High temperature calcium silicate insulation

Patent metadata

Field	Value
Publication number	US-9670098-B2
Application number	US-201514688304-A
Country	US
Kind code	B2
Filing date	Apr 16, 2015
Priority date	Apr 16, 2015
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

A calcium silicate insulation product includes a calcium silicate hydrate matrix that is predominantly but not substantially all xonotlite, for example 51-90 weight percent xonotlite and 10-49 weight percent tobermorite. The insulation product also contains wollastonite, fines of lime and silica, and reinforcing carbon fibers. A method of producing the insulation product includes providing the components of the insulation as dry solids, blending the dry solids with water to form a slurry, filter pressing the slurry to form a pressed shape, and curing the pressed shape under steam pressure only until the desired proportions of xonotlite and tobermorite are achieved in the calcium silicate hydrate matrix.

First claim

What is claimed is:

1. An insulating material, comprising:
xonotlite;
tobermorite;
wollastonite;
carbon fibers; and
fines of lime and silica;
wherein the xonotlite, tobermorite, wollastonite, carbon fibers, and fines of lime and silica are formed into a substantially uniform rigid body, wherein the insulating material includes a calcium silicate hydrate matrix having 51-90 weight percent xonotlite and 10-49 weight percent tobermorite.

2. The insulating material of claim 1 , wherein the calcium silicate hydrate matrix has 62-81 weight percent xonotlite and 19-38 weight percent tobermorite.

3. The insulating material of claim 1 , wherein the calcium silicate hydrate matrix has 66-76 weight percent xonotlite and 24-34 weight percent tobermorite.

4. The insulating material of claim 1 , wherein, other than the carbon fibers, the insulating material includes:
18-50 weight percent xonotlite;
8-30 weight percent tobermorite;
30-60 weight percent wollastonite; and
1-20 weight percent fines of lime and silica.

5. The insulating material of claim 1 , wherein, other than the carbon fibers, the insulating material includes:
18-50 weight percent xonotlite;
8-30 weight percent tobermorite;
40-60 weight percent wollastonite; and
4-20 weight percent fines of lime and silica.

6. The insulating material of claim 1 , wherein, other than the carbon fibers, the insulating material includes:
22-32 weight percent xonotlite;
8-14 weight percent tobermorite;
49-59 weight percent wollastonite; and
5-11 weight percent fines of lime and silica.

7. The insulating material of claim 1 , wherein the insulating material has a flexural strength of at least 1300 lb/in 2 .

8. The insulating material of claim 1 , wherein the insulating material has a flexural strength of at least 1400 lb/in 2 .

9. The insulating material of claim 1 , wherein the insulating material has a flexural strength of at least 1500 lb/in 2 .

10. The insulating material of claim 1 , wherein the insulating material has a compressive strength of at least 2600 lb/in 2 .

11. The insulating material of claim 1 , wherein the insulating material has a compressive strength of at least 3200 lb/in 2 .

12. The insulating material of claim 11 , wherein the density of the insulating material is less than 55 lb/ft 3 .

13. The insulating material of claim 1 , wherein the insulating material has a linear shrinkage in length of less than 0.5 percent at 1380° F.

14. The insulating material of claim 1 , wherein the insulating material has a linear shrinkage in length of less than 0.4 percent at 1380° F.

15. The insulating material of claim 14 , wherein the insulating material has a linear shrinkage in thickness of less than 0.90 percent at 1380° F.

16. A method of making an insulating material, the method comprising:
providing as dry solids
10-20 weight percent previously-prepared xonotlite,
15-25 weight percent lime,
15-25 weight percent silica,
35-55 weight percent wollastonite, and
1-5 weight percent carbon fibers;

blending the dry solids with water to form a slurry;
filter pressing the slurry to form a pressed shape; and
curing the resulting pressed shape under steam pressure only until the resulting composition includes, in addition to the carbon fibers, wollastonite, and any residual lime and silica, a calcium silicate hydrate matrix having 51-90 weight percent xonotlite and 10-49 weight percent tobermorite.

17. The method of claim 16 , comprising curing the resulting pressed shape under steam pressure only until the resulting composition includes, in addition to the carbon fibers, wollastonite, and any residual lime and silica, a calcium silicate hydrate matrix having 62-81 weight percent xonotlite and 19-38 weight percent tobermorite.

18. The method of claim 16 , comprising curing the resulting pressed shape under steam pressure only until the resulting composition includes, in addition to the carbon fibers, wollastonite, and any residual lime and silica, a calcium silicate hydrate matrix having 66-76 weight percent xonotlite and 24-34 weight percent tobermorite.

19. The method of claim 16 , comprising curing the resulting pressed shape under steam pressure comprises curing the resulting pressed shape under saturated steam at 12-18 bar for 5 to 8 hours.

20. The method of claim 16 , wherein 4 to 6 pounds of water are used per pound of dry solids.

Assignees

• Johns Manville

Inventors

• Kulprathipanja Ames
• Dolin Rick Lee
• Camp Noel

Classifications

• C04B2111/28

  Fire resistance, i.e. materials resistant to accidental fires or high temperatures · CPC title

• C04B28/188 Primary

  the Ca-silicates being present in the starting mixture · CPC title

• C04B14/043

  Alkaline-earth metal silicates, e.g. wollastonite · CPC title

• C04B14/062

  Microsilica, e.g. colloïdal silica (preparing microsilica slurries or suspensions C04B18/148) · CPC title

• C04B40/024

  Steam hardening, e.g. in an autoclave · CPC title