comprises a catalytic nanowire component.

10. The processing system of claim 1 , wherein the inlet of the OCM reactor system is fluidly coupled to an outlet of a purification system, an outlet of the extraction system or an outlet of the fractionation system, and the outlet of the OCM reactor system is fluidly connected to an inlet of one or more of the extraction system and the fractionation system.

11. A natural gas processing system, comprising:
(a) an oxidative coupling of methane (OCM) reactor system comprising at least one reactor vessel having an OCM catalyst disposed therein and configured to operate with an inlet temperature between about 400° C. and about 600° C. to yield a product stream comprising at least two different hydrocarbon compounds, wherein the OCM catalyst comprises a nanostructured component which comprises a nanowire component having an aspect ratio greater than ten;
(b) an extraction system for separating at least one non-hydrocarbon compound from at least one hydrocarbon compound as part of the product stream or a feed stream to the at least one reactor vessel;
(c) a fractionation system for separating the at least two different hydrocarbon compounds; and
(d) an interconnected pipeline fluidly connecting (i) an inlet of the OCM reactor system to an outlet of the fractionation system and/or the extraction system, or (ii) an outlet of the OCM reactor system to an inlet of the extraction system and/or the fractionation system.

12. The processing system of claim 11 , wherein the extraction system comprises a methane rich effluent outlet, and wherein the inlet of the OCM reactor system is fluidly coupled to the methane rich effluent outlet of the extraction system, to convey methane rich effluent from the extraction system to the at least one reactor vessel.

13. The processing system of claim 11 , wherein the fractionation system comprises one or more of a de-ethanizing unit, a de-propanizing unit and a de-butanizing unit, and the outlet of the OCM reactor system is fluidly coupled to an inlet of the fractionation system for transferring an OCM product in the product stream to the fractionation system.

14. The processing system of claim 13 , wherein the outlet of the OCM reactor system is fluidly coupled to an inlet of the de-ethanizing unit in the fractionation system for transferring an OCM product to the de-ethanizing unit.

15. The processing system of claim 11 , wherein the outlet of the OCM reactor system is fluidly coupled to the inlet of the extraction system for transferring an OCM product to the extraction system.

16. The processing system of claim 11 , wherein the extraction system is selected from a cryogenic extraction system and a lean oil extraction system.

17. The processing system of claim 11 , wherein the extraction system comprises a cryogenic extraction system, wherein the cryogenic extraction system comprises a nitrogen rejection unit and a cryogenic de-methanizing unit for separating methane from the OCM product.

18. The processing system of claim 11 , wherein the OCM catalyst catalyzes an OCM reaction of methane and oxygen at a reactor inlet temperature of between about 400° C. and 600° C., and a pressure of less than 150 psig, wherein the reaction has methane conversion of at least 10% in a single process pass and a C2+selectivity of at least 50%.

19. The processing system of claim 11 , wherein the nanowire component comprises a catalytic nanowire component.

20. The processing system of claim 11 , wherein the inlet of the OCM reactor system is fluidly coupled to an outlet of a purification system, an outlet of the extraction system or an outlet of the fractionation system, and the outlet of the OCM reactor system is fluidly connected to an inlet of one or more of the extraction system and the fractionation system.

Assignees

• Siluria Technologies Inc

Inventors

• Iyer Rahul
• Tkachenko Alex
• Weinberger Sam
• Scher Erik C
• Zurcher Fabio R
• Cizeron Joel M
• Schammel Wayne P
• Gamoras Joel
• Karshtedt Dmitry
• Nyce Greg

Classifications

• C10G9/00

  Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils · CPC title

• C07C2/06

  of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• B01J8/02

  with stationary particles, e.g. in fixed beds · CPC title

• C10G50/00

  Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title

• B01J8/04

  the fluid passing successively through two or more beds · CPC title