Composition and method for treating oilfield water

Patent metadata

Field	Value
Publication number	US-9670080-B2
Application number	US-201313924801-A
Country	US
Kind code	B2
Filing date	Jun 24, 2013
Priority date	Jun 24, 2013
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

A method for reducing sulfide in oilfield waste water includes contacting oilfield waste water with an oxidizer in the presence of an iron catalyst. The oilfield waste water includes sulfide that is oxidized to sulfate while avoiding formation of a colloidal or bulk sulfur precipitate. A method for recycling oilfield waste water includes contacting oilfield waste water with an oxidizer in the presence of an iron catalyst, the oilfield waste water comprising sulfide; oxidizing the sulfide to sulfate; avoiding formation of a colloidal sulfur precipitate, a bulk sulfur precipitate, or a combination comprising at least one of the foregoing; clarifying the oilfield waste water by contacting the oilfield waste water with a flocculant to form an aggregate precipitate; separating the aggregate precipitate from the oilfield waste water to form a recycled water; combining an additive with the recycled water; and disposing the recycled water in a downhole environment.

First claim

What is claimed is:

1. A method for reducing sulfide in oilfield waste water, the method comprising:
contacting oilfield waste water with a combination of an oxidizer and an iron catalyst, the oilfield waste water comprising sulfide, the oxidizer comprising one or more of the following: a halogen oxidizer; a nitrate; a nitrite; a dichromate; or a nitrogen-chloro oxidizer; and the iron catalyst comprising an iron salt; the iron catalyst comprising one or more of the following: ferric sulfate; ferric chloride, or ferric nitrate;
oxidizing the sulfide in the oilfield waste water to sulfate with the oxidizer in the presence of the iron catalyst to reduce the amount of the sulfide to less than 0.5 ppm, based on the weight of the oilfield waste water; and
avoiding formation of elemental sulfur.

2. The method of claim 1 , further comprising clarifying the oilfield waste water by contacting the oilfield waste water with a coagulant, a flocculant, or a combination thereof.

3. The method of claim 2 , further comprising separating, from the oilfield waste water, an aggregate precipitate formed by the coagulant, the flocculant, or a combination thereof.

4. The method of claim 1 , wherein contacting the oilfield waste water with the oxidizer comprises combining the oilfield waste water, the oxidizer, and the iron catalyst in a flowing stream.

5. The method of claim 1 , wherein contacting the oilfield waste water with the oxidizer comprises disposing the oilfield waste water, the oxidizer, and the iron catalyst together in a storage container.

6. The method of claim 1 , wherein the sulfide comprises one or more of the following: hydrogen sulfide; bisulfide; or sulfide ion.

7. The method of claim 1 , wherein the sulfide oxidizer comprises chlorine dioxide.

8. The method of claim 1 , wherein the oilfield waste water is produced water, flowback water, or a combination thereof.

9. The method of claim 1 , wherein the oxidizer is present in an amount from 1 ppm to 20,000 ppm, based on a volume of the oxidizer added to the oilfield waste water.

10. The method of claim 1 , wherein oxidizing the sulfide to sulfate is complete within five minutes after contacting the oxidizer in the presence of the iron catalyst.

11. The method of claim 1 , wherein oxidizing sulfide to sulfate is carried out at a pH of from 0 to 12.

12. A method for recycling oilfield waste water, the method comprising:
contacting oilfield waste water with a combination of an oxidizer and an iron catalyst, the oilfield waste water comprising sulfide; the oxidizer comprising one or more of the following: a halogen oxidizer; a nitrate; a nitrite; a dichromate; or a nitrogen-chloro oxidizer, and the iron catalyst comprising an iron salt; the iron catalyst comprising one or more of the following: ferric sulfate; ferric chloride, or ferric nitrate;
oxidizing the sulfide in the oilfield waste water to sulfate with the oxidizer in the presence of the iron catalyst to reduce the amount of the sulfide to less than 0.5 ppm, based on the weight of the oilfield waste water;
avoiding formation of elemental sulfur;
clarifying the oilfield waste water by contacting the oilfield waste water with a flocculant to form an aggregate precipitate;
separating the aggregate precipitate from the oilfield waste water to form a recycled water;
combining an additive with the recycled water; and
disposing the recycled water in a downhole environment.

13. The method of claim 12 , wherein the recycled water is
a hydraulic fracturing fluid comprising slickwater or a crosslink fluid; or
an enhanced oil recovery fluid.

14. The method of claim 12 , wherein the sulfide is present in the recycled water in an amount less than 0.5 ppm, based on a weight of the recycled water.

15. The method of claim 14 , wherein, before oxidizing the sulfide, the sulfide is present in the oilfield waste water in an amount greater than 1,000 ppm, based on a weight of the oilfield waste water.

16. A method for reducing sulfide in oilfield waste water, the method comprising:
contacting oilfield waste water with a combination of chlorine dioxide and an iron catalyst, the oilfield waste water comprising sulfide, and the iron catalyst comprising ferric sulfate;
oxidizing the sulfide in the oilfield waste water to sulfate with the chlorine dioxide in the presence of the iron catalyst to reduce the amount of the sulfide to less than 0.5 ppm, based on the weight of the oilfield waste water; and
avoiding formation of elemental sulfur;
wherein the catalyst is present in an amount of 0.5 ppm to 50 ppm based on the volume of the oilfield waste water.

17. The method of claim 16 , wherein the oxidizing the sulfide to sulfate is complete within five minutes after contacting the oxidizer in the presence of the iron catalyst.

18. The method of claim 16 , wherein the oilfield waste water is produced water, flowback water, or a combination thereof.

19. The method of claim 1 , wherein the catalyst is present in an amount of 0.5 ppm to 50 ppm, based on the volume of the oilfield waste water.

Assignees

• Seth Kushal
• Baker Hughes Inc

Inventors

• Seth Kushal

Classifications

• C02F1/52

  by flocculation or precipitation of suspended impurities {(C02F1/463 takes precedence)} · CPC title

• C02F2103/10

  from quarries or from mining activities · CPC title

• C02F1/725 Primary

  by catalytic oxidation · CPC title

• C02F1/766

  by means of halogens other than chlorine or of halogenated compounds containing halogen other than chlorine · CPC title

• E21B43/40

  Separation associated with re-injection of separated materials {(E21B43/385 takes precedence)} · CPC title